ChemicalBook--->CAS DataBase List--->12039-13-3

12039-13-3

12039-13-3 Structure

12039-13-3 Structure
IdentificationMore
[Name]

TITANIUM(IV) SULFIDE
[CAS]

12039-13-3
[Synonyms]

TITANIUM DISULFIDE
TITANIUM DISULPHIDE
TITANIUM(IV) SULFIDE
TITANIUM SULFIDE
TITANIUM(IV) SULFIDE ANHYDROUS POWDER&
TITANIUM(IV) SULFIDE, POWDER, 1 MICRON, 99.9%
TITANIUM DISULFIDE, 99.5%
Titanium(Ⅳ)sulfide
Titanium(IV)sulfide(99.8%-Ti)
TITANIUM(IV) SULFIDE: 99.8%
Titanium(IV) sulfide, 99.8% (metals basis)
Titan disulfide
Titanium(IV)disulfide
[EINECS(EC#)]

234-883-0
[Molecular Formula]

S2Ti
[MDL Number]

MFCD00049598
[Molecular Weight]

112
[MOL File]

12039-13-3.mol
Chemical PropertiesBack Directory
[Definition]

Yellow solid. Decomposed by steam.
[density ]

3,37 g/cm3
[RTECS ]

XR2460000
[solubility ]

soluble in HSO4
[form ]

powder
[color ]

yellow to brown
[Specific Gravity]

3.22
[Water Solubility ]

Titanium(IV) sulfide is insoluble in water and moderately acid soluble.
[Crystal Structure]

CdI2 type
[Sensitive ]

Moisture Sensitive
[crystal system]

Three sides
[Space group]

P3m1
[Lattice constant]

a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.340730.340730.5695390901200.0573
[InChI]

1S/2S.Ti
[InChIKey]

CFJRPNFOLVDFMJ-UHFFFAOYSA-N
[SMILES]

S=[Ti]=S
[Uses]

Solid lubricant.
[CAS DataBase Reference]

12039-13-3(CAS DataBase Reference)
[EPA Substance Registry System]

Titanium sulfide (TiS2) (12039-13-3)
Hazard InformationBack Directory
[Chemical Properties]

yellowish brown powder(s); hexagonal; sensitive to moisture, forming H2S and TiO2; decomposed by steam; is obtained as a product of the reaction of H2S and TiCl4 at 600°C; used as a solid lubricant [HAW93] [STR93] [KIR83]
[General Description]

A yellow or gray powder with an unpleasant odor that is used as a solid lubricant. Contact with the material may cause burns to skin, eyes, and mucous membranes. TITANIUM DISULFIDE(12039-13-3) may be toxic by ingestion, inhalation or skin absorption.
[Reactivity Profile]

TITANIUM DISULFIDE reacts with acids to generate hydrogen sulfide, a toxic gas. Reacts slowly with water and is decomposed by steam, generating hydrogen sulfide.
[Air & Water Reactions]

Contact with water leads to the slow evolution of hydrogen sulfide, a toxic and flammable gas.
[Health Hazard]

Fire will produce irritating, corrosive and/or toxic gases. Inhalation of decomposition products may cause severe injury or death. Contact with substance may cause severe burns to skin and eyes. Runoff from fire control may cause pollution.
[Fire Hazard]

Flammable/combustible material. May ignite on contact with moist air or moisture. May burn rapidly with flare-burning effect. Some react vigorously or explosively on contact with water. Some may decompose explosively when heated or involved in a fire. May re-ignite after fire is extinguished. Runoff may create fire or explosion hazard. Containers may explode when heated.
[reaction suitability]

core: titanium
reagent type: catalyst
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection .
[RIDADR ]

UN 3174 4.2/PG 3
[WGK Germany ]

3
[TSCA ]

Yes
[HazardClass ]

4.3
[PackingGroup ]

III
[Storage Class]

4.2 - Pyrophoric and self-heating hazardous materials
[Hazard Classifications]

Eye Irrit. 2
Self-heat. 2
Skin Irrit. 2
STOT SE 3
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Titanium(IV) sulfide, 99.8% (metals basis)(12039-13-3)
[Sigma Aldrich]

12039-13-3(sigmaaldrich)
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