| Identification | More | [Name]
2-Hydroxybenzophenone | [CAS]
117-99-7 | [Synonyms]
2-BENZOYLPHENOL
2-HYDROXYBENZOPHENONE
O-BENZOYLPHENOL
O-HYDROXYBENZOPHENONE
(2-Hydroxy-phenyl)-phenylmethanon
(2-hydroxyphenyl)phenyl-methanon
(2-hydroxyphenyl)phenylmethanone
(2-Hydroxy-phenyl)-phenylmethanone
Benzophenone, 2-hydroxy-
benzophenone,2-hydroxy-
methanone,(2-hydroxyphenyl)phenyl-
ortho-Hydroxybenzophenone
Phenyl 2-hydroxyphenyl ketone
Hydroxybenzophenone
2-Hydroxybenzophenone99%
2-HYDROXYBENZOPHENONE 99% | [EINECS(EC#)]
204-226-2 | [Molecular Formula]
C13H10O2 | [MDL Number]
MFCD00002216 | [Molecular Weight]
198.22 | [MOL File]
117-99-7.mol |
| Chemical Properties | Back Directory | [Appearance]
yellow crystalline powder | [Melting point ]
37-39 °C (lit.) | [Boiling point ]
171-173 °C/12 mmHg (lit.) | [density ]
1.1184 (rough estimate) | [refractive index ]
1.5954 (estimate) | [Fp ]
>230 °F
| [storage temp. ]
Sealed in dry,2-8°C | [form ]
Crystalline Powder | [pka]
8.07±0.30(Predicted) | [color ]
Yellow | [Water Solubility ]
insoluble | [BRN ]
1638174 | [InChI]
InChI=1S/C13H10O2/c14-12-9-5-4-8-11(12)13(15)10-6-2-1-3-7-10/h1-9,14H | [InChIKey]
HJIAMFHSAAEUKR-UHFFFAOYSA-N | [SMILES]
C(C1=CC=CC=C1O)(C1=CC=CC=C1)=O | [Uses]
UV absorber in plastics. | [CAS DataBase Reference]
117-99-7(CAS DataBase Reference) | [NIST Chemistry Reference]
Methanone, (2-hydroxyphenyl)phenyl-(117-99-7) | [EPA Substance Registry System]
117-99-7(EPA Substance) |
| Hazard Information | Back Directory | [Chemical Properties]
yellow crystalline powder | [Application]
2-Hydroxybenzophenone was used to quantify the metabolites of unmethylated extracts from the supernatants of Pseudomonas acidovorans cultures grown on 1,1-diphenylethylene.
2-Hydroxybenzophenone forms copolymer 2-hydroxy, 3-allyl, 4,4′-dimethoxybenzophenone with methyl methacrylate.
It forms photostabilizer compounds with 2,2,6,6-tetramethylpiperidine under phase transfer catalysis conditions.
It reacts with 3-aminophenyl boronic acid to form macrocyclic boronates. | [Preparation]
Preparation by Friedel–Crafts acylation of benzene in the presence of aluminium chloride,
? with 2-hydroxybenzoyl chloride (salicylic acid chloride), (52%), (39%), at temperature <60°;
? with o-anisoyl chloride. Demethylation occurred during the Friedel–Crafts acylation, especially in the presence of ferric chloride at 130–140°;
? with 2-ethoxybenzoyl chloride in a boiling water bath (42%). | [Synthesis Reference(s)]
Journal of the American Chemical Society, 76, p. 5469, 1954 DOI: 10.1021/ja01650a062
The Journal of Organic Chemistry, 32, p. 3844, 1967 DOI: 10.1021/jo01287a027 | [General Description]
- 2-Hydroxybenzophenone forms copolymer 2-hydroxy, 3-allyl, 4,4′-dimethoxybenzophenone with methyl methacrylate.
- It forms photostabilizer compounds with 2,2,6,6-tetramethylpiperidine under phase transfer catalysis conditions.
- It reacts with 3-aminophenyl boronic acid to form macrocyclic boronates.
|
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
China Langchem Inc.
|
| Telephone: |
0086-21-58956006 |
| Website: |
www.chemicalbook.com/ShowSupplierProductsList19141/0_EN.htm |
|