ChemicalBook--->CAS DataBase List--->108-37-2

108-37-2

108-37-2 Structure

108-37-2 Structure
IdentificationMore
[Name]

3-BROMOCHLOROBENZENE
[CAS]

108-37-2
[Synonyms]

1-BROMO-3-CHLOROBENZENE
3-BROMOCHLOROBENZENE
M-BROMOCHLOROBENZENE
M-CHLOROBROMOBENZENE
1-bromo-3-chloro-benzen
1-Chloro-3-bromobenzene
3-Bromo-1-chlorobenzene
3-Chlorobromobenzene
3-Chlorophenyl bromide
3-chlorophenylbromide
Benzene, 1-bromo-3-chloro-
benzene,1-bromo-3-chloro-
m-Bromophenyl chloride
m-bromophenylchloride
m-Chlorophenyl bromide
m-chlorophenylbromide
3-BROMOCHLOROBENZENE 99%
3-Bromochlorobenzene/1-Bromo-3-chlorobenzene
Bromochlorobenzene, m-
[EINECS(EC#)]

203-575-8
[Molecular Formula]

C6H4BrCl
[MDL Number]

MFCD00000568
[Molecular Weight]

191.45
[MOL File]

108-37-2.mol
Chemical PropertiesBack Directory
[Appearance]

CLEAR COLOURLESS TO LIGHT YELLOW LIQUID
[Melting point ]

-21.5 °C
[Boiling point ]

196 °C(lit.)
[density ]

1.63 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.576(lit.)
[Fp ]

177 °F
[storage temp. ]

Sealed in dry,Room Temperature
[form ]

Liquid
[color ]

Clear colorless to light yellow
[Specific Gravity]

1.630
[Water Solubility ]

Insoluble
[BRN ]

1446353
[Dielectric constant]

4.5
[InChI]

1S/C6H4BrCl/c7-5-2-1-3-6(8)4-5/h1-4H
[InChIKey]

JRGGUPZKKTVKOV-UHFFFAOYSA-N
[SMILES]

Clc1cccc(Br)c1
[CAS DataBase Reference]

108-37-2(CAS DataBase Reference)
[NIST Chemistry Reference]

3-Chlorobromobenzene(108-37-2)
[EPA Substance Registry System]

108-37-2(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319
[Precautionary statements ]

P264-P280-P302+P352-P305+P351+P338-P332+P313-P337+P313
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[WGK Germany ]

3
[RTECS ]

CY9005000
[Hazard Note ]

Irritant
[TSCA ]

Yes
[HS Code ]

29039990
[Storage Class]

10 - Combustible liquids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
Raw materials And Preparation ProductsBack Directory
[Preparation Products]

1-(3-Chlorophenyl)-1-ethanol-->1-(3-Chlorphenyl)piperazine-->INDANOFAN-->2,7-Dichlorofluorene-->1-Chloro-3-ethylbenzene-->3-Chlorophenylboronic acid, pinacol ester-->3-Chloro-N-methylaniline-->Methyl 3-chlorobenzoate-->2,3'-Dichloroacetophenone-->3-Chlorophenyl cyclopropyl ketone-->3-Cyclopropyl-benzeneboronic acid -->1-Bromo-3-chloro-5-iodobenzene-->Dimethyl isophthalate
Hazard InformationBack Directory
[Chemical Properties]

CLEAR COLOURLESS TO LIGHT YELLOW LIQUID
[Uses]

1-Bromo-3-chlorobenzene undergoes bromine-magnesium exchange reactions with i-PrMgCl-LiCl in THF at 0°C and is strongly accelerated by electron-withdrawing substituents. It acts as test substrate to study the application of a new catalytic system for cyanation of various aryl halides using K4[Fe(CN)6] as cyanating source.
[Synthesis Reference(s)]

The Journal of Organic Chemistry, 52, p. 664, 1987 DOI: 10.1021/jo00380a031
[General Description]

1-Bromo-3-chlorobenzene undergoes bromine-magnesium exchange reactions with i-PrMgCl-LiCl in THF at 0°C and is strongly accelerated by electron-withdrawing substituents. It acts as test substrate to study the application of a new catalytic system for cyanation of various aryl halides using K4[Fe(CN)6] as cyanating source.
[Synthesis]

