ChemicalBook--->CAS DataBase List--->4984-82-1

4984-82-1

4984-82-1 Structure

4984-82-1 Structure
IdentificationMore
[Name]

SODIUM CYCLOPENTADIENIDE
[CAS]

4984-82-1
[Synonyms]

CYCLOPENTADIENYLSODIUM
NACP
SODIUM CYCLOPENTADIENIDE
SODIUM CYCLOPENTADIENYLIDE
Cyclopentadienylsodium solution
cyclopenta-2,4-dien-1-ylsodium
SODIUM CYCLOPENTADIENIDE, 2.0M SOLUTION IN TETRAHYDROFURAN
CYCLOPENTADIENYLSODIUM SOLUTION, ~2 M IN THF
Sodium Cyclopentadienide, approx. 20 wt% in THF/Toluene
20%inTHF
Sodiumcyclopentadiene
Sodiumcyclopentadienide,2-3MinTHF
SODIUM CYCLOPENTADIENIDE 2.0 M IN THF
Cyclopentadienylsodium, 0.4 M in tetrahydrofuran
Sodium cyclopentadienide, 2-3M in THF, packaged under Argon in resealable ChemSeal bottles
Sodium cyclopentadienide ,2.0 M in tetrahydrofuran [2.0 M in tetrahydrofuran]
(2,4-Cyclopentadienyl) sodium
2,4-Cyclopentadien-1-ylsodium
2,4-Cyclopentadienylsodium
5-Sodio-1,3-cyclopentadiene
[EINECS(EC#)]

225-636-8
[Molecular Formula]

C5H5Na
[MDL Number]

MFCD00012161
[Molecular Weight]

88.08
[MOL File]

4984-82-1.mol
Chemical PropertiesBack Directory
[Appearance]

White to greyish or yellowish powder
[Melting point ]

172 °C
[density ]

0.946 g/mL at 20 °C
[Fp ]

1 °F
[storage temp. ]

2-8°C
[color ]

dark red
[Water Solubility ]

Reacts with water.
[Sensitive ]

Air & Moisture Sensitive
[Detection Methods]

T
[BRN ]

969542
[InChIKey]

PDTZVKVFAJGNRV-UHFFFAOYSA-N
[CAS DataBase Reference]

4984-82-1(CAS DataBase Reference)
[EPA Substance Registry System]

Sodium, 2,4-cyclopentadien-1-yl- (4984-82-1)
Safety DataBack Directory
[Hazard Codes ]

F,Xi
[Risk Statements ]

R11:Highly Flammable.
R19:May form explosive peroxides.
R34:Causes burns.
[Safety Statements ]

S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 1993 3/PG 2
[WGK Germany ]

3
[F ]

1-10
[TSCA ]

Yes
[HazardClass ]

4.3
[PackingGroup ]

II
[HS Code ]

29319090
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sodium hydroxide-->Tetrahydrofuran-->Sodium-->Toluene-->Dicyclopentadiene-->Methyl Orange
[Preparation Products]

2-Amino-1,9-dihydro-9-[(1S,3R,4S)-4-(benzyloxy)-3-(benzyloxymethyl)-2-methylenecyclopentyl]-6H-purin-6-one-->(1s-trans)-2-[(phenylmethoxy)methyl]-3-cyclopenten-1-ol-->6-(Benzyloxy)-9-((1S,3S)-4-(benzyloxy)-3-((benzyloxy)methyl)-2-methylenecyclopentyl)-N-((4-methoxyphenyl)diphenylmethyl)-9H-purin-2-amine-->SPIRO[2.4]HEPTA-4,6-DIENE
Hazard InformationBack Directory
[Chemical Properties]

White to greyish or yellowish powder
[Uses]

Sodium cyclopentadienide is used as a reagent for the preparation of metallocenes. It is used to prepare Cp-cobaltacycles from diphenylphosphinoalkynes and CoCl(PPh3)3. It is a useful reagent for the preparation of metallocenes and cyclopentadienyl metal complexes.
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Sodium cyclopentadienide(4984-82-1)
[Alfa Aesar]

Sodium cyclopentadienide, 2-3M in THF(4984-82-1)
[Sigma Aldrich]

4984-82-1(sigmaaldrich)
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