| Identification | More | [Name]
(-)-Diisopinocampheyl chloroborane | [CAS]
85116-37-6 | [Synonyms]
(-)-B-CHLORODIISOPINOCAMPHENYLBORANE
(-)-B-CHLORODIISOPINOCAMPHEYLBORANE
(-)-B-DIISOPINOCAMPHEYL-CHLOROBORANE
(-)-BETA-CHLORODIISOPINOCAMPHEYLBORANE
(-)-DIP-CHLORIDE
(-)-DIP-CHLORIDE(TM)
(-)-IPC2BCL
(-)-b-chlorodiisopinocampherylborane
(-)-diisopinocampheylchloroborane,(-)-dpc,inheptanes
(-)-diisopinocampheylchloroborane,(-)-dpc,inhexanes
(-)-Diisopinocampheylchloroborane, in hexanes, 2M solution
(-)-Diisopinocampheylchloroborane, in heptanes, 2M solution
(-)-DIP-CHLORIDE, 50-65 WT% IN HEPTANE
(-)-DIP-CHLORIDE, 60-75 WT% IN HEXANES
(-)-DIP CHLORIDE, 65-75 WT% IN ALPHA-PI&
(-)-dip-chloride tm solution
(-)-B-Chlorodiisopinocampheylborane
(-)-Diisopinocampheyl chloroborane
(-)-DIP-Chloride
(-)-SS-CHLORODIISOPINOCAMPHEYLBORANE | [EINECS(EC#)]
237-458-8 | [Molecular Formula]
C20H34BCl | [MDL Number]
MFCD00074807 | [Molecular Weight]
320.75 | [MOL File]
85116-37-6.mol |
| Chemical Properties | Back Directory | [Appearance]
solutio | [Melting point ]
52-56 °C(lit.)
| [Boiling point ]
66-69°C | [density ]
0.954 g/mL at 25 °C
| [refractive index ]
-51 ° (C=neat) | [Fp ]
82 °F
| [storage temp. ]
2-8°C
| [form ]
clear liquid | [color ]
Colorless to Almost colorless | [BRN ]
5937756 | [InChI]
InChI=1S/C20H34BCl/c1-11-15-7-13(19(15,3)4)9-17(11)21(22)18-10-14-8-16(12(18)2)20(14,5)6/h11-18H,7-10H2,1-6H3/t11-,12-,13+,14+,15-,16-,17-,18-/m1/s1 | [InChIKey]
PSEHHVRCDVOTID-VMAIWCPRSA-N | [SMILES]
B(Cl)([C@@H]1C[C@]2([H])C[C@@]([H])(C2(C)C)[C@H]1C)[C@@H]1C[C@]2([H])C[C@@]([H])(C2(C)C)[C@H]1C | [CAS DataBase Reference]
85116-37-6(CAS DataBase Reference) |
| Safety Data | Back Directory | [Symbol(GHS) ]
    
GHS02,GHS05,GHS07,GHS08,GHS09 | [Signal word ]
Danger | [Hazard statements ]
H225-H304-H314-H336-H410 | [Precautionary statements ]
P210-P280-P301+P330+P331-P303+P361+P353-P304+P340+P310-P305+P351+P338 | [Hazard Codes ]
C,F+,N | [Risk Statements ]
R34:Causes burns.
R20/22:Harmful by inhalation and if swallowed .
R12:Extremely Flammable.
R10:Flammable.
R67:Vapors may cause drowsiness and dizziness.
R65:Harmful: May cause lung damage if swallowed.
R62:Possible risk of impaired fertility.
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R48/20:Harmful: danger of serious damage to health by prolonged exposure through inhalation . | [Safety Statements ]
S9:Keep container in a well-ventilated place .
S16:Keep away from sources of ignition-No smoking .
S29:Do not empty into drains .
S33:Take precautionary measures against static discharges .
S36/37:Wear suitable protective clothing and gloves .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S62:If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . | [RIDADR ]
UN 3261 8/PG 2
| [WGK Germany ]
3
| [F ]
10-21 | [HazardClass ]
3/8 | [PackingGroup ]
II | [HS Code ]
29319090 | [Storage Class]
3 - Flammable liquids | [Hazard Classifications]
Acute Tox. 4 Oral
Aquatic Chronic 2
Asp. Tox. 1
Flam. Liq. 3
Skin Corr. 1B
Skin Sens. 1 |
| Hazard Information | Back Directory | [Chemical Properties]
solutio | [Uses]
Both (+)- and (-)-DIP-chloride are used for asymmetric reduction of prochiral ketones and for the preparation of β-amino alcohols. |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
Jia Xing Isenchem Co.,Ltd
|
| Telephone: |
0573-85285100 18627885956 |
| Website: |
https://www.chemicalbook.com/ShowSupplierProductsList14265/0_EN.htm |
| Company Name: |
Aemon Chemical
|
| Telephone: |
0086-755-86198205 |
| Website: |
www.aemonchem.com |
|