| | Identification | More |  | [Name] 
 1-Nitroso-2-naphthol
 |  | [CAS] 
 131-91-9
 |  | [Synonyms] 
 1-NITROSO-2-NAPHTHOL
 ALPHA-NITROSO-BETA-NAPHTHOL
 CI NO 10005
 LABOTEST-BB LT00068477
 TIMTEC-BB SBB009148
 1,2-Napthtoquinone 1-oxime
 1-Nitroso-2-naftol
 1-nitroso-2-naphthaleno
 1-Nitroso-2-naphthalenol
 1-nitroso-2-naphtho
 2-Naphthol, 1-nitroso-
 alpha-Nitroso-beta-naftol
 alpha-Nitrosonaphthol
 Nitroso-beta-naphthol
 Zelen moridlova 4
 zelenmoridlova4
 α-Nitroso-β-nophthol
 1-nitroso-2-naphthol (alpha-beta)
 1-nitrosonaphthalen-2-ol
 2-Hydroxy-1-nitrosonaphthalene
 |  | [EINECS(EC#)] 
 205-043-0
 |  | [Molecular Formula] 
 C10H7NO2
 |  | [MDL Number] 
 MFCD00003884
 |  | [Molecular Weight] 
 173.17
 |  | [MOL File] 
 131-91-9.mol
 | 
 | Chemical Properties | Back Directory |  | [Appearance] 
 brown powder
 |  | [Melting point ] 
 106-108 °C (dec.) (lit.)
 |  | [Boiling point ] 
 303.81°C (rough estimate)
 |  | [density ] 
 1.2427 (rough estimate)
 |  | [refractive index ] 
 1.5200 (estimate)
 |  | [storage temp. ] 
 Keep in dark place,Sealed in dry,Room Temperature
 |  | [Colour Index ] 
 10005
 |  | [form ] 
 crystalline
 
 |  | [pka] 
 7.87±0.10(Predicted)
 |  | [color ] 
 tan to brown
 
 |  | [Water Solubility ] 
 insoluble
 |  | [Merck ] 
 14,6641
 |  | [BRN ] 
 776947
 |  | [Uses] 
 Organic synthesis, prevention of gum formation
in gasoline, dye intermediate, analytical reagent.
 |  | [CAS DataBase Reference] 
 131-91-9(CAS DataBase Reference)
 |  | [NIST Chemistry Reference] 
 2-Naphthalenol, 1-nitroso-(131-91-9)
 |  | [EPA Substance Registry System] 
 131-91-9(EPA Substance)
 | 
 | Safety Data | Back Directory |  | [Hazard Codes ] 
 Xn
 |  | [Risk Statements ] 
 R22:Harmful if swallowed.
 R36/37/38:Irritating to eyes, respiratory system and skin .
 R33:Danger of cumulative effects.
 R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
 |  | [Safety Statements ] 
 S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
 S36:Wear suitable protective clothing .
 S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
 |  | [RIDADR ] 
 UN3077
 |  | [WGK Germany ] 
 3
 
 |  | [RTECS ] 
 QL4725000
 
 |  | [F ] 
 8
 |  | [TSCA ] 
 Yes
 |  | [HazardClass ] 
 9
 |  | [PackingGroup ] 
 III
 |  | [HS Code ] 
 29089000
 |  | [Toxicity] 
 LDLo orl-rat: 500 mg/kg NCNSA6 5,35,53
 | 
 | Hazard Information | Back Directory |  | [Chemical Properties] 
 brown powder
 |  | [Definition] 
 ChEBI: 1-Nitroso-2-naphthol is a member of naphthols.
 |  | [Safety Profile] 
 Moderately toxic by ingestion.Many nitroso compounds are carcinogens. Ignites whenheated to 124°C. Mutation data reported. When heated todecomposition it emits toxic fumes of NOx.
 |  | [Purification Methods] 
 Crystallise the naphthol from pet ether (b 60-80o, 7.5mL/g). [Beilstein 7 H 712, 7 IV 2419.]
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