ChemicalBook--->CAS DataBase List--->120-37-6

120-37-6

120-37-6 Structure

120-37-6 Structure
IdentificationMore
[Name]

3-Ethylamino-4-methylphenol
[CAS]

120-37-6
[Synonyms]

3-ETHYLAMINO-4-CRESOL
3-ETHYLAMINO-4-METHYLPHENOL
3-ETHYLAMINO-PARAMETHYLPHENOL
3-(ETHYLAMINO)-P-CRESOL
3-(ethylamino)-4-methyl-pheno
3-Ethylamino
4-Methyl-3-(N-ethylamino)-phenol
4-Methyl-3-ethylaminophenol.
3-Ethylamino-4-kresol
3-ETHYLAMINO-4-METHYLPHENOL: TECH., 90%
5-Ethylamino-p-cresol (OH=1)
2-Ethylamino-4-hydroxytoluene
1-Methyl-2-(ethylamino)-4-hydroxybenzene
2-Ethylamino-4-hydroxy-1-methylbenzene
[EINECS(EC#)]

204-391-0
[Molecular Formula]

C9H13NO
[MDL Number]

MFCD00002382
[Molecular Weight]

151.21
[MOL File]

120-37-6.mol
Chemical PropertiesBack Directory
[Appearance]

purple solid
[Melting point ]

85-87 °C (lit.)
[Boiling point ]

135-140°C 3mm
[density ]

1.0406 (rough estimate)
[refractive index ]

1.5380 (estimate)
[Fp ]

135-140°C/3mm
[storage temp. ]

Keep in dark place,Inert atmosphere,Room temperature
[pka]

10.66±0.18(Predicted)
[Stability:]

Stable. Incompatible with strong oxidizing agents.
[Water Solubility ]

Insoluble in water.
[BRN ]

3241548
[CAS DataBase Reference]

120-37-6(CAS DataBase Reference)
[NIST Chemistry Reference]

Phenol, 3-(ethylamino)-4-methyl-(120-37-6)
[EPA Substance Registry System]

120-37-6(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection .
[WGK Germany ]

2
[RTECS ]

SL4105000
[TSCA ]

Yes
[HS Code ]

29222990
Hazard InformationBack Directory
[General Description]

Purple solid.
[Reactivity Profile]

An amine and phenol. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides. Phenols do not behave as organic alcohols, as one might guess from the presence of a hydroxyl (-OH) group in their structure. Instead, they react as weak organic acids. Phenols and cresols are much weaker as acids than common carboxylic acids (phenol has Ka = 1.3 x 10^[-10]). These materials are incompatible with strong reducing substances such as hydrides, nitrides, alkali metals, and sulfides. Flammable gas (H2) is often generated, and the heat of the reaction may ignite the gas. Heat is also generated by the acid-base reaction between phenols and bases. Such heating may initiate polymerization of the organic compound. Phenols are sulfonated very readily (for example, by concentrated sulfuric acid at room temperature). The reactions generate heat. Phenols are also nitrated very rapidly, even by dilute nitric acid.
[Air & Water Reactions]

This compound may be sensitive to prolonged exposure to air. . Insoluble in water.
[Fire Hazard]

Flash point data for this chemical are not available. 3-ETHYLAMINO-4-METHYLPHENOL is probably combustible.
[Chemical Properties]

purple solid
[Uses]

3-Ethylamino-4-methylphenol was used in the synthesis of rhodol by undergoing condensation reaction with 2-(2,4-dihydroxybenzoyl)benzoic acid.
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

2-Ethylamino-4-hydroxytoluene(120-37-6).msds
Spectrum DetailBack Directory
[Spectrum Detail]

3-Ethylamino-4-methylphenol(120-37-6)MS
3-Ethylamino-4-methylphenol(120-37-6)1HNMR
3-Ethylamino-4-methylphenol(120-37-6)13CNMR
3-Ethylamino-4-methylphenol(120-37-6)IR1
3-Ethylamino-4-methylphenol(120-37-6)IR2
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

3-Ethylamino-4-methylphenol, tech. 90%(120-37-6)
[Sigma Aldrich]

120-37-6(sigmaaldrich)
[TCI AMERICA]

3-Ethylamino-4-methylphenol,>92.0%(GC)(120-37-6)
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