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1197-19-9

1197-19-9 Structure

1197-19-9 Structure
IdentificationMore
[Name]

4-(DIMETHYLAMINO)BENZONITRILE
[CAS]

1197-19-9
[Synonyms]

1-CYANO-4-(DIMETHYLAMINO)BENZENE
4-CYANO-N,N-DIMETHYLANILINE
4-(DIMETHYLAMINO)BENZONITRILE
AKOS B004059
LABOTEST-BB LT00233151
P-(DIMETHYLAMINO)BENZONITRILE
TIMTEC-BB SBB008018
4-(Dimethylamino)benzenecarbonitrile
Benzonitrile, p-(dimethylamino)-
Benzonitrile,4-(dimethylamino)-
N,N-Dimethyl-4-cyanoaniline
N,N-Dimethyl-p-cyanoaniline
p-(Dimethylamino)benzoic acid nitrile
p-(N,N-Dimethylamino)benzonitrile
para(Dimethylamino)benzonitrile
p-Cyano-N,N-dimethylaniline
4-CYANODIMETHYLANILINE
[EINECS(EC#)]

214-819-8
[Molecular Formula]

C9H10N2
[MDL Number]

MFCD00001815
[Molecular Weight]

146.19
[MOL File]

1197-19-9.mol
Chemical PropertiesBack Directory
[Appearance]

light brown crystalline powder
[Melting point ]

72-75 °C(lit.)
[Boiling point ]

318 °C(lit.)
[density ]

1.3346 (rough estimate)
[refractive index ]

1.5600 (estimate)
[Fp ]

317-319°C
[solubility ]

soluble in Methanol
[form ]

Crystalline Powder
[pka]

1.61±0.12(Predicted)
[color ]

Light brown
[BRN ]

971606
[CAS DataBase Reference]

1197-19-9(CAS DataBase Reference)
[EPA Substance Registry System]

Benzonitrile, 4-(dimethylamino)- (1197-19-9)
Safety DataBack Directory
[Hazard Codes ]

Xn,Xi
[Risk Statements ]

R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin .
R43:May cause sensitization by skin contact.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37:Wear suitable protective clothing and gloves .
S36:Wear suitable protective clothing .
[RIDADR ]

3276
[WGK Germany ]

2
[HazardClass ]

6.1
[PackingGroup ]

III
[HS Code ]

29269090
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sodium hydroxide-->Hydrochloric acid-->Diethyl ether-->Sodium sulfate-->Acetic anhydride-->Trimethyl phosphate-->4-Aminobenzonitrile-->Benzamide, 4-(dimethylamino)-N,N-dimethyl--->4-(DIMETHYLAMINO)PHENYLACETIC ACID-->4-(DIMETHYLAMINO)BENZYL ALCOHOL-->N-Methoxy-N-Methyl-4-(diMethylaMino)benzaMide-->4-(N-Methylamino)benzonitrile
[Preparation Products]

4-DIMETHYLAMINO-BENZAMIDINE-->Formamide, N-(4-cyanophenyl)-N-methyl--->3-oxatricyclo[3.2.1.02,4]octane-->4-DIMETHYLAMINOBENZYLAMINE
Hazard InformationBack Directory
[Chemical Properties]

light brown crystalline powder
[Uses]

4-(Dimethylamino)benzonitrile is used in predicting the carcinogenicity of aromatic amine derivative in UK EMS collaborative study.
[Synthesis Reference(s)]

Tetrahedron Letters, 36, p. 4035, 1995 DOI: 10.1016/0040-4039(95)00710-T
[General Description]

4-(Dimethylamino)benzonitrile is extensively used in photophysical studies due to its ability to undergo intramolecular charge transfer (ICT) from the dimethylamino moiety to the cyanophenyl moiety on photo-excitation leading to the appearance of dual fluorescence.
Spectrum DetailBack Directory
[Spectrum Detail]

4-(DIMETHYLAMINO)BENZONITRILE(1197-19-9)MS
4-(DIMETHYLAMINO)BENZONITRILE(1197-19-9)1HNMR
4-(DIMETHYLAMINO)BENZONITRILE(1197-19-9)13CNMR
4-(DIMETHYLAMINO)BENZONITRILE(1197-19-9)IR1
4-(DIMETHYLAMINO)BENZONITRILE(1197-19-9)IR2
4-(DIMETHYLAMINO)BENZONITRILE(1197-19-9)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

4-(Dimethylamino)benzonitrile, 95%(1197-19-9)
[Alfa Aesar]

4-Dimethylaminobenzonitrile, 98%(1197-19-9)
[Sigma Aldrich]

1197-19-9(sigmaaldrich)
[TCI AMERICA]

4-(Dimethylamino)benzonitrile,>98.0%(GC)(T)(1197-19-9)
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