ChemicalBook--->CAS DataBase List--->10377-66-9

10377-66-9

10377-66-9 Structure

10377-66-9 Structure
IdentificationMore
[Name]

Manganese nitrate
[CAS]

10377-66-9
[Synonyms]

manganese dinitrate
MANGANESE ICP STANDARD, MN(NO3)2
MANGANESE(II) NITRATE
MANGANESE NITRATE
MANGANOUS NITRATE
MN(NO3)2
manganese(2+)nitrate
manganese(ii)nitrate,anhydrous
manganese(II)nitrate,NitricAcid,Manganese(2+)Salt
Manganesenitrate,50%solution
manganousdinitrate
Nitricacid,manganese(2+)salt
nitricacid,manganese(2++)salt
Manganese ion chromatography standard solution Fluka
Manganese nitrate aqueous solution pinkliq
Manganese(II) nitrate solution
MANGANESE ION CHROMATOGRAPHY STD SOL. FL UKA, IN H2O, STAB.
MANGANESE(II) NITRATE, 45-50 WT. % SOLUT ION IN DILUTE NITRIC ACID
MANGANESE NITRATE 50% SOLUTION, FOR ANALYTICAL PURPOSE
Manganese(Ⅱ)nitrate hexahydrate
[EINECS(EC#)]

233-828-8
[Molecular Formula]

MnN2O6
[MDL Number]

MFCD00011112
[Molecular Weight]

178.95
[MOL File]

10377-66-9.mol
Chemical PropertiesBack Directory
[Melting point ]

37°C
[Boiling point ]

100°C
[density ]

1.536 g/mL at 25 °C
[vapor pressure ]

0Pa at 20℃
[RTECS ]

QU9780000
[solubility ]

very soluble in ethanol
[form ]

Liquid
[color ]

Pink
[Specific Gravity]

1.5
[Water Solubility ]

soluble
[Merck ]

13,5756
[Exposure limits]

ACGIH: TWA 0.02 mg/m3; TWA 0.1 mg/m3
OSHA: Ceiling 5 mg/m3
NIOSH: IDLH 500 mg/m3; TWA 1 mg/m3; STEL 3 mg/m3
[InChI]

1S/Mn.2NO3/c;2*2-1(3)4/q+2;2*-1
[InChIKey]

MIVBAHRSNUNMPP-UHFFFAOYSA-N
[SMILES]

[Mn++].[O-][N+]([O-])=O.[O-][N+]([O-])=O
[Uses]

Ceramics, intermediates, catalyst, manganese dioxide.
[CAS DataBase Reference]

10377-66-9(CAS DataBase Reference)
[EPA Substance Registry System]

10377-66-9(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Flame Over Circle (GHS03)Skull and Crossbones (GHS06)Corrosion (GHS05)Exclamation Mark (GHS07)Health Hazard (GHS08)
GHS03,GHS06,GHS05,GHS07,GHS08
[Signal word ]

Danger
[Hazard statements ]

H302-H314-H318-H373-H402-H412-H272-H315-H319-H331
[Precautionary statements ]

P220-P261-P305+P351+P338-P311-P210a-P221-P303+P361+P353-P405-P501a
[Hazard Codes ]

O,C
[Risk Statements ]

R8:Contact with combustible material may cause fire.
R34:Causes burns.
R40:Limited evidence of a carcinogenic effect.
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S17:Keep away from combustible material .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S27:Take off immediately all contaminated clothing .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36:Wear suitable protective clothing .
[RIDADR ]

UN 3264 8/PG 3
[WGK Germany ]

1
[TSCA ]

Yes
[REACH Registrations]

Active
[HazardClass ]

5.1
[PackingGroup ]

III
[HS Code ]

28342990
[Storage Class]

5.1B - Oxidizing hazardous materials
[Hazard Classifications]

Acute Tox. 4 Oral
Eye Dam. 1
Met. Corr. 1
Ox. Liq. 2
Skin Corr. 1C
STOT RE 2 Inhalation
[Safety Profile]

Mutation data reported. When heated to decomposition it emits toxic vapors of manganese.
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Nitric acid-->Manganese carbonate-->Manganese
[Preparation Products]

Manganese dioxide-->Deprodone propionate-->Lithium manganese oxide-->Manganese(II) nitrate tetrahydrate
Hazard InformationBack Directory
[General Description]

A white crystalline solid. Denser than water. May ignite on contact with organic matter. Contact may irritate skin, eyes and mucous membranes. May be toxic by ingestion. Used to make other chemicals.
[Reactivity Profile]

Mixtures of metal/nonmetal nitrates with alkyl esters may explode, owing to the formation of alkyl nitrates; mixtures of nitrate with phosphorus, tin (II) chloride, or other reducing agents may react explosively [Bretherick 1979. p. 108-109]. The anhydrous nitrate salt with urea explodes upon heating, [Chem Abs., 1975, 82, 48151].
[Air & Water Reactions]

Soluble in water.
[Hazard]

Fire and explosion risk in contact with organic materials.
[Health Hazard]

Inhalation, ingestion or contact (skin, eyes) with vapors or substance may cause severe injury, burns or death. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may cause pollution.
[Fire Hazard]

These substances will accelerate burning when involved in a fire. Some may decompose explosively when heated or involved in a fire. May explode from heat or contamination. Some will react explosively with hydrocarbons (fuels). May ignite combustibles (wood, paper, oil, clothing, etc.). Containers may explode when heated. Runoff may create fire or explosion hazard.
[Description]

Manganese nitrate is a colorless to pink crystalline solid. Molecular weight= 178.96. Hazard Identification (based on NFPA-704 M Rating System): Health 3, Flammability 0, Reactivity 3 (Oxidizer). Highly soluble in water.
[Chemical Properties]

Light red liquid
[Potential Exposure]

Manganese nitrate is used as a color agent in porcelain and ceramic manufacture, as a catalyst, and in the production of manganese dioxide.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit. Medical observation is recommended for 2448 h after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a corticosteroid spray.
[storage]

Color Code—Yellow: Reactive Hazard (strong oxidizer); Store in a location separate from other materials, especially flammables and combustibles. Prior to working with this chemical you should be trained on its proper handling and storage. Manganese nitrate must be stored to avoid contact with organic materials since violent reactions occur. Store in tightly closed containers in a cool, well-ventilated area. Where possible, automatically transfer material from drums or other storage containers to process containers. See OSHA Standard 1910.104 and NFPA 43A Code for the Storage of Liquid and Solid Oxidizers for detailed handling and storage regulations.
[Shipping]

This compound requires a shipping label of “OXIDIZER.” It falls in Hazard Class 5.1 and Packing Group III.
[Incompatibilities]

A strong oxidizer. Violent reaction with reducing agents, organics, and combustible materials.
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Manganese dinitrate(10377-66-9).msds
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Manganese(II) nitrate, 50% w/w aq. soln.(10377-66-9)
[Sigma Aldrich]

10377-66-9(sigmaaldrich)
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