ChemicalBook--->CAS DataBase List--->1277-43-6

1277-43-6

1277-43-6 Structure

1277-43-6 Structure
IdentificationMore
[Name]

BIS(CYCLOPENTADIENYL)COBALT
[CAS]

1277-43-6
[Synonyms]

BIS(CYCLOPENTADIENYL)COBALT
BIS(CYCLOPENTADIENYL)COBALT(II)
COBALTOCENE
bis-(eta5-Cyclopentadienyl) cobalt
Cobalt, bis(eta5-cyclopentadienyl)-
Cobalt, bis(eta5-2,4-cyclopentadien-1-yl)-
Cobalt, di-pi-cyclopentadienyl-
cobalt,bis(η5-2,4-cyclopentadien-1-yl)-
Dicyclopentadienylcobalt
di-pi-cyclopentadienyl-cobal
Kobaltocen
Bis(cyclopentadienyl)cobalt (II), (Cobaltocene)
Bis(cyclopentadienyl)cobalt(II),min.98%(Cobaltocene)
[EINECS(EC#)]

215-061-0
[Molecular Formula]

C10H10Co 10*
[MDL Number]

MFCD00013749
[Molecular Weight]

189.12
[MOL File]

1277-43-6.mol
Chemical PropertiesBack Directory
[Definition]

A metallocene.
[Appearance]

dark violet crystals
[Melting point ]

176-180 °C (dec.)(lit.)
[Boiling point ]

173℃ [CRC10]
[storage temp. ]

0-6°C
[form ]

crystal
[color ]

purplish-black
[Stability:]

Stable, but very reactive and air and moisture sensitive-store under inert gas. Incompatible with strong oxidizing agents. Highly flammable.
[Water Solubility ]

Insoluble in water.
[Sensitive ]

Air & Moisture Sensitive
[InChI]

InChI=1S/2C5H5.Co/c2*1-2-4-5-3-1;/h2*1-5H;
[InChIKey]

PXFGMRZPRDJDEK-UHFFFAOYSA-N
[SMILES]

[CH]1[CH][CH][CH][CH]1.[CH]1[CH][CH][CH][CH]1.[Co] |^1:0,1,2,3,4,5,6,7,8,9|
[Uses]

Polymerization inhibitor of olefins up to 200C, Diels–Alder reaction, catalyst, paint drier, oxygen stripping agent.
[CAS DataBase Reference]

1277-43-6(CAS DataBase Reference)
[EPA Substance Registry System]

Cobaltocene (1277-43-6)
Hazard InformationBack Directory
[Chemical Properties]

dark violet crystals
[General Description]

Black-purple crystals or black solid. Sublimes at 104°F and 0.1 mm Hg.
[Reactivity Profile]

COBALTOCENE(1277-43-6) is very sensitive to air and is readily oxidized. COBALTOCENE(1277-43-6) is also sensitive to exposure to light. Readily oxidized by water and dilute acids .
[Air & Water Reactions]

Air-sensitive. Highly flammable. Insoluble in water.
[Hazard]

Toxic by ingestion.
[Health Hazard]

ACUTE/CHRONIC HAZARDS: This compound is toxic by ingestion.
[Fire Hazard]

Vendor information indicates that this chemical is flammable.
[reaction suitability]

core: cobalt
[Safety Profile]

Poison by intraperitoneal route.Questionable carcinogen with experimental tumorigenicdata. Mutation data reported. When heated todecomposition it emits acrid smoke and fumes.
Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)Health Hazard (GHS08)
GHS02,GHS08
[Signal word ]

Danger
[Hazard statements ]

H228-H317-H334-H341-H351
[Precautionary statements ]

P201-P210-P280-P302+P352-P308+P313
[Hazard Codes ]

F
[Risk Statements ]

R11:Highly Flammable.
[Safety Statements ]

S16:Keep away from sources of ignition-No smoking .
S33:Take precautionary measures against static discharges .
S7/9:Keep container tightly closed and in a well-ventilated place .
[RIDADR ]

UN 1325 4.1/PG 3
[WGK Germany ]

3
[RTECS ]

GG0350000
[TSCA ]

Yes
[HazardClass ]

4.1
[PackingGroup ]

II
[HS Code ]

29319090
[Storage Class]

4.1B - Flammable solid hazardous materials
[Hazard Classifications]

Carc. 2
Flam. Sol. 2
Muta. 2
Resp. Sens. 1
Skin Sens. 1
[Toxicity]

mmo-sat 3333 mg/plate EMMUEG 19(Suppl 21),2,92
Spectrum DetailBack Directory
[Spectrum Detail]

BIS(CYCLOPENTADIENYL)COBALT(1277-43-6)IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Cobaltocene, 98%(1277-43-6)
[Alfa Aesar]

Bis(cyclopentadienyl)cobalt(1277-43-6)
[Sigma Aldrich]

1277-43-6(sigmaaldrich)
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