Identification | More | [Name]
(R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate) | [CAS]
126613-06-7 | [Synonyms]
1,1'-BI-2-NAPHTHOL BIS(TRIFLUOROMETHANESULFONATE) 1,1-BI-2-NAPHTHOL BIS(TRIFLUOROMETHANESULFONATE) 1,1'-BI-2-NAPHTHOL-BIS(TRIFLUOROMETHANESULPHONATE) 1,1'-BINAPHTHYL-2,2'-DIYL BIS(TRIFLUOROMETHANESULPHONATE) 1,1'-BIS(2-NAPHTHOL) DITRIFLATE BINOL-TF2 (R)-(-)-1,1'-BI-2-NAPHTHOL BIS(TRIFLUOROMETHANESULFONATE) (R)-(-)-1,1'-BI-2-NAPHTHOL-BIS(TRIFLUOROMETHANESULPHONATE) (R)-(-)-1,1'-BI-2-NAPHTHYL BIS-TRIFLUOROMETHANESULFONATE (R)-1,1'-BINAPHTHALENE-2,2'-DIYL BIS(TRIFLUOROMETHANESULFONATE) (R)-(-)-1,1'-BINAPHTHOL-2,2'-BIS(TRIFLUOROMETHANESULFONATE) (R)-(-)-1,1'-BINAPHTHYL-2,2'-DIYL BIS(TRIFLUOROMETHANESULFONATE) (R)-1,1'-BINAPHTHYL-2,2'-DIYL BIS(TRIFLUOROMETHANE)SULPHONATE (R)-(-)-1,1'-BIS(2-NAPHTHOL) DITRIFLATE R-BINOL-TF2 (RS)-TRIFLUOROMETHANESULFONIC ACID 2'-TRIFLUOROMETHANESULFONYLOXY-[1,1']BINAPTHALENYL-2-YL ESTER (R)-TRIFLUOROMETHANESULFONIC ACID 2'-TRIFLUOROMETHANSULFONYLOXY-[1,1']BINAPHTHALENYL-2-YL ESTER (S)-(-)-1,1'-BI-2-NAPHTHOL BIS(TRIFLUOROMETHANESULFONATE) (S)-(+)-1,1'-BI-2-NAPHTHOL BIS(TRIFLUOROMETHANESULFONATE) (S)-(+)-1,1'-BI-2-NAPHTHOL-BIS(TRIFLUOROMETHANESULPHONATE) | [Molecular Formula]
C22H18F6O8S2 | [MDL Number]
MFCD00274615 | [Molecular Weight]
588.49 | [MOL File]
126613-06-7.mol |
Chemical Properties | Back Directory | [Appearance]
white powder | [Melting point ]
83-85 °C(lit.)
| [alpha ]
-149 º (c=1, CHCl3) | [Boiling point ]
578.8±50.0 °C(Predicted) | [density ]
1.5402 (estimate) | [storage temp. ]
Sealed in dry,Room Temperature | [form ]
Powder | [color ]
White | [optical activity]
[α]23/D 146°, c = 1 in chloroform | [Water Solubility ]
Insoluble | [Sensitive ]
moisture sensitive | [BRN ]
4282753 | [CAS DataBase Reference]
126613-06-7(CAS DataBase Reference) |
Safety Data | Back Directory | [Hazard Codes ]
C,Xi | [Risk Statements ]
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . S27:Take off immediately all contaminated clothing . | [RIDADR ]
UN 3261 8/PG 2
| [WGK Germany ]
3
| [F ]
10-21 | [Hazard Note ]
Irritant | [HazardClass ]
8 | [PackingGroup ]
II | [HS Code ]
29072990 |
Hazard Information | Back Directory | [Chemical Properties]
white powder | [Uses]
(R)-(?)-1,1′-Bi-2-naphthol bis(trifluoromethanesulfonate) can be used:
- In the synthesis of heterobidentate ligands for asymmetric catalysis.
- To prepare 2-(diphenylphosphino)-2′-alkoxy-1,1′-binaphthyls by reacting with bis(aryl) phosphonic acids.
- As a starting material for the synthesis of binaphthyl based rhodium catalysts used in the hydrogenation of styrene.
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