| Identification | More | [Name]
N,N-Dimethyl-1,4-phenylenediamine | [CAS]
99-98-9 | [Synonyms]
4-AMINODIMETHYLANILINE
4-AMINO-N,N-DIMETHYLANILINE
4-ANIMODIMETHYLANILINE
4-DIMETHYLAMINOANILINE
DIMETHYL(N,N-)-P-PHENYLENEDIAMINE
Dimethyl-p-phenylenediamine
N,N-DIMETHYL-1,4-PHENYLENEDIAMINE
N,N-DIMETHYL-P-PHENYLENEDIAMINE
P-AMINODIMETHYLANILINE
P-DIMETHYLAMINOAZOBENZENE
WURSTER'S RED
4-(dimethylamino)benzenamine
4-(dimethylamino)phenylamine
4-Benzenediamine,N,N-dimethyl-1
C.I. 76075
c.i.76075
ci76075
Crategine
dimethyl-4-phenylenediamine
Dimethyl-paraphenylenediamine | [EINECS(EC#)]
202-807-5 | [Molecular Formula]
C8H12N2 | [MDL Number]
MFCD00007860 | [Molecular Weight]
136.19 | [MOL File]
99-98-9.mol |
| Chemical Properties | Back Directory | [Appearance]
grey to black solid | [Melting point ]
34-36 °C(lit.)
| [Boiling point ]
262 °C(lit.)
| [density ]
1.09
| [refractive index ]
1.5914 (estimate) | [Fp ]
130 °C
| [storage temp. ]
2-8°C
| [solubility ]
Chloroform (Slightly), Methanol (Slightly), Water (Slightly) | [form ]
crystalline
| [pka]
6?+-.0.12(Predicted) | [color ]
black
| [Stability:]
Stable. Incompatible with acid chlorides, acid anhydrides, strong acids, strong oxidizing agents. Combustible. | [Water Solubility ]
11 g/L (20 ºC) | [Sensitive ]
Light Sensitive | [Merck ]
14,3254 | [BRN ]
508105 | [Cosmetics Ingredients Functions]
HAIR DYEING | [InChI]
1S/C8H12N2/c1-10(2)8-5-3-7(9)4-6-8/h3-6H,9H2,1-2H3 | [InChIKey]
BZORFPDSXLZWJF-UHFFFAOYSA-N | [SMILES]
CN(C)c1ccc(N)cc1 | [CAS DataBase Reference]
99-98-9(CAS DataBase Reference) | [NIST Chemistry Reference]
1,4-Benzenediamine, N,N-dimethyl-(99-98-9) | [Storage Precautions]
Air sensitive;Light sensitive | [EPA Substance Registry System]
99-98-9(EPA Substance) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS06 | [Signal word ]
Danger | [Hazard statements ]
H300+H310-H331 | [Precautionary statements ]
P262-P264-P280-P301+P310-P302+P352+P310-P304+P340+P311 | [Hazard Codes ]
T | [Risk Statements ]
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . | [RIDADR ]
UN 2811 6.1/PG 2
| [WGK Germany ]
3
| [RTECS ]
ST0874000
| [F ]
8-10-23 | [Hazard Note ]
Toxic/Keep Cold | [TSCA ]
Yes | [HazardClass ]
6.1 | [PackingGroup ]
II | [HS Code ]
29215900 | [Storage Class]
6.1A - Combustible acute toxic Cat. 1 and 2
very toxic hazardous materials | [Hazard Classifications]
Acute Tox. 1 Dermal
Acute Tox. 2 Oral
Acute Tox. 3 Inhalation | [Hazardous Substances Data]
99-98-9(Hazardous Substances Data) |
| Hazard Information | Back Directory | [General Description]
Colorless to reddish-violet solid. Used in the production of methylene blue and photographic developer. Used as a chemical intermediate for dyes and diazonium chloride salts and as an analytical reagent to detect chloroamine in water. | [Reactivity Profile]
DIMETHYL-P-PHENYLENEDIAMINE neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides. Incompatible with strong oxidizers, strong acids and acid anhydrides. Also incompatible with alkalis . | [Health Hazard]
Lowest toxic dose with skin effect is 14 mg/kg. Irritant to skin and eyes. | [Fire Hazard]
When heated to decomposition, DIMETHYL-P-PHENYLENEDIAMINE emits toxic fumes of nitrogen oxides. | [Description]
Dimethyl-p-phenylenediamine is a colorless toreddish-violet crystalline solid; Molecular weight= 136.23;Boiling point = 262℃; Freezing/Melting point = 41℃;Flash point = 90℃. Insoluble in water | [Chemical Properties]
grey to black solid | [Uses]
Base for production of methylene blue, photodeveloper, reagent for detection of hydrogen sulfide, reagent for cellulose, organic synthesis, reagent for certain bacteria. | [Definition]
ChEBI: N,N-dimethyl-1,4-phenylenediamine is a substituted aniline and a diamine. | [Synthesis Reference(s)]
Chemistry Letters, 9, p. 439, 1980
Tetrahedron Letters, 34, p. 2441, 1993 DOI: 10.1016/S0040-4039(00)60436-7 | [Hazard]
Toxic by ingestion or inhalation of vapor. | [First aid]
If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin,remove contaminated clothing and wash immediately withsoap and water. Seek medical attention immediately. If thischemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart actionhas stopped. Transfer promptly to a medical facility. Whenthis chemical has been swallowed, get medical attention.Give large quantities of water and induce vomiting. Do notmake an unconscious person vomit. | [storage]
Color Code—Blue: Health Hazard/Poison: Storein a secure poison location. Store in cool, dry place awayfrom strong oxidizers and acids. | [Shipping]
Phenylenediamines require a shipping label of“POISONOUS/TOXIC MATERIALS.” T |
| Spectrum Detail | Back Directory | [Spectrum Detail]
N,N-Dimethyl-1,4-phenylenediamine(99-98-9)MS
N,N-Dimethyl-1,4-phenylenediamine(99-98-9)1HNMR
N,N-Dimethyl-1,4-phenylenediamine(99-98-9)13CNMR
N,N-Dimethyl-1,4-phenylenediamine(99-98-9)IR1
N,N-Dimethyl-1,4-phenylenediamine(99-98-9)IR2
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| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
China Langchem Inc.
|
| Telephone: |
0086-21-58956006 |
| Website: |
www.chemicalbook.com/ShowSupplierProductsList19141/0_EN.htm |
| Company Name: |
Maya High Purity Chemicals
|
| Telephone: |
+86 (573) 82222445 (0)18006601000 452520369 |
| Website: |
www.chemicalbook.com/ShowSupplierProductsList15221/0_EN.htm |
| Company Name: |
Spectrum Chemical Manufacturing Corp.
|
| Telephone: |
021-021-021-67601398-809-809-809 15221380277 |
| Website: |
www.spectrumchemical.com/oa_html/index.jsp?minisite=10020&respid=22372&language=us |
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