ChemicalBook--->CAS DataBase List--->10294-31-2

10294-31-2

10294-31-2 Structure

10294-31-2 Structure
IdentificationMore
[Name]

GOLD(I) IODIDE
[CAS]

10294-31-2
[Synonyms]

GOLD(I) IODIDE
GOLD MONOIODIDE
goldiodide(aui)
GOLD(I) IODIDE, 99.9%
Gold(I)iodide,99%(99.9+%-Au)
GOLD(I) IODIDE (99.9%-AU)
GOLD(I) IODIDE (61%AU)
Aurous iodide
gold iodide
[EINECS(EC#)]

233-656-3
[Molecular Formula]

AuI
[MDL Number]

MFCD00014175
[Molecular Weight]

323.87
[MOL File]

10294-31-2.mol
Chemical PropertiesBack Directory
[Melting point ]

120 °C (dec.)(lit.)
[density ]

8.25 g/mL at 25 °C(lit.)
[storage temp. ]

Keep in dark place,Inert atmosphere,Room temperature
[solubility ]

insoluble in H2O; soluble in CN solution
[form ]

Powder
[color ]

yellowish-green
[Specific Gravity]

8.25
[Water Solubility ]

Insoluble in water. Soluble in alkali iodide, cyanide solutions. Decomposes in warm acids
[Sensitive ]

Moisture Sensitive
[Solubility Product Constant (Ksp)]

pKsp: 22.8
[Stability:]

store cold
[InChI]

1S/Au.HI/h;1H/q+1;/p-1
[InChIKey]

ATGIETUGWDAYPU-UHFFFAOYSA-M
[SMILES]

I[Au]
[CAS DataBase Reference]

10294-31-2(CAS DataBase Reference)
[EPA Substance Registry System]

Gold iodide (AuI) (10294-31-2)
Hazard InformationBack Directory
[Chemical Properties]

yellowish to greenish yellow powder(s); decomposes slowly at ordinary temp, rapidly at elevated temp [MER06]
[Uses]

Gold(I) iodide is employed in the synthesis of chemicals.
[Purification Methods]

It has been prepared by heating gold and iodine in a tube at 120o for 4 months. Since it decomposes to Au and I2 in the presence of UV light and heat, then the main impurity is Au. The salt is therefore purified by heating at 120o with I2 for several weeks. The crystals should be kept dry and in a cool place in the dark. [Weiss & Weiss Z Naturforsch 11B 604 1956.]
[General Description]

AuI can be prepared by adding KI in an acidic solution of HAuCl4.
[reaction suitability]

reagent type: catalyst
core: gold
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection .
[RIDADR ]

UN3260
[WGK Germany ]

3
[TSCA ]

Yes
[HazardClass ]

8
[PackingGroup ]

III
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Gold(I) iodide, 99%(10294-31-2)
[Sigma Aldrich]

10294-31-2(sigmaaldrich)
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