| Identification | More | [Name]
SODIUM BISMUTHATE | [CAS]
12232-99-4 | [Synonyms]
BISMUTH SODIUM TRIOXIDE SODIUM BISMUTHATE SODIUM BISMUTHATE HYDRATE SODIUM BISMUTHATE(V) SODIUM BISMUTH OXIDE bismuthate(bio31-),sodium Bismuthate,sodium Bismuthsodiumoxide Sodiumbismuthate,dihydrate SODIUM TRIOXOBISMUTHATE(V) R. G. SodiumBismuthateGr Sodiumbismuthate(V) 85+% SODIUM BISMUTHATE REAGENT (ACS) Bismuth sodium oxide (BiNaO3) sodium bismuth oxide, acs SODIUMBISMUTHATE,POWDER,PRACTICAL SODIUMBISMUTHATE,POWDER,REAGENT,ACS Sodium bismuth oxide, ACS, 80% min Sodium Bismuthate, Powder, Reagent | [EINECS(EC#)]
235-455-6 | [Molecular Formula]
BiNaO3 | [MDL Number]
MFCD00003474 | [Molecular Weight]
279.97 | [MOL File]
12232-99-4.mol |
| Chemical Properties | Back Directory | [Appearance]
yellow-brown powder | [Melting point ]
>300°C | [storage temp. ]
Room Temperature | [solubility ]
Aqueous Acid (Slightly, Heated) | [form ]
Powder | [color ]
Yellow to brown | [Odor]
Odorless | [Stability:]
Stable. | [Water Solubility ]
Soluble in aqueous acid. Insoluble in water. | [Sensitive ]
Hygroscopic | [Merck ]
14,8585 | [InChI]
1S/Bi.Na.3O/q;+1;;;-1 | [InChIKey]
PNYYBUOBTVHFDN-UHFFFAOYSA-N | [SMILES]
[Na+].[O-][Bi](=O)=O | [CAS DataBase Reference]
12232-99-4(CAS DataBase Reference) | [EPA Substance Registry System]
Bismuth sodium oxide (BiNaO3) (12232-99-4) |
| Questions And Answer | Back Directory | [Preparation]
The main method for preparing sodium bismuthate is the bromine water oxidation method, but this method yields sodium bismuthate with low purity. Kumada et al. reported an improved synthesis process for bismuthates using an ion exchange method, but these methods require several days of heating. |
| Safety Data | Back Directory | [Symbol(GHS) ]
 GHS07 | [Signal word ]
Warning | [Hazard statements ]
H302 | [Precautionary statements ]
P264-P270-P301+P312-P501 | [Hazard Codes ]
Xn | [Risk Statements ]
R22:Harmful if swallowed. | [Safety Statements ]
S22:Do not breathe dust . S24/25:Avoid contact with skin and eyes . | [WGK Germany ]
3
| [RTECS ]
VZ1750000
| [F ]
3 | [TSCA ]
Yes | [HS Code ]
28419085 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Acute Tox. 4 Oral | [Toxicity]
LD100 orally in rats: 720 mg/kg, Hanzlik et al., J. Pharmacol. Exp. Ther. 62, 372 (1938) |
| Hazard Information | Back Directory | [Chemical Properties]
yellow-brown powder | [Uses]
For the determination of manganese in iron and steel, etc., the manganese being oxidized by it in hot HNO3 or H2SO4 solution to permanganate. | [Uses]
Oxidizer; determination of manganese in iron and steel. | [Uses]
Sodium Bismuthate, is an inorganic compound, which is a strong oxidiser. Sodium Bismuthate converts almost any manganese compound to permanganate, which is easily assayed spectrophotometrically. | [reaction suitability]
reagent type: catalyst core: bismuth |
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