| Identification | More | [Name]
(+)-Diisopinocampheyl chloroborane | [CAS]
112246-73-8 | [Synonyms]
(+)-B-CHLORODIISOPINOCAMPHENYLBORANE
(+)-B-CHLORODIISOPINOCAMPHEYLBORANE
(+)-B-DIISOPINOCAMPHEYL-CHLOROBORANE
(+)-BETA-CHLORODIISOPINOCAMPHEYLBORANE
(+)-Diisopinocampheylchloroborane
(+)-DIP CHLORIDE
(+)-DIP-CHLORIDE(TM)
(+)-IPC2BCL
(+)-beta-Chlorodiisopinocampheylborane (ca. 65% in n-hexane)
(+)-β-Chlorodiisopinocampheylborane
(+)-DIP-CHLORIDE, TYPICALLY 90-105%
(+)-DIP chloride[R]
(+)-Diisopinocampheylchloroborane, 1.8M solution in hexanes
(+)-DIP CHLORIDE 60-70% SOLUTION IN HEPTANE
(+)-B-Chlorodiisopinocampheylborane
(+)-Diisopinocampheyl chloroborane
(+)-DIP chloride
(+)-DIP-CHLORIDE IN HEPTANES, 2M SOLUTION
(+)-B-Chlorodiisopinocampheylborane (58% in Hexane, ca. 1.6mol/L) | [Molecular Formula]
C20H34BCl | [MDL Number]
MFCD00074808 | [Molecular Weight]
320.75 | [MOL File]
112246-73-8.mol |
| Chemical Properties | Back Directory | [Appearance]
White crystalline powder | [Melting point ]
53-55 °C(lit.)
| [Boiling point ]
369.6±25.0 °C(Predicted) | [density ]
0.91 | [Fp ]
>230 °F
| [storage temp. ]
2-8°C
| [Usage]
(+)-Diisopinocampheyl chloroborane(112246-73-8) are used for high enantiselective asymmetric reduction of prochiral ketones and for the preparation of β-amino alcohols. | [InChIKey]
PSEHHVRCDVOTID-YYNWCRCSSA-N | [CAS DataBase Reference]
112246-73-8(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns.
R37:Irritating to the respiratory system. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3261 8/PG 2
| [WGK Germany ]
3
| [F ]
10-21 | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
29319090 |
| Hazard Information | Back Directory | [Chemical Properties]
white to light yellow crystal powde | [Uses]
Both (+)- and (-)-DIP-chloride are used for asymmetric reduction of prochiral ketones and for the preparation of β-amino alcohols. |
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