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12081-22-0

12081-22-0 Structure

12081-22-0 Structure
IdentificationBack Directory
[Name]

CROTYLPALLADIUM CHLORIDE DIMER
[CAS]

12081-22-0
[Synonyms]

Di-π-Crotylpalladium chloride
CROTYLPALLADIUM CHLORIDE DIMER
Crotylpalladiumchloridedimer,99%
(2-Butenyl)chloropalladium dimer
2-Butenylpalladium Chloride Dimer
Di-2-butenyldipalladium dichloride
CrotylpalladiuM chloride diMer,98%
Dichloro-(1-methylallyl)-dipalladium
Dichlorobis(1-methylallyl)dipalladium
(2-Butenyl)chloropalladium dimer >=97%
(1-Methylallyl)palladiuM chloride diMer
(1-METHYLALLYL)PALLADIUMCHLORIDEDIMER,99%
Palladium, bis[(1,2,3-h)-2-buten-1-yl]di-m-chlorodi-
Bis[(1,2,3-η)-2-buten-1-yl]di-μ-chlorodi-palladiumdi-π-crotylpalladium chloride
[Molecular Formula]

C8H14Cl2Pd2
[MDL Number]

MFCD01074457
[MOL File]

12081-22-0.mol
[Molecular Weight]

393.94
Chemical PropertiesBack Directory
[Melting point ]

133-140 °C
[storage temp. ]

under inert gas (nitrogen or Argon) at 2-8°C
[form ]

Powder
[color ]

yellow
[Sensitive ]

air sensitive
[InChI]

InChI=1S/2C4H7.2ClH.2Pd/c2*1-3-4-2;;;;/h2*3-4H,1H2,2H3;2*1H;;/q;;;;2*+1/p-2/b2*4-3+;;;;
[InChIKey]

NTFUUQYNUUTALG-HYTOEPEZSA-L
[SMILES]

C(=C/C)\C[Pd]Cl.C(=C/C)\C[Pd]Cl
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P264-P271-P280-P302+P352-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36/37/39
[WGK Germany ]

3
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Hazard InformationBack Directory
[Uses]

Catalyst for:
  • Enantioselective elimination of palladium hydride
  • Non-covalent anchoring of catalysts to silica supports
  • Allylations of cyanoacetates
  • Enantioselective nucleophilic substitutions

Reactant for:
  • Allylic alkylation reactions
  • Preparation of phosphane-functionalized carbosilane dendrimers
[reaction suitability]

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
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