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1470-57-1

1470-57-1 Structure

1470-57-1 Structure
IdentificationMore
[Name]

2-HYDROXY-5-METHYLBENZOPHENONE
[CAS]

1470-57-1
[Synonyms]

2'-HYDROXY 5'-METHYL BENZOPHENONE
2-HYDROXY-5-METHYLBENZOPHENONE
RARECHEM FH 1L 0064
(2-Hydroxy-5-methylphenyl)phenylmethanone
2-Benzoyl-4-methylphenol
5-Methyl-2-hydroxybenzophenone
Benzophenone, 2-hydroxy-5-methyl-
Methanone, (2-hydroxy-5-methylphenyl)phenyl-
[EINECS(EC#)]

216-002-1
[Molecular Formula]

C14H12O2
[MDL Number]

MFCD00002379
[Molecular Weight]

212.24
[MOL File]

1470-57-1.mol
Chemical PropertiesBack Directory
[Appearance]

yellow crystalline powder
[Melting point ]

83-85 °C (lit.)
[Boiling point ]

312.08°C (rough estimate)
[density ]

1.1035 (rough estimate)
[refractive index ]

1.6000 (estimate)
[form ]

powder to crystal
[pka]

8.24±0.43(Predicted)
[color ]

Light orange to Yellow to Green
[CAS DataBase Reference]

1470-57-1(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection .
[WGK Germany ]

3
[Hazard Note ]

Irritant
[HS Code ]

29145000
Hazard InformationBack Directory
[Chemical Properties]

yellow crystalline powder
[Uses]

2-?Hydroxy-?5-?methylbenzophenone is a general reagent used in the synthesis of anti-bacterial and anti-fungal agents.
[Preparation]

Preparation by condensation of benzotrichloride with p-cresol,
? in the presence of aluminium chloride in carbon disulfide for 2 h (75%). The 6,12-diphenyl-2,8-dimethyl-6,12-epoxy-6H,12H-dibenzo[b,f] dioxocin, an intermediate compound, was also formed under these conditions (29%). This “dioxocin”, by hydrolysis with concentrated sulfuric acid at r.t., gave the expected ketone (91%);
? in the presence of aqueous sodium hydroxide in a water bath for 4 h (33%) or in 32–40% aqueous sodium hydroxide at 70–80° (67%).
[Synthesis Reference(s)]

The Journal of Organic Chemistry, 38, p. 1924, 1973 DOI: 10.1021/jo00950a030
Spectrum DetailBack Directory
[Spectrum Detail]

2-HYDROXY-5-METHYLBENZOPHENONE(1470-57-1)1HNMR
2-HYDROXY-5-METHYLBENZOPHENONE(1470-57-1)FT-IR
2-HYDROXY-5-METHYLBENZOPHENONE(1470-57-1)IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

2-Hydroxy-5-methylbenzophenone, 99%(1470-57-1)
[Sigma Aldrich]

1470-57-1(sigmaaldrich)
[TCI AMERICA]

2-Hydroxy-5-methylbenzophenone,>97.0%(GC)(1470-57-1)
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