| Identification | More | [Name]
Fmoc-D-Asparagine | [CAS]
108321-39-7 | [Synonyms]
9-FLUORENYLMETHOXYCARBONYL-D-ASPARAGINE
FMOC-D-ASN
FMOC-D-ASN-OH
FMOC-D-ASPARAGINE
N-(9-FLUORENYLMETHOXYCARBONYL)-D-ASPARAGINE
N-ALPHA-(9-FLUORENYLMETHOXYCARBONYL)-D-ASPARAGINE
N-ALPHA-(9-FLUORENYLMETHYLOXYCARBONYL)-D-ASPARAGINE
NALPHA-[(9H-FLUOREN-9-YLMETHOXY)CARBONYL]-D-ASPARAGINE
N-ALPHA-FMOC-D-ASPARAGINE
N-α-Fmoc-D-asparagine
2-(((9H-fluoren-9-yl)methoxy)carbonylamino)-5-amino-5-oxopentanoic acid
FMOC-D-ASPARGINE extrapure
9-fluorenylmethyloxycarbonyl-D-asparagine hydroxide | [EINECS(EC#)]
1533716-785-6 | [Molecular Formula]
C19H18N2O5 | [MDL Number]
MFCD00062956 | [Molecular Weight]
354.36 | [MOL File]
108321-39-7.mol |
| Chemical Properties | Back Directory | [Appearance]
white to light yellow crystal powde | [Melting point ]
~185 °C (dec.) | [alpha ]
11.9 º (c=1%, DMF) | [Boiling point ]
678.6±55.0 °C(Predicted) | [density ]
1.362±0.06 g/cm3(Predicted) | [refractive index ]
12 ° (C=1, DMF) | [storage temp. ]
2-8°C
| [solubility ]
Soluble in water or 1% acetic acid | [form ]
powder to crystal | [pka]
3.68±0.10(Predicted) | [color ]
White to Almost white | [Optical Rotation]
[α]20/D +11.9±1.5°, c = 1% in DMF | [BRN ]
8510210 | [InChI]
InChI=1S/C19H18N2O5/c20-17(22)9-16(18(23)24)21-19(25)26-10-15-13-7-3-1-5-11(13)12-6-2-4-8-14(12)15/h1-8,15-16H,9-10H2,(H2,20,22)(H,21,25)(H,23,24)/t16-/m1/s1 | [InChIKey]
YUGBZNJSGOBFOV-MRXNPFEDSA-N | [SMILES]
C(O)(=O)[C@@H](CC(N)=O)NC(OCC1C2=C(C=CC=C2)C2=C1C=CC=C2)=O | [CAS DataBase Reference]
108321-39-7(CAS DataBase Reference) |
| Hazard Information | Back Directory | [Chemical Properties]
white to light yellow crystal powde | [Uses]
Nα-Fmoc-D-asparagine is an N-Fmoc-protected form of D-Asparagine (A788990). D-Asparagine is an isomer of L-Asparagine (A790005) and is used by bacteria (such as Saccharomyces cerevisiae) as a sole nitrogen source for replication. L-Asparagine is also a competitive inhibitor of staphylococcal L-asparaginase and is used as a reagent to synthesize peptide antibiotics. | [reaction suitability]
reaction type: Fmoc solid-phase peptide synthesis |
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