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126613-06-7

126613-06-7 Structure

126613-06-7 Structure
IdentificationMore
[Name]

(R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate)
[CAS]

126613-06-7
[Synonyms]

1,1'-BI-2-NAPHTHOL BIS(TRIFLUOROMETHANESULFONATE)
1,1-BI-2-NAPHTHOL BIS(TRIFLUOROMETHANESULFONATE)
1,1'-BI-2-NAPHTHOL-BIS(TRIFLUOROMETHANESULPHONATE)
1,1'-BINAPHTHYL-2,2'-DIYL BIS(TRIFLUOROMETHANESULPHONATE)
1,1'-BIS(2-NAPHTHOL) DITRIFLATE
BINOL-TF2
(R)-(-)-1,1'-BI-2-NAPHTHOL BIS(TRIFLUOROMETHANESULFONATE)
(R)-(-)-1,1'-BI-2-NAPHTHOL-BIS(TRIFLUOROMETHANESULPHONATE)
(R)-(-)-1,1'-BI-2-NAPHTHYL BIS-TRIFLUOROMETHANESULFONATE
(R)-1,1'-BINAPHTHALENE-2,2'-DIYL BIS(TRIFLUOROMETHANESULFONATE)
(R)-(-)-1,1'-BINAPHTHOL-2,2'-BIS(TRIFLUOROMETHANESULFONATE)
(R)-(-)-1,1'-BINAPHTHYL-2,2'-DIYL BIS(TRIFLUOROMETHANESULFONATE)
(R)-1,1'-BINAPHTHYL-2,2'-DIYL BIS(TRIFLUOROMETHANE)SULPHONATE
(R)-(-)-1,1'-BIS(2-NAPHTHOL) DITRIFLATE
R-BINOL-TF2
(RS)-TRIFLUOROMETHANESULFONIC ACID 2'-TRIFLUOROMETHANESULFONYLOXY-[1,1']BINAPTHALENYL-2-YL ESTER
(R)-TRIFLUOROMETHANESULFONIC ACID 2'-TRIFLUOROMETHANSULFONYLOXY-[1,1']BINAPHTHALENYL-2-YL ESTER
(S)-(-)-1,1'-BI-2-NAPHTHOL BIS(TRIFLUOROMETHANESULFONATE)
(S)-(+)-1,1'-BI-2-NAPHTHOL BIS(TRIFLUOROMETHANESULFONATE)
(S)-(+)-1,1'-BI-2-NAPHTHOL-BIS(TRIFLUOROMETHANESULPHONATE)
[Molecular Formula]

C22H18F6O8S2
[MDL Number]

MFCD00274615
[Molecular Weight]

588.49
[MOL File]

126613-06-7.mol
Chemical PropertiesBack Directory
[Appearance]

white powder
[Melting point ]

83-85 °C(lit.)
[alpha ]

-149 º (c=1, CHCl3)
[Boiling point ]

578.8±50.0 °C(Predicted)
[density ]

1.5402 (estimate)
[storage temp. ]

Sealed in dry,Room Temperature
[form ]

Powder
[color ]

White
[optical activity]

[α]23/D 146°, c = 1 in chloroform
[Water Solubility ]

Insoluble
[Sensitive ]

moisture sensitive
[BRN ]

4282753
[CAS DataBase Reference]

126613-06-7(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

C,Xi
[Risk Statements ]

R34:Causes burns.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S27:Take off immediately all contaminated clothing .
[RIDADR ]

UN 3261 8/PG 2
[WGK Germany ]

3
[F ]

10-21
[Hazard Note ]

Irritant
[HazardClass ]

8
[PackingGroup ]

II
[HS Code ]

29072990
Hazard InformationBack Directory
[Chemical Properties]

white powder
[Uses]

(R)-(?)-1,1′-Bi-2-naphthol bis(trifluoromethanesulfonate) can be used:
  • In the synthesis of heterobidentate ligands for asymmetric catalysis.
  • To prepare 2-(diphenylphosphino)-2′-alkoxy-1,1′-binaphthyls by reacting with bis(aryl) phosphonic acids.
  • As a starting material for the synthesis of binaphthyl based rhodium catalysts used in the hydrogenation of styrene.
Spectrum DetailBack Directory
[Spectrum Detail]

(R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate)(126613-06-7)FT-IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

(R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate), 97%(126613-06-7)
[Sigma Aldrich]

126613-06-7(sigmaaldrich)
[TCI AMERICA]

(R)-(-)-1,1'-Binaphthyl-2,2'-diyl Bis(trifluoromethanesulfonate),>96.0%(LC)(126613-06-7)
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