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114-26-1

114-26-1 Structure

114-26-1 Structure
IdentificationBack Directory
[Name]

Propoxur
[CAS]

114-26-1
[Synonyms]

PHC
IPMC
phc7
IMPC
Tugen
Bolfo
oms33
UNDEN
Bifex
PROPER
BAYGON
oms-33
OMS 33
o-Impc
Boruho
Boygon
Brygou
Tendex
Rhoden
Undeen
Undene
DMS 33
PROPOXU
baygone
Sendran
Suncide
Propyon
Isocarb
MITOXUR
bay5122
bay9010
5812315
Aprocarb
UNDEN(R)
BAY 5122
BAY 9010
bay39007
PROPOXUR
PROPOGON
dalfdust
Propotox
Baygon G
Baygon(R)
Pillargon
Propoxure
Dalf Dust
ent25,671
ent-25671
Boruho 50
Blattosep
Mrowkozol
TENDEX(R)
Blattanex
Arporcarb
Arprocarb
BAY 39007
SENDRAN(R)
SUNCIDE(R)
bayerb5122
ENT 25,671
Propoxylor
Propoksuru
Propotox M
phc (jmaf)
Bayer 9010
Invisi-Gard
APROCARB(R)
BAYGON (TM)
BAYER 39007
BLATTANEX(R)
Blattanex 20
Bayer B 5122
chemagro9010
Chemagro 9010
phc(carbamate)
Propoxur (ISO)
Fumite propoxur
Baygon,Propoxur,
Propoxur(Baygon)
BAYGON, 1GM, NEAT
tugonfliegenkugel
Unden (Pesticide)
propoksuru(polish)
Tugon fliegenkugel
propoxur (bsi,iso,esa)
Baygon (TM) 1g [114-26-1]
Isopropoxyphenyl methylcarbamate
o-isopropoxy-phenomethylcarbamate
Methyl-2-isopropoxyphenylcarbamate
o-isopropoxyphenyln-methylcarbamate
2-Isopropoxyphenyl-N-methylcarbamat
2-ISO-PROPOXYPHENYL METHYLCARBAMATE
O-ISOPROPOXYPHENYL METHYL CARBAMATE
o-Isopropoxyphenyl N-methylcarbamate
N-Methyl-2-isopropoxyphenylcarbamate
2-ISOPROPOXYPHENYL-N-METHYL-CARBAMATE
ORTHO-ISOPROPOXYPHENYLMETHYLCARBAMATE
Phenol, o-isopropoxy-, methylcarbamate
PROPOXUR PESTANAL (2-ISOPROPOXY- PHENYL
2-(1-methylethoxy)-phenomethylcarbamate
o-(2-isopropoxyphenyl)n-methylcarbamate
O-(2-Isopropoxyphenyl) N-methylcarbamate
2-(1-Methylethoxy)phenol methylcarbamate
2-(1-Methylethoxy)phenyl methylcarbamate
methyl-carbamicacio-isopropoxyphenylester
n-2-(1-methylethoxy)phenylmethyl-carbamate
2-(1-Methylethoxy)phenyl N-methylcarbamate
phenol,2-(1-methylethoxy)-,methylcarbamate
(2-propan-2-yloxyphenyl) N-methylcarbamate
N-2-(1-Methylethoxy)phenyl methyl-carbamate
n-methylcarbamicacid,o-isopropoxyphenylester
Phenol, 2-(1-methylethoxy)-, methylcarbamate
Methylcarbamic acid, o-isopropoxyphenol ester
BAYGON [N-METHYL-2-ISOPROPOXYPHENYLCARBAMATE]
PROPOXUR (2-ISOPROPOXYPHENYL METHYL CARBAMATE)
2-(1-Methylethoxy)phenol 1-(N-MethylcarbaMate)
Methylcarbamicacid2-(1-methylethoxy)phenylester
methyl-carbamicaci2-(1-methylethoxy)phenylester
Carbamic acid, methyl-, o-isopropoxyphenyl ester
CARBAMICACID,METHYL-,ORTHO-ISOPROPOXYPHENYLESTER
N-methylcarbamic acid (2-isopropoxyphenyl) ester
METHYLCARBAMIC ACID-(1-METHYLETHOXY)PHENYL ESTER
Phenol, 2-(1-Methylethoxy)-, 1-(N-MethylcarbaMate)
n-methylcarbamicacid,2-(1-methylethoxy)phenylester
Carbamic acid, methyl-, 2-(1-methylethoxy)phenyl ester
propoxur (ISO) 2-isopropyloxyphenyl N-methylcarbamate 2-isopropoxyphenyl methylcarbamate
[EINECS(EC#)]

204-043-8
[Molecular Formula]

C11H15NO3
[MDL Number]

MFCD00055455
[Molecular Weight]

209.24
[MOL File]

114-26-1.mol
Chemical PropertiesBack Directory
[Appearance]