Taking m-chloroaniline as raw material, mixed with concentrated hydrobromic acid, make the temperature drop to 0 ℃, under stirring, quickly add sodium nitrite aqueous solution, make o-chloroaniline nitrogenation, to produce diazonium salts, in the process
Spectrum DetailBack Directory
[Spectrum Detail]

3-BROMOCHLOROBENZENE(108-37-2)MS
3-BROMOCHLOROBENZENE(108-37-2)1HNMR
3-BROMOCHLOROBENZENE(108-37-2)13CNMR
3-BROMOCHLOROBENZENE(108-37-2)IR1
3-BROMOCHLOROBENZENE(108-37-2)IR2
3-BROMOCHLOROBENZENE(108-37-2)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

3-Bromochlorobenzene, 99%(108-37-2)
[Alfa Aesar]

1-Bromo-3-chlorobenzene, 99%(108-37-2)
[Sigma Aldrich]

108-37-2(sigmaaldrich)
[TCI AMERICA]

3-Bromochlorobenzene,>99.0%(GC)(108-37-2)
108-37-2 suppliers list
Company Name: Changzhow Moisten International Trading Co., Ltd.  Gold
Telephone: 13606112397
Website: gtnchem.com/
Company Name: NanJing JingWei Chemical Co., Ltd.  Gold
Telephone: 13270709979
Website: http://www.njjwchem.com/
Company Name: Changzhou Hongda New Material Technology Co., Ltd.  Gold
Telephone: 15262235181
Website:
Company Name: Panjin Greenchem Technology Co., Ltd.  Gold
Telephone: 13121959385
Website:
Company Name: Sanjing New Materials Technology (Taizhou) Co., Ltd.  Gold
Telephone: 13852622638
Website: www.sanjingchem.com/
Company Name: Yancheng Longxinghong Industry and Trade Co., Ltd  Gold
Telephone: 88710281 13921881287
Website: www.longxinghong.com/index.html
Company Name: J & K SCIENTIFIC LTD.  
Telephone: 18210857532 18210857532
Website: https://www.jkchemical.com
Company Name: Meryer (Shanghai) Chemical Technology Co., Ltd.  
Telephone: 4006356688 18621169109
Website: www.x-labseek.com/
Company Name: future industrial shanghai co., ltd  
Telephone: 400-0066400 13621662912
Website: http://www.jonln.com
Company Name: Alfa Aesar  
Telephone: 400-6106006
Website: http://chemicals.thermofisher.cn
Company Name: TCI (Shanghai) Development Co., Ltd.  
Telephone: 021-67121386
Website: https://www.tcichemicals.com/CN/zh/
Company Name: ShangHai DEMO Chemical Co.,Ltd  
Telephone: 400-021-7337 2355568890
Website: www.demochem.com
Company Name: Beijing HwrkChemical Technology Co., Ltd  
Telephone: 89508211 18501085097
Website: http://www.hwrkchemical.com
Company Name: Energy Chemical  
Telephone: 400-0056266
Website: www.energy-chemical.com
Company Name: Shijiazhuang Sdyano Fine Chemical Co., Ltd.  
Telephone: 0311-89250318 13582355795
Website: www.sdynchem.com
Company Name: Wuhan Chemwish Technology Co., Ltd  
Telephone: 86-027-67849912
Website: www.chemwish.com
Company Name: Capot Chemical Co., Ltd  
Telephone: +86 (0) 571 85 58 67 18
Website: www.capotchem.com
Company Name: Beijing Ouhe Technology Co., Ltd  
Telephone: 13552068683 13522913783
Website: www.ouhetech.cn/
Tags:108-37-2 Related Product Information
402-23-3 585-76-2 121-92-6 98-17-9 99-04-7 151-10-0 121-89-1 54060-30-9 1073-06-9 620-20-2 18282-59-2 695-96-5 697-86-9 3460-24-0 874-18-0 98041-69-1 99-29-6 56961-77-4