ChemicalBook--->CAS DataBase List--->111-75-1

111-75-1

111-75-1 Structure

111-75-1 Structure
IdentificationMore
[Name]

2-(BUTYLAMINO)ETHANOL
[CAS]

111-75-1
[Synonyms]

2-(BUTYLAMINO)ETHANOL
ETHANOL-N-BUTYLAMINE
N-BUTYL-2-HYDROXYETHYLAMINE
N-BUTYLETHANOLAMINE
N-N-BUTYLETHANOLAMINE
2-(butylamino)-ethano
2-(n-butylamino)ethanol
2-(n-monobutylamino)ethanol
2-butylamino-ethano
2-n-Butylaminoethanol
butyl(2-hydroxyethyl)amine
butylethanalamine
Butylethanolamine
Butylmonoethanolamine
N-Butyl monoethanolamine
n-Butylaminoethanol
Buthylethanolamine
N-n-Buthylethanolamine
2-(BUTYLAMINO)ETHANOL, 98+%
N-ButylEthanolamine(N-Bea)
[EINECS(EC#)]

203-904-5
[Molecular Formula]

C6H15NO
[MDL Number]

MFCD00020570
[Molecular Weight]

117.19
[MOL File]

111-75-1.mol
Chemical PropertiesBack Directory
[Melting point ]

28.94°C (estimate)
[Boiling point ]

198-200 °C(lit.)
[density ]

0.891 g/mL at 25 °C(lit.)
[vapor pressure ]

13.94Pa at 20℃
[refractive index ]

n20/D 1.444(lit.)
[Fp ]

170 °F
[storage temp. ]

2-8°C
[solubility ]

1000g/l
[form ]

clear liquid
[pka]

14.81±0.10(Predicted)
[color ]

Colorless to Almost colorless
[Specific Gravity]

0.893
[PH]

11.9 (100g/l, H2O, 20℃)
[biological source]

goat
[explosive limit]

1.5-8.6%(V)
[Water Solubility ]

1000g/L at 20℃
[BRN ]

1732522
[Cosmetics Ingredients Functions]

BUFFERING
[InChI]

1S/C6H15NO/c1-2-3-4-7-5-6-8/h7-8H,2-6H2,1H3
[InChIKey]

LJDSTRZHPWMDPG-UHFFFAOYSA-N
[SMILES]

CCCCNCCO
[LogP]

0.64 at 25℃
[CAS DataBase Reference]

111-75-1(CAS DataBase Reference)
[EPA Substance Registry System]

Ethanol, 2-(butylamino)- (111-75-1)
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)Exclamation Mark (GHS07)
GHS05,GHS07
[Signal word ]

Danger
[Hazard statements ]

H302-H314
[Precautionary statements ]

P280-P301+P312+P330-P303+P361+P353-P305+P351+P338+P310
[Hazard Codes ]

C
[Risk Statements ]

R22:Harmful if swallowed.
R34:Causes burns.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 2735 8/PG 2
[WGK Germany ]

1
[RTECS ]

KK0175000
[TSCA ]

TSCA listed
[REACH Registrations]

Active
[HazardClass ]

8
[PackingGroup ]

II
[HS Code ]

29221990
[Storage Class]

8A - Combustible corrosive hazardous materials
[Hazard Classifications]

Acute Tox. 4 Oral
Eye Dam. 1
Skin Corr. 1B
[Safety Profile]

Moderately toxic by ingestion and intraperitoneal routes. A skin and severe eye irritant. See also AMINES. Combustible when exposed to heat or flame. To fight fire, use alcohol foam, foam, Con, dry chemical. Incompatible with oxihzing materials. When heated to decomposition it emits toxic fumes of NOx
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Petroleum ether-->Potassium hydroxide-->Monoethanolamine-->1-Bromobutane
Hazard InformationBack Directory
[Description]

2-(butylamino)ethanol (BAE) is a secondary amine and has steric hindrance with a strong tendency to form bicarbonate on reaction with CO2. As a result, equilibrium CO2 loading can exceed 0.5 mol CO2/mol amine, resulting in higher cyclic capacity than conventional MEA. BAE's hydrophobicity is very high and highly soluble with most amines and ethers. The advantages of preferring BAE over traditional 2-amino-2-methyl-1-propanol (AMP) are that BAE does not produce solid precipitation on CO2 loading, CO2 absorption and reaction rate of BAE is higher than AMP, it can be regenerated at low temperature, low heat of CO2 absorption and BAE is cheaper than AMP[1].
[Chemical Properties]

Colorless liquid
[Uses]

2-(Butylamino)ethanol (N-Butylethanolamine) may be employed for the synthesis of 4-alkylamino-2,5,6-trimethyl -7-(2,4,6-trimethylphenyl)pyrrolo[2,3-d]pyrimidines and N-butyl-N-(2-nitroxyethyl)nitramine (BuNENA).
[General Description]

2-(Butylamino)ethanol is a secondary amine having a -OH group.
[Synthesis]

To a solution of 3-aminopropan-1-ol (1.0 g, 13.3 mmol) and propionaldehyde (0.77 g, 13.3 mmol) in MeOH (20 mL) was added MgSO4 (6.4 g, 53.3 mmol). The reaction mixture was stirred at 25 °C for 12 h. The undissolved material was filtered and the filtrate w
[Toxics Screening Level]

The Initial Risk Screening Level (ITSL) for 2-Butylaminoethanol is 4 μg/m3 based on annual averaging time.
[References]

[1] Ashish Gautam, Monoj Kumar Mondal. “Novel aqueous amine blend of 2-(Butylamino)ethanol and 2-Dimethylaminoethanol for CO2 capture: Equilibrium CO2 loading, RSM optimization, desorption study, characterization and toxicity assessment.” Separation and Purification Technology 322 (2023): Article 124279.
Spectrum DetailBack Directory
[Spectrum Detail]

2-(BUTYLAMINO)ETHANOL(111-75-1)MS
2-(BUTYLAMINO)ETHANOL(111-75-1)1HNMR
2-(BUTYLAMINO)ETHANOL(111-75-1)13CNMR
2-(BUTYLAMINO)ETHANOL(111-75-1)IR1
2-(BUTYLAMINO)ETHANOL(111-75-1)IR2
2-(BUTYLAMINO)ETHANOL(111-75-1)Raman
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

111-75-1(sigmaaldrich)
[TCI AMERICA]

2-(Butylamino)ethanol,>98.0%(GC)(T)(111-75-1)
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