| Identification | More | [Name]
3-BROMOCHLOROBENZENE | [CAS]
108-37-2 | [Synonyms]
1-BROMO-3-CHLOROBENZENE
3-BROMOCHLOROBENZENE
M-BROMOCHLOROBENZENE
M-CHLOROBROMOBENZENE
1-bromo-3-chloro-benzen
1-Chloro-3-bromobenzene
3-Bromo-1-chlorobenzene
3-Chlorobromobenzene
3-Chlorophenyl bromide
3-chlorophenylbromide
Benzene, 1-bromo-3-chloro-
benzene,1-bromo-3-chloro-
m-Bromophenyl chloride
m-bromophenylchloride
m-Chlorophenyl bromide
m-chlorophenylbromide
3-BROMOCHLOROBENZENE 99%
3-Bromochlorobenzene/1-Bromo-3-chlorobenzene
Bromochlorobenzene, m- | [EINECS(EC#)]
203-575-8 | [Molecular Formula]
C6H4BrCl | [MDL Number]
MFCD00000568 | [Molecular Weight]
191.45 | [MOL File]
108-37-2.mol |
| Chemical Properties | Back Directory | [Appearance]
CLEAR COLOURLESS TO LIGHT YELLOW LIQUID | [Melting point ]
-21.5 °C
| [Boiling point ]
196 °C(lit.)
| [density ]
1.63 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.576(lit.)
| [Fp ]
177 °F
| [storage temp. ]
Sealed in dry,Room Temperature | [form ]
Liquid | [color ]
Clear colorless to light yellow | [Specific Gravity]
1.630 | [Water Solubility ]
Insoluble | [BRN ]
1446353 | [Dielectric constant]
4.5 | [InChI]
1S/C6H4BrCl/c7-5-2-1-3-6(8)4-5/h1-4H | [InChIKey]
JRGGUPZKKTVKOV-UHFFFAOYSA-N | [SMILES]
Clc1cccc(Br)c1 | [CAS DataBase Reference]
108-37-2(CAS DataBase Reference) | [NIST Chemistry Reference]
3-Chlorobromobenzene(108-37-2) | [EPA Substance Registry System]
108-37-2(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [WGK Germany ]
3
| [RTECS ]
CY9005000
| [Hazard Note ]
Irritant | [TSCA ]
Yes | [HS Code ]
29039990 | [Storage Class]
10 - Combustible liquids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2 |
| Hazard Information | Back Directory | [Chemical Properties]
CLEAR COLOURLESS TO LIGHT YELLOW LIQUID | [Uses]
1-Bromo-3-chlorobenzene undergoes bromine-magnesium exchange reactions with i-PrMgCl-LiCl in THF at 0°C and is strongly accelerated by electron-withdrawing substituents. It acts as test substrate to study the application of a new catalytic system for cyanation of various aryl halides using K4[Fe(CN)6] as cyanating source. | [Synthesis Reference(s)]
The Journal of Organic Chemistry, 52, p. 664, 1987 DOI: 10.1021/jo00380a031 | [General Description]
1-Bromo-3-chlorobenzene undergoes bromine-magnesium exchange reactions with i-PrMgCl-LiCl in THF at 0°C and is strongly accelerated by electron-withdrawing substituents. It acts as test substrate to study the application of a new catalytic system for cyanation of various aryl halides using K4[Fe(CN)6] as cyanating source. | [Synthesis]
Taking m-chloroaniline as raw material, mixed with concentrated hydrobromic acid, make the temperature drop to 0 ℃, under stirring, quickly add sodium nitrite aqueous solution, make o-chloroaniline nitrogenation, to produce diazonium salts, in the process |
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