ChemicalBook--->CAS DataBase List--->109-82-0

109-82-0

109-82-0 Structure

109-82-0 Structure
IdentificationMore
[Name]

Methylenaminoacetonitrile
[CAS]

109-82-0
[Synonyms]

ALPHA-HYDROFORMAMINE CYANIDE
METHYLENAMINOACETONITRILE
METHYLENEAMINOACETONITRILE
METHYLENEGLYCINONITRILE
METHYLENEIMINOACETONITRILE
N-Methylenaminoacetonitrile
(methyleneamino)-acetonitril
Glycinonitrile, n-methylene-
-Hydroformaminecyanide
maan
methyleniminoacetonitrile
n-methylene-glycinonitril
usafdo-5
METHLYENEIMINOACETONITRILE
3-Aminoacetonitrile
(METHYLENEAMINO)ACETONITRILE 98+%
[EINECS(EC#)]

203-709-5
[Molecular Formula]

C3H4N2
[MDL Number]

MFCD00001889
[Molecular Weight]

68.08
[MOL File]

109-82-0.mol
Chemical PropertiesBack Directory
[Appearance]

WHITE CRYSTALS
[Melting point ]

127-130 °C
[Boiling point ]

106.45°C (rough estimate)
[density ]

0.8765 (rough estimate)
[refractive index ]

1.4089 (estimate)
[solubility ]

slightly sol. in Benzene
[form ]

powder to crystal
[pka]

3.30±0.50(Predicted)
[color ]

White to Almost white
[Merck ]

14,6057
[BRN ]

1848155
[Exposure limits]

NIOSH: IDLH 25 mg/m3
[InChI]

InChI=1S/C3H4N2/c1-5-3-2-4/h1,3H2
[InChIKey]

GFZMFCVDDFHSJK-UHFFFAOYSA-N
[SMILES]

C(#N)CN=C
[CAS DataBase Reference]

109-82-0(CAS DataBase Reference)
[NIST Chemistry Reference]

Methyleneaminoacetonitrile(109-82-0)
[EPA Substance Registry System]

109-82-0(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S22:Do not breathe dust .
[RTECS ]

MC1925000
[TSCA ]

Yes
[HS Code ]

2926.90.5050
Raw materials And Preparation ProductsBack Directory
[Preparation Products]

Glycine-->Aminoacetonitrile
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

N-Methylenaminoacetonitrile(109-82-0).msds
Hazard InformationBack Directory
[Chemical Properties]

WHITE CRYSTALS
[Uses]

Methylenaminoacetonitrile can be used as a precursor in organic synthesis.
[Preparation]

Methylenaminoacetonitrile can be prepared by the action of formaldehyde on a mixture of ammonium chloride, potassium cyanide, and acetic acid, and by the action of formaldehyde on aminoacetonitrile.
Methylenaminoacetonitrile synthesis route
[Purification Methods]

Crystallise MAAN from EtOH or acetone. It crystallises nicely from H2O but with considerable loss of material. It is an inhibitor of bone growth. [Adams & Langley Org Synth Coll Vol I 355 1941.]
Spectrum DetailBack Directory
[Spectrum Detail]

Methylenaminoacetonitrile(109-82-0)MS
Methylenaminoacetonitrile(109-82-0)1HNMR
Methylenaminoacetonitrile(109-82-0)IR1
Methylenaminoacetonitrile(109-82-0)IR2
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Methyleneiminoacetonitrile, 98%(109-82-0)
[Sigma Aldrich]

109-82-0(sigmaaldrich)
[TCI AMERICA]

(Methyleneamino)acetonitrile,>98.0%(N)(109-82-0)
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