ChemicalBook--->CAS DataBase List--->587-98-4

587-98-4

587-98-4 Structure

587-98-4 Structure
IdentificationMore
[Name]

METANIL YELLOW
[CAS]

587-98-4
[Synonyms]

3-(4-ANILINOPHENYLAZO)BENZENESULFONIC ACID SODIUM SALT
3-[[4-(PHENYLAMINO)PHENYL]AZO]BENZENESULFONIC ACID MONOSODIUM SALT
ACID YELLOW 36
CI 13065
CI NO 13065
KITON ORANGE MNO
KITON YELLOW MS
METANIL YELLOW
METANIL YELLOW ORANGE
M-[(P-ANILINOPHENYL)AZO]BENZENESULFONIC ACID SODIUM SALT
ORANGE MNO
SODIUM M-(P-ANILINOPHENYLAZO)BENZENESULFONATE
TROPAEOLIN G
VICTORIA YELLOW
11363yellow
3-((4-(phenylamino)phenyl)azo)-benzenesulfonicacimonosodiumsalt
3-[[4-(phenylamino)phenyl]azo]-benzenesulfonicacimonosodiumsalt
abcolmetanilyellow
AcidgoldenyellowG
acidicmetanilyellow
[EINECS(EC#)]

209-608-2
[Molecular Formula]

C18H14N3NaO3S
[MDL Number]

MFCD00007486
[Molecular Weight]

375.38
[MOL File]

587-98-4.mol
Chemical PropertiesBack Directory
[Appearance]

orange powder
[Melting point ]

>250°C
[Boiling point ]

325℃[at 101 325 Pa]
[bulk density]

330kg/m3
[density ]

0.488[at 20℃]
[vapor pressure ]

0Pa at 25℃
[storage temp. ]

Storage temperature: no restrictions.
[solubility ]

25g/l
[Colour Index ]

13065
[form ]

Powder
[pka]

4.4-5.5
[color ]

Orange
[PH]

10 (10g/l, H2O, 20℃)
[PH Range]

Red (1.2) to yellow (2.3)
[Water Solubility ]

Soluble in water (25g/L).
[ε(extinction coefficient)]

≥18500 at 415.0-419.0nm
[λmax]

414nm, 435nm
[Merck ]

14,5928
[BRN ]

3831568
[Major Application]

Display device, nanoparticles, optical sensors, batteries, lithographic printing plates, inks, highlighters, children’s coloring books, floor coatings, disinfectants, dyes, personal care products, cosmetics, food storage, antiseptic, dental impressionmaterials
[Cosmetics Ingredients Functions]

HAIR DYEING
[InChI]

1S/C18H15N3O3S.Na/c22-25(23,24)18-8-4-7-17(13-18)21-20-16-11-9-15(10-12-16)19-14-5-2-1-3-6-14;/h1-13,19H,(H,22,23,24);/q;+1/p-1/b21-20+;
[Contact allergens]

Metanil yellow is a yellow monoazoic dye. This color ing agent is used in leather and wood stains, and is also employed as a food dye in India.
[InChIKey]

NYGZLYXAPMMJTE-ANVLNOONSA-M
[SMILES]

[Na+].[O-]S(=O)(=O)c1cccc(c1)\N=N\c2ccc(Nc3ccccc3)cc2
[LogP]

0.137 at 25℃
[CAS DataBase Reference]

587-98-4(CAS DataBase Reference)
[EPA Substance Registry System]

C.I. Acid Yellow 36, monosodium salt (587-98-4)
Hazard InformationBack Directory
[Chemical Properties]

orange powder
[Definition]

ChEBI: An organic sodium salt having 3-[(4-anilinophenyl)diazenyl]benzene-1-sulfonate as the counterion. Used in one variant of Masson's trichrome to stain collagen yellow in contrast to the red muscle, but is not in common used.
[Uses]

As indicator in 0.1% solution, of which 2 drops are required for 10 ml liquid. pH: 1.2 red to 2.3 yellow.
[Description]

Metanil yellow is a yellow monoazo dye. This coloring agent is used in leather and wood stains, and was also employed as a food dye in India.
[General Description]

Metanil yellow is an azo dye, which is used as a counterstain in PAS (periodic acid-Schiff) or iron-hematoxylin stained sections to increase contrast. At pH 1.2, metanil yellow is red in color, whereas in pH 2.3, it is yellow in color.
[Flammability and Explosibility]

Notclassified
[Biochem/physiol Actions]

Metanil yellow is an azo dye. It is used as a counterstain in PAS (periodic acid-Schiff)/iron-hematoxylin stained sections to increase contrast. Metanil yellow changes its color from red at pH 1.2 to yellow at pH 2.3.
[Properties and Applications]

Standard

Light Fastness

Soaping

Persperation Fastness

Oxygen bleaching

Fastness to seawater

Fading

Stain

Fading

Stain

Fading

Stain

ISO

3

2

2-3

AATCC

3

1

4

5

1

[Purification Methods]

It can be salted out from water three times with sodium acetate, then repeatedly extracted with EtOH [McGrew & Schneider J Am Chem Soc 72 2547 1950]. [Beilstein 16 II 168.]
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R43:May cause sensitization by skin contact.
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes .
S36/37:Wear suitable protective clothing and gloves .
S36:Wear suitable protective clothing .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[WGK Germany ]

2
[RTECS ]

DB7329500
[TSCA ]

Yes
[REACH Registrations]

Inactive
[HS Code ]

32041200
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Aquatic Chronic 3
Eye Dam. 1
[Safety Profile]

Moderately toxic by intraperitoneal route. Experimental reproductive effects. Human mutation data reported. When heated to decomposition it emits toxic fumes of SOx, NOx, and NazO. See also AROMATIC AMINES and SULFONATES.
[Toxicity]

LD50 orally in Rabbit: > 2000 mg/kg LD50 dermal Rat > 2000 mg/kg
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Metanilic acid-->Diphenylamine-->Metanilic acid-->Diphenylamine
[Preparation Products]

4-Aminodiphenylamine
Spectrum DetailBack Directory
[Spectrum Detail]

METANIL YELLOW(587-98-4)1HNMR
METANIL YELLOW(587-98-4)IR1
METANIL YELLOW(587-98-4)IR2
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Metanil Yellow, pure, 98%(587-98-4)
[Alfa Aesar]

Metanil Yellow(587-98-4)
[Sigma Aldrich]

587-98-4(sigmaaldrich)
[TCI AMERICA]

Metanil Yellow(587-98-4)
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