Propoxur is a white to tan crystalline solid or powder. Faint characteristic odor
[Appearance]

White, crystalline powder; odorless. Soluble in most alcohols; very slightly solublein water; unstable in highly alkaline media; stableunder normal conditions.
[Melting point ]

91°C
[Boiling point ]

348.6°C (rough estimate)
[density ]

1.1200
[refractive index ]

1.5080 (estimate)
[Fp ]

-18 °C
[storage temp. ]

2-8°C
[form ]

Minute Crystals
[Water Solubility ]

Slightly soluble. 0.2 g/100 mL
[Merck ]

13,7929
[CAS DataBase Reference]

114-26-1
[NIST Chemistry Reference]

2-Isopropoxyphenyl N-methylcarbamate(114-26-1)
[EPA Substance Registry System]

Phenol, 2-(1-methylethoxy)-, methylcarbamate(114-26-1)
Hazard InformationBack Directory
[Chemical Properties]

White Solid
[Uses]

Propoxur is a non-systematic carbamate insecticide. Propoxur is used against a wide range of insects such as fleas, mosquitoes, ants, gypsy moths, and other agricultural pests. Propoxur functions by r eversibly inactivating the enzyme acetylcholinesterase in insects.
[Definition]

ChEBI: A carbamate ester that is phenyl methylcarbamate substituted at position 2 by a propan-2-yloxy group.
[Uses]

Insecticide.
[General Description]

White to tan crystalline powder with a faint, characteristic odor. Used as an insecticide.
[Reactivity Profile]

Propoxur is incompatible with the following: Strong oxidizers, alkalis [Note: Emits highly toxic methyl isocyanate fumes when heated to decomposition.] .
[Hazard]

Toxic by ingestion and inhalation.
[Potential Exposure]

Personnel engaged in the manufacture, formulation and application of this organonitrogen agricul- tural chemical and pesticide.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, includ- ing resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medi- cal attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.
[Shipping]

UN2757 Carbamate pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.
[Incompatibilities]

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explo- sions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, alkalis, heat, and mois- ture. Emits highly toxic methyl isocyanate fumes when heated to decomposition.
[Waste Disposal]

In accordance with 40CFR165, follow recommendations for the disposal of pes- ticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contact- ing your regional EPA office. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations govern- ing storage, transportation, treatment, and waste disposal.
Safety DataBack Directory
[Hazard Codes ]

T;N,N,T,Xn,F
[Risk Statements ]

25-50/53-67-65-38-11
[Safety Statements ]

37-45-60-61-62
[RIDADR ]

UN 2811/2588
[RTECS ]

FC3150000
[HazardClass ]

6.1(b)
[PackingGroup ]

III
[Hazardous Substances Data]

114-26-1(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

PETROLEUM ETHER-->Potassium carbonate-->Triethylamine-->1,4-Dioxane-->Chlorine-->Carbon tetrachloride-->METHYLAMINE-->Ethylene glycol-->Pyrocatechol-->2-Bromopropane-->2-Chloropropane-->METHYLISOCYANATE 1 X 500MG NEAT-->Carbaryl-->Methylaminoformyl chloride-->METHYL ISOCYANATE-->2-Isopropylphenol-->2-Isopropoxyphenol
Questions And AnswerBack Directory
[Chemical Properties]

The pure propoxur is white crystalline powder. m.p.91.5℃(industrial products84~87℃) and vapour pressure 1.33Pa (120℃). It can be dissolved in most polar organic solvents, and the solubility in water is 0.2%. It is easy to hydrolyze under alkaline conditions and the half-life of pH at 10 time is 40min (20℃).
[Uses]

Quick acting, long-acting carbamate insecticide. It has the effect of touch and kill, stomach poison and fumigation, and there is no internal absorption. It is mainly used for prevention and control of rice stem borer and rice leafhopper, planthopper, cotton aphid, scale insect, rust ticks, cereal pests and sanitary insect pest  in crops. It can kill in vitro parasites, family health pests (mosquitoes, flies, cockroaches, etc.) and storehouse pests.
[Toxicity]

The acute oral LD50 is 90 to 128mg/kg for the male rats,104mg/kg for the female rats and 100 to 109mg/kg for the male mice. The acute transdermal LD50 is 800 ~ 1000mg/kg for the rats. In the 2 year feeding test, the non action dose is 800 ~ 1000mg/kg. For carp it is LC50>10mg/L. The acute oral LD50 is 15 ~ 30mg/kg for cowbirds. It is of high toxicity to bees.
[Preparation]

The following two methods can be adopted and the reaction is:
Spectrum DetailBack Directory
[Spectrum Detail]

Propoxur(114-26-1)IR1
Propoxur(114-26-1)13CNMR
Propoxur(114-26-1)1HNMR
Propoxur(114-26-1)MS
Propoxur(114-26-1)IR2
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