ChemicalBook--->CAS DataBase List--->101-72-4

101-72-4

101-72-4 Structure

101-72-4 Structure
IdentificationMore
[Name]

N-Isopropyl-N'-phenyl-1,4-phenylenediamine
[CAS]

101-72-4
[Synonyms]

4-ISOPROPYLAMINODIPHENYLALANINE
4-ISOPROPYLAMINODIPHENYLAMINE
IPPD
n-(1-methylethyl)-n'-phenyl-1,4-benzenediamine
N-2-Propyl-N'-phenyl-p-phenylenediamine
N-ISOPROPYL-N'-PHENYL-1,4-PHENYLENEDIAMINE
N-ISOPROPYL-N'-PHENYL-P-PHENYHLENEDIAMINE
N-ISOPROPYL-N-PHENYL-P-PHENYLENE DIAMINE
N-ISOPROPYL-N'-PHENYL-P-PHENYLENEDIAMINE
N-PHENYL-N-ISOPROPYL-P-PHENYLENEDIAMINE
SANTOFLEX(R) IP
VANOX 3C
1,4-Benzenediamine, N-(1-methylethyl)-N'-phenyl-
1,4-Benzenediamine,N-(1-methylethyl)-N’-phenyl-
4010 NA
4010na
4-Anilino-N-isopropylaniline
4-Benzenediamine,N-(1-methylethyl)-N’-phenyl-1
Akrochem antioxidant pd1
Antigen 3c
[EINECS(EC#)]

202-969-7
[Molecular Formula]

C15H18N2
[MDL Number]

MFCD00026348
[Molecular Weight]

226.32
[MOL File]

101-72-4.mol
Chemical PropertiesBack Directory
[Appearance]

dark grey to black solid
[Melting point ]

72-76°C
[Boiling point ]

161°C
[density ]

1,17 g/cm3
[vapor pressure ]

0.007Pa at 20℃
[refractive index ]

1.5000 (estimate)
[Fp ]

161°C/1mm
[storage temp. ]

-20°C
[solubility ]

Chloroform (Slightly), DMSO (Slightly, Sonicated)
[form ]

Solid
[pka]

6.76±0.32(Predicted)
[color ]

Grey to Very Dark Grey
[Stability:]

Stable. Combustible. Incompatible with strong oxidizing agents.
[biological source]

rabbit
[Water Solubility ]

<0.1 g/100 mL at 18 ºC
[Sensitive ]

Air Sensitive
[Henry's Law Constant]

7.0×103 mol/(m3Pa) at 25℃, HSDB (2015)
[Contact allergens]

This rubber chemical is used as an antioxidant and antiozonant. The main occupational sources are tires.
[LogP]

2.77 at 20℃
[Uses]

Protection of rubbers against oxidation, ozone, flex-cracking, and poisoning by copper and manganese.
[CAS DataBase Reference]

101-72-4(CAS DataBase Reference)
[NIST Chemistry Reference]

P-phenylenediamine, n-isopropyl-n'-phenyl-(101-72-4)
[EPA Substance Registry System]

101-72-4(EPA Substance)
Hazard InformationBack Directory
[Chemical Properties]

dark grey to black solid
[Definition]

ChEBI: The N-substituted diamine that is 1,4-phenylenediamine substituted at one N with an isopropyl group and at the other with a phenyl group.
[General Description]

Dark gray to black flakes or brown-black small chip-like solid with an aromatic odor.
[Reactivity Profile]

N-ISOPROPYL-N'-PHENYL-P-PHENYLENEDIAMINE(101-72-4) reacts with oxidizing agents . Neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.
[Air & Water Reactions]

May be sensitive to heat, air, light and moisture during long term storage. Insoluble in water.
[Fire Hazard]

This chemical is combustible.
[Synthesis Reference(s)]

The Journal of Organic Chemistry, 29, p. 1265, 1964 DOI: 10.1021/jo01028a511
[Flammability and Explosibility]

Nonflammable
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)Environment (GHS09)
GHS07,GHS09
[Signal word ]

Warning
[Hazard statements ]

H302-H317-H400-H410
[Precautionary statements ]

P262-P273-P280g-P501a
[Hazard Codes ]

Xi,N,Xn
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R43:May cause sensitization by skin contact.
R22:Harmful if swallowed.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S60:This material and/or its container must be disposed of as hazardous waste .
S37:Wear suitable gloves .
S24:Avoid contact with skin .
[RIDADR ]

3077
[RTECS ]

ST2650000
[Hazard Note ]

Irritant
[TSCA ]

Yes
[REACH Registrations]

Active
[HazardClass ]

9
[PackingGroup ]

III
[HS Code ]

29215900
[Hazardous Substances Data]

101-72-4(Hazardous Substances Data)
[Toxicity]

LD50 oral in rat: 720mg/kg
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Potassium carbonate-->Acetone-->Isopropyl alcohol-->Hydrogen-->Aniline-->4-Aminodiphenylamine-->Copper chromite
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

N-2-Propyl-N'-phenyl-p-phenylenediamine(101-72-4).msds
Spectrum DetailBack Directory
[Spectrum Detail]

N-Isopropyl-N'-phenyl-1,4-phenylenediamine(101-72-4)MS
N-Isopropyl-N'-phenyl-1,4-phenylenediamine(101-72-4)1HNMR
N-Isopropyl-N'-phenyl-1,4-phenylenediamine(101-72-4)13CNMR
N-Isopropyl-N'-phenyl-1,4-phenylenediamine(101-72-4)IR1
N-Isopropyl-N'-phenyl-1,4-phenylenediamine(101-72-4)IR2
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

N-Isopropyl-N'-phenyl-p-phenylenediamine, 95%(101-72-4)
[Sigma Aldrich]

101-72-4(sigmaaldrich)
[TCI AMERICA]

4-Isopropylaminodiphenylamine,>95.0%(T)(101-72-4)
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