| Identification | More | [Name]
Scandium trifluoromethanesulfonate | [CAS]
144026-79-9 | [Synonyms]
PS-SC(OTF)2
SCANDIUM(III) TRIFLATE
SCANDIUM(III) TRIFLUOROMETHANESULFONATE
SCANDIUM(III) TRIFLUOROMETHANESULPHONATE
SCANDIUM TRIFLATE
SCANDIUM TRIFLATE RESIN
SCANDIUM TRIFLUOROMETHANESULFONATE
SCANDIUM TRIFLUOROMETHANESULFONATE, POLYMER-BOUND
SC(O3SCF3)3
TRIFLUOROMETHANESULFONIC ACID SCANDIUM(3) SALT
TRIFLUOROMETHANESULFONIC ACID SCANDIUM(III) SALT
TRIFLUOROMETHANESULFONIC ACID SCANDIUM SALT
Scandium (lll) trifluoromethanesulfonate
Scandium(III) triflate, 99.995% metals basis
SCANDIUM (III) TRIFLUOROMETHANESULFONATE, 97+% (SCANDIUM TRIFLATE)
ScandiumTrifluoromethanesulfonate,Microencapsulated
Scandium(III)trifluoromethanesulfonate,min.97%(Scandiumtriflate)
Methanesulfonic acid, trifluoro-, scandium(3+) salt
Scandium(III) trifluoromethanesulphonate 99%
Scandium(III)trifluoromethanesulphonate99% | [Molecular Formula]
C3F9O9S3Sc | [MDL Number]
MFCD00192433 | [Molecular Weight]
492.16 | [MOL File]
144026-79-9.mol |
| Chemical Properties | Back Directory | [Appearance]
White powder | [Melting point ]
>300 °C
| [storage temp. ]
Inert atmosphere,Room Temperature | [solubility ]
Water (Slightly) | [form ]
Powder | [color ]
White | [Water Solubility ]
Soluble in water, alcohol and acetonitrile. | [Hydrolytic Sensitivity]
6: forms irreversible hydrate | [Sensitive ]
Hygroscopic | [BRN ]
8510151 | [Stability:]
hygroscopic | [InChI]
InChI=1S/3CHF3O3S.Sc/c3*2-1(3,4)8(5,6)7;/h3*(H,5,6,7);/q;;;+3/p-3 | [InChIKey]
HZXJVDYQRYYYOR-UHFFFAOYSA-K | [SMILES]
C(F)(S([O-])(=O)=O)(F)F.C(F)(F)(F)S([O-])(=O)=O.C(F)(F)(F)S([O-])(=O)=O.[Sc+3] | [CAS DataBase Reference]
144026-79-9(CAS DataBase Reference) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H315-H319-H335 | [Precautionary statements ]
P261-P305+P351+P338-P280a-P304+P340-P405-P501a | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [WGK Germany ]
3
| [F ]
3-10 | [Hazard Note ]
Irritant | [TSCA ]
No | [HS Code ]
28469099 | [Storage Class]
11 - Combustible Solids |
| Hazard Information | Back Directory | [Description]
Scandium trifluoromethanesulfonate, commonly called Scandium(III) triflate, is a chemical compound with formula Sc(SO3CF3)3, a salt consisting of scandium cations Sc3+ and triflate SO3CF3? anions.
Scandium(III) triflate is an extremely active, efficient, recoverable and reusable acylation catalyst. Its an important catalyst for the Friedel-Crafts acylation, Diels-Alder reactions and other carbon-carbon bond-forming reactions. It also stereochemically catalyzes the radical polymerization of acrylates. Scandium(III) triflate complex of (4′S,5′S)-2,6-bis[4′-(triisopropylsilyl)oxymethyl-5′-phenyl-1′,3′-oxazolin-2′-yl]pyridine has been employed as catalyst for the asymmetric Friedel-Crafts reaction between substituted indoles and methyl (E)-2-oxo-4-aryl-3-butenoates. | [Chemical Properties]
White powder | [Uses]
Scandium(III) trifluoromethanesulfonate is widely used as a catalyst in hydrothiolation, selective two-electron reduction of oxygen by ferrocene derivatives and vinylogous Fridel-crafts alkylation of indoles and pyrrole in water. It is involved in the Mukaiyama aldol addition and stereochemically catalyzes the radical polymerization of acrylates. It acts as a Lewis acid catalyst and used in the synthesis of bullvalone via a stabilized sulfur ylide.? | [Application]
Scandium(III) triflate was used as a catalyst in:
Hydrothiolation reaction of aromatic and aliphatic thiols.
Selective two-electron reduction of O2 by ferrocene derivatives.
Vinylogous Friedel-Crafts alkylation of indoles and pyrroles in water.
Synthesis of β-cyanoketones.
Combination with triethylsilane to reductively open functionalized pyranoside rings.
The key steps of synthesis of bullvalone via a stabilized sulfur ylide. | [Preparation]
Scandium triflate (Scandium trifluoromethanesulfonate) can be prepared from the corresponding oxide (Sc2O3) and aqueous trifluoromethanesulfonic acid (TfOH). After filtration and concentration of the clear aqueous solution in vacuo, the resulting hydrated salt is dried in vacuo (<1 mmHg) at 200?°C for 40 h to afford the anhydrous triflate stored over P2O5.
| [Reactions]
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-
Water tolerant Lewis acid.
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-
Commonly used in a range of Lewis acid catalyzed reactions.
-
-
Efficient metal source for Lewis acid catalyzed asymmetric reactions.
-
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Catalyzes Friedel-Crafts alkylation, acylation and related reactions.
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Catalyzes various domino- and multi-component processes.
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Catalyzes electrophilic additions of alpha-diazoesters with ketones.
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Catalyzes carbon insertion reactions.
| [General Description]
Scandium(III) triflate is an extremely active, efficient, recoverable and reusable acylation catalyst. Its an important catalyst for the Friedel-Crafts acylation, Diels-Alder reactions and other carbon-carbon bond-forming reactions. It also stereochemically catalyzes the radical polymerization of acrylates. Scandium(III) triflate complex of (4′S,5′S)-2,6-bis[4′-(triisopropylsilyl)oxymethyl-5′-phenyl-1′,3′-oxazolin-2′-yl]pyridine has been employed as catalyst for the asymmetric Friedel-Crafts reaction between substituted indoles and methyl (E)-2-oxo-4-aryl-3-butenoates. | [reaction suitability]
core: scandium
reagent type: catalyst |
|
| Company Name: |
J & K SCIENTIFIC LTD.
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18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
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400-6106006 |
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http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
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| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
Jia Xing Isenchem Co.,Ltd
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0573-85285100 18627885956 |
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https://www.chemicalbook.com/ShowSupplierProductsList14265/0_EN.htm |
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