ChemicalBook--->CAS DataBase List--->101-75-7

101-75-7

101-75-7 Structure

101-75-7 Structure
IdentificationMore
[Name]

4-(PHENYLAZO)DIPHENYLAMINE
[CAS]

101-75-7
[Synonyms]

4-ANILINOAZOBENZENE
4-BENZENEAZODIPHENYLAMINE
4-(PHENYLAZO)DIPHENYLAMINE
BENZENEAZODIPHENYLAMINE
N-PHENYL-4-PHENYLAZOANILINE
P-PHENYLAZODIPHENYLAMINE
4-(phenylamino)azobenzene
4-(phenylazo)-diphenylamin
4-anilino-azobenzen
Azobenzene, 4-anilino-
Diphenylamine, 4-(phenylazo)-
N-Phenyl-4-[(E)-phenyldiazenyl]aniline
N-Phenyl-4-aminoazobenzene
4-Azobenzeneaniline
4-Phenylazodiphenylamine98%
N-PHENYL-4-(PHENYLAZO)-BENZENAMINE
N-Phenyl-4-(phenylazo)anilin
4-(Phenylazo)diphenylamine, 4-Anilinoazobenzene
4-Anilinoazobenzene, N-Phenyl-4-phenylazoaniline
N-Phenylazobenzene-4-amine
[EINECS(EC#)]

202-972-3
[Molecular Formula]

C18H15N3
[MDL Number]

MFCD00003023
[Molecular Weight]

273.33
[MOL File]

101-75-7.mol
Chemical PropertiesBack Directory
[Appearance]

orange fine crystalline powder
[Melting point ]

87-91 °C
[Boiling point ]

406.35°C (rough estimate)
[density ]

1.0332 (rough estimate)
[refractive index ]

1.5480 (estimate)
[storage temp. ]

room temp
[solubility ]

Solubility Insoluble in water; soluble in ethanol, methanol
[form ]

Fine Crystalline Powder
[pka]

0.42(at 25℃)
[color ]

Orange
[PH Range]

Red (1.2) to yellow (2.5)
[λmax]

411nm, 272nm
[BRN ]

749359
[Major Application]

Display device, nonlinear optial (NLO) material, photoresists, printing plates, lithographic plates, photosensitive materials, photography, markers
[InChI]

InChI=1S/C18H15N3/c1-3-7-15(8-4-1)19-16-11-13-18(14-12-16)21-20-17-9-5-2-6-10-17/h1-14,19H
[InChIKey]

VXLFYNFOITWQPM-UHFFFAOYSA-N
[SMILES]

C1(NC2=CC=CC=C2)=CC=C(N=NC2=CC=CC=C2)C=C1
[CAS DataBase Reference]

101-75-7(CAS DataBase Reference)
[EPA Substance Registry System]

Benzenamine, N-phenyl-4-(phenylazo)- (101-75-7)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[RIDADR ]

3234
[WGK Germany ]

1
[RTECS ]

JK0185000
[TSCA ]

Yes
[HS Code ]

29270000
[Toxicity]

LD50 ivn-mus: 56 mg/kg CSLNX* NX#03760
Hazard InformationBack Directory
[Chemical Properties]

orange fine crystalline powder
[Uses]

4-(Phenylazo)diphenylamine is a soluble azo dye and stain. Dyes and metabolites.
[Safety Profile]

Poison by intravenous route. When heated to decomposition it emits toxic vapors of NOx.
[Purification Methods]

Purify the dye by chromatography on neutral alumina using dry *C6H6 with 1% of dry MeOH. The major component, which gave a stationary band, is cut out and eluted with EtOH or MeOH. [H.gfeldt & Bigeleisen J Am Chem Soc 82 15 1960.] It crystallises from pet ether, EtOH or aqueous EtOH, and has max at 420nm ( 28,000) (aqueous EtOH) and 540nm (aqueous EtOH/H2SO4) [Badger et al. J Chem Soc 1888 1954, Beilstein 16 H 314, 16 III 343, 16 IV 457.]
Spectrum DetailBack Directory
[Spectrum Detail]

4-(PHENYLAZO)DIPHENYLAMINE(101-75-7)MS
4-(PHENYLAZO)DIPHENYLAMINE(101-75-7)13CNMR
4-(PHENYLAZO)DIPHENYLAMINE(101-75-7)IR1
4-(PHENYLAZO)DIPHENYLAMINE(101-75-7)IR2
4-(PHENYLAZO)DIPHENYLAMINE(101-75-7)IR3
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

4-(Phenylazo)diphenylamine, 97%(101-75-7)
[Alfa Aesar]

4-Phenylazodiphenylamine, 97%(101-75-7)
[Sigma Aldrich]

101-75-7(sigmaaldrich)
[TCI AMERICA]

4-(Phenylazo)diphenylamine,>98.0%(T)(101-75-7)
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