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1723-00-8

1723-00-8 Structure

1723-00-8 Structure
IdentificationMore
[Name]

D(+)-Pipecolinic acid
[CAS]

1723-00-8
[Synonyms]

2-PIPERIDINECARBOXYLIC ACID, (S)-
(2S)-(-)-PIPECOLINIC ACID
H-HOMOPRO-OH
H-HOPRO-OH
H-L-PIP-OH
HOMOPROLINE
H-PIC(2)-OH
H-PIPERIDINE-2-CARBOXYLIC ACID
L-2-PIPERIDINECARBOXYLIC ACID
L-HOMOPRO
L-HOMOPROLINE
L-PIPECOLIC ACID
(L)-PIPECOLIC ACIDS
(-)-L-PIPECOLINIC ACID
L-(-)-PIPECOLINIC ACID
L-PIPECOLINIC ACID
PIP-OH
RARECHEM BK PT F201
(S)-(-)-2-PIPERIDINECARBOXYLIC ACID
(S)-2-PIPERIDINECARBOXYLIC ACID
[EINECS(EC#)]

221-462-1
[Molecular Formula]

C6H11NO2
[MDL Number]

MFCD00005981
[Molecular Weight]

129.16
[MOL File]

1723-00-8.mol
Chemical PropertiesBack Directory
[Appearance]

white to light yellow crystal powder
[Melting point ]

272 °C(lit.)
[alpha ]

26.5 º (c=5,water 25 ºC)
[Boiling point ]

239.22°C (rough estimate)
[density ]

1.1426 (rough estimate)
[refractive index ]

1.4300 (estimate)
[storage temp. ]

Keep in dark place,Sealed in dry,Room Temperature
[solubility ]

DMSO (Slightly, Heated), Methanol (Slightly), Water (Slightly)
[form ]

Crystalline Powder
[pka]

2.28(at 25℃)
[color ]

White to off-white
[Optical Rotation]

[α]25/D +27°, c = 1 in H2O
[Water Solubility ]

soluble
[BRN ]

81094
[InChIKey]

HXEACLLIILLPRG-RXMQYKEDSA-N
[CAS DataBase Reference]

1723-00-8(CAS DataBase Reference)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P264-P271-P280-P302+P352-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S24/25:Avoid contact with skin and eyes .
[WGK Germany ]

3
[HS Code ]

29333990
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

D(+)-Pipecolinic acid(1723-00-8).msds
Hazard InformationBack Directory
[Chemical Properties]

white to light yellow crystal powder
[Uses]

Pipecolic acid is involved in synaptic transmission in the central nervous system.
[Definition]

ChEBI: D-pipecolic acid is the D-enantiomer of pipecolic acid. It has a role as a human metabolite. It is a conjugate base of a D-pipecolate. It is an enantiomer of a L-pipecolic acid.
[reaction suitability]

reaction type: solution phase peptide synthesis
[storage]

Store at -20°C
[Purification Methods]

D-Pipecolinic acid recrystallises as platelets from EtOH and is soluble in H2O. The hydrochloride has m 256-257o(dec) from H2O and [] D25 +10.8o (c 2, H2O). [cf p 422, Lukés et al. Collect Czech Chem Commun 22 286 1957, Bayerman Recl Trav Chim Pays-Bas 78 134 1959, Asher et al. Tetrahedron Lett 22 141 1981, Beilstein 22/1 V 220.]
Spectrum DetailBack Directory
[Spectrum Detail]

D(+)-Pipecolinic acid(1723-00-8)MS
D(+)-Pipecolinic acid(1723-00-8)1HNMR
D(+)-Pipecolinic acid(1723-00-8)IR1
D(+)-Pipecolinic acid(1723-00-8)IR2
D(+)-Pipecolinic acid(1723-00-8)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

D(+)-Pipecolinic acid, 99%(1723-00-8)
[Sigma Aldrich]

1723-00-8(sigmaaldrich)
[TCI AMERICA]

D-Pipecolic Acid,>98.0%(T)(1723-00-8)
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