ChemicalBook--->CAS DataBase List--->7790-47-8

7790-47-8

7790-47-8 Structure

7790-47-8 Structure
IdentificationMore
[Name]

TIN(IV) IODIDE
[CAS]

7790-47-8
[Synonyms]

STANNIC IODIDE
TIN IODIDE
TIN(IV) IODIDE
Stannane, tetraiodo-
tetraiodo-stannan
Tetraiodostannane
tetraiodo-Stannane
Tetraiodotin
Tin iodide (SnI4)
Tin(iv) iodide (1:4)
tin(iv)iodide(1:4)
Tintetraiodide
Tiniodideorangextl
Tin(Ⅳ)iodide
TIN(IV) IODIDE 95%
TIN(IV) IODIDE, 99.999%
ultradry,99.998%metalsbasis
Tin(IV)iodide,95%
tin(iv) iodide, ultra dry
Tin(IV) iodide, ultra dry, 99.998% (metals basis)
[EINECS(EC#)]

232-208-4
[Molecular Formula]

I4Sn
[MDL Number]

MFCD00036272
[Molecular Weight]

626.33
[MOL File]

7790-47-8.mol
Chemical PropertiesBack Directory
[Appearance]

Brown powder
[Melting point ]

144 °C
[Boiling point ]

364 °C
[density ]

4.47 g/mL at 25 °C(lit.)
[refractive index ]

2.106
[Fp ]

340°C
[solubility ]

Soluble in alcohol, benzene, carbon disulfide, chloroform and ether.
[form ]

powder
[color ]

Red
[Specific Gravity]

4.473
[Water Solubility ]

Soluble in alcohol, benzene, CS{2}, chloroform, and ether. Decomposes in water
[Specific Heat Capacity]

Cp(crystal):0.135552J/(g·K);Cp(gas):0.168282J/(g·K),at 25℃
[Hydrolytic Sensitivity]

8: reacts rapidly with moisture, water, protic solvents
[Sensitive ]

Moisture Sensitive
[Merck ]

14,8777
[Exposure limits]

ACGIH: TWA 2 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 2 mg/m3
[Major Application]

electroplating
material synthesis precursor
perovskite solar cells
[InChI]

1S/4HI.Sn/h4*1H;/q;;;;+4/p-4
[InChIKey]

QPBYLOWPSRZOFX-UHFFFAOYSA-J
[SMILES]

I[Sn](I)(I)I
[CAS DataBase Reference]

7790-47-8(CAS DataBase Reference)
[EPA Substance Registry System]

Stannane, tetraiodo- (7790-47-8)
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R34:Causes burns.
R42/43:May cause sensitization by inhalation and skin contact .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 3260 8/PG 2
[WGK Germany ]

3
[RTECS ]

XQ3675000
[F ]

1-8-10-19
[TSCA ]

Yes
[HazardClass ]

8
[PackingGroup ]

III
[HS Code ]

28276000
[Storage Class]

8A - Combustible corrosive hazardous materials
[Hazard Classifications]

Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Eye Dam. 1
Resp. Sens. 1
Skin Corr. 1B
Skin Sens. 1
[Safety Profile]

Poison by intravenous route. Strong reaction with N02Cl, (K+ S), (Na + S). When heated to decomposition it emits toxic fumes of I-. See also TIN COMPOUNDS and IODIDES.
[Toxicity]

MLD in rats (mg/kg): 200 i.v. (Kolmer)
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

stannic iodide(7790-47-8).msds
Hazard InformationBack Directory
[Chemical Properties]

Brown powder
[Uses]

Tin(IV) iodide is used in the preparation of tin(IV) oxide and tin(II) oxide. It reacts with hydroiodic acid to get rare tin hexaiodide. It forms tetraiodobis triphenylphosphine tin complexes by reacting with triphenylphosphine, which finds application in toothpaste formulation. Further, it acts as analytical reagents and also used in organic synthesis.
[Purification Methods]

It is recrystallised from anhydrous CHCl3, dry it under vacuum and store it in a vacuum desiccator. It sublimes at 180o.
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Tin(IV) iodide(7790-47-8)
[Alfa Aesar]

Tin(IV) iodide, ultra dry, 99.998% (metals basis)(7790-47-8)
[Sigma Aldrich]

7790-47-8(sigmaaldrich)
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