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110-68-9

110-68-9 Structure

110-68-9 Structure
IdentificationMore
[Name]

N-METHYLBUTYLAMINE
[CAS]

110-68-9
[Synonyms]

N-BUTYLMETHYLAMINE
N-METHYLBUTYLAMINE
N-METHYL-N-BUTYLAMINE
N-N-BUTYLMETHYLAMINE
1-Butanamine,N-methyl-
Butylamine, N-methyl-
Butylamine,N-methyl-
Butylmethylamine
Methylaminobutane
Methylbutylamine
Methyl-N-butylamine
N-Butylmethylamin
N-Butyl-N-methylamine
n-methyl-1-butanamin
N-Methyl-1-butanamine
N-Methylbutanamine
N-Methylbutylamin
n-methyl-butylamin
N-Methyl-1-butylamine
N-Methyl-1-butaneamine
[EINECS(EC#)]

203-791-2
[Molecular Formula]

C5H13N
[MDL Number]

MFCD00009426
[Molecular Weight]

87.16
[MOL File]

110-68-9.mol
Chemical PropertiesBack Directory
[Appearance]

Butyl amines are highly flammable, colorless liquids (n-turns yellow on standing) with ammoniacal or fishlike odors. n-isomer:
[Appearance]

CLEAR COLOURLESS LIQUID
[mp ]

-75 °C
[bp ]

90.5-91.5 °C(lit.)
[density ]

0.736 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.3995(lit.)
[Fp ]

35 °F
[storage temp. ]

Flammables area
[BRN ]

1209231
[Uses]

Intermediate.
[CAS DataBase Reference]

110-68-9(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

F,C
[Risk Statements ]

R11:Highly Flammable.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R34:Causes burns.
[Safety Statements ]

S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 2945 3/PG 2
[WGK Germany ]

3
[RTECS ]

EO5250000
[HazardClass ]

3
[PackingGroup ]

II
[HS Code ]

29211999
[Safety Profile]

Poison by intravenous route. Moderately toxic by ingestion, skin contact, and intraperitoneal routes. Mildly toxic by inhalation. A skin and severe eye irritant. Flammable liquid when exposed to heat, sparks, or flame. To fight fire, use alcohol foam. When heated to decomposition it emits toxic fumes of NOx. See also AMINES.
Hazard InformationBack Directory
[General Description]

A water-white liquid with an ammonia-like odor. Density 0.736 g/cm3 and flash point 35°F (Aldrich) .Vapors heavier than air. Used to make other chemicals.
[Reactivity Profile]

N-METHYLBUTYLAMINE(110-68-9) neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.
[Air & Water Reactions]

Highly flammable. Slightly soluble in water.
[Hazard]

Flammable, dangerous fire risk.
[Health Hazard]

May cause toxic effects if inhaled or ingested/swallowed. Contact with substance may cause severe burns to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
[Potential Exposure]

Alert: (n-isomer): Possible risk of forming tumors, suspected of causing genetic defects, suspected reprotoxic hazard, Primary irritant (w/o allergic reaction), (sec-isomer): Drug. n-Butylamine is used in pharmaceuticals; dyestuffs, rubber, chemicals, emulsifying agents; photography, desizing agents for textiles; pesticides, and synthetic agents. sec-Butylamine is used as a fungistate. tert-Butylamine is used as a chemical intermediate in the production of tert-Butylaminoethyl methacrylate (a lube oil additive); as an intermediate in the production of rubber and in rust preventatives and emulsion deterrents in petroleum products. It is used in the manufacture of several drugs
[Fire Hazard]

Flammable/combustible material. May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Rinse out mouth and do not induce vomiting. Medical observation is recommended for 24 to 48 hours after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a drug or other inhalation therapy
[Shipping]

UN1125 n-Butylamine, Hazard Class: 3; Labels: 3—Flammable liquid, 8—Corrosive material. UN2014 Isobutylamine, Hazard Class: 3; Labels: 3—Flammable liquid, 8—Corrosive material
[Incompatibilities]

May form explosive mixture with air. May accumulate static electrical charges, and may causeignition of its vapors. n-Butylamine is a weak base; reacts with strong oxidizers and acids, causing fire and explosion hazard. Incompatible with organic anhydrides; isocyanates, vinyl acetate; acrylates, substituted allyls; alkylene oxides; epichlorohydrin, ketones, aldehydes, alcohols, glycols, phenols, cresols, caprolactum solution. Attacks some metals in presence of moisture. The tert-isomer will attack some forms of plastics
[Waste Disposal]

Use a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner andscrubber. All federal, state, and local environmental regulations must be observed.
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

N-methyl butylamine(110-68-9).msds
Spectrum DetailBack Directory
[Spectrum Detail]

N-METHYLBUTYLAMINE(110-68-9) 1H NMR
N-METHYLBUTYLAMINE(110-68-9) IR1
N-METHYLBUTYLAMINE(110-68-9) IR2
N-METHYLBUTYLAMINE(110-68-9) MS
N-METHYLBUTYLAMINE(110-68-9) 13C NMR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

N-Methylbutylamine, 98%(110-68-9)
[Alfa Aesar]

N-Methyl-1-butylamine, 98%(110-68-9)
[Sigma Aldrich]

110-68-9(sigmaaldrich)
[TCI AMERICA]

N-Methylbutylamine,>90.0%(GC)(110-68-9)
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