| Identification | More | [Name]
Methylenaminoacetonitrile | [CAS]
109-82-0 | [Synonyms]
ALPHA-HYDROFORMAMINE CYANIDE
METHYLENAMINOACETONITRILE
METHYLENEAMINOACETONITRILE
METHYLENEGLYCINONITRILE
METHYLENEIMINOACETONITRILE
N-Methylenaminoacetonitrile
(methyleneamino)-acetonitril
Glycinonitrile, n-methylene-
-Hydroformaminecyanide
maan
methyleniminoacetonitrile
n-methylene-glycinonitril
usafdo-5
METHLYENEIMINOACETONITRILE
3-Aminoacetonitrile
(METHYLENEAMINO)ACETONITRILE 98+% | [EINECS(EC#)]
203-709-5 | [Molecular Formula]
C3H4N2 | [MDL Number]
MFCD00001889 | [Molecular Weight]
68.08 | [MOL File]
109-82-0.mol |
| Chemical Properties | Back Directory | [Appearance]
WHITE CRYSTALS | [Melting point ]
127-130 °C | [Boiling point ]
106.45°C (rough estimate) | [density ]
0.8765 (rough estimate) | [refractive index ]
1.4089 (estimate) | [solubility ]
slightly sol. in Benzene | [form ]
powder to crystal | [pka]
3.30±0.50(Predicted) | [color ]
White to Almost white | [Merck ]
14,6057 | [BRN ]
1848155 | [Exposure limits]
NIOSH: IDLH 25 mg/m3 | [InChI]
InChI=1S/C3H4N2/c1-5-3-2-4/h1,3H2 | [InChIKey]
GFZMFCVDDFHSJK-UHFFFAOYSA-N | [SMILES]
C(#N)CN=C | [CAS DataBase Reference]
109-82-0(CAS DataBase Reference) | [NIST Chemistry Reference]
Methyleneaminoacetonitrile(109-82-0) | [EPA Substance Registry System]
109-82-0(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . | [Safety Statements ]
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S22:Do not breathe dust . | [RTECS ]
MC1925000 | [TSCA ]
Yes | [HS Code ]
2926.90.5050 |
| Hazard Information | Back Directory | [Chemical Properties]
WHITE CRYSTALS | [Uses]
Methylenaminoacetonitrile can be used as a precursor in organic synthesis.
| [Preparation]
Methylenaminoacetonitrile can be prepared by the action of formaldehyde on a mixture of ammonium chloride, potassium cyanide, and acetic acid, and by the action of formaldehyde on aminoacetonitrile.
| [Purification Methods]
Crystallise MAAN from EtOH or acetone. It crystallises nicely from H2O but with considerable loss of material. It is an inhibitor of bone growth. [Adams & Langley Org Synth Coll Vol I 355 1941.] |
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