| Identification | Back Directory | [Name]
(+/-)-cis-Bicyclo[3.2.0]hept-2-en-6-one | [CAS]
13173-09-6 | [Synonyms]
Bicyclohepten
BICYCLO[3.2.0]HEPT-2-EN-6-ONE
bicyclo[3.2.0]hept-3-en-7-one
Bicyclo(3.2.0)hept-2-en-6-one,96%
Bicyclo3.2.0ühept-2-en-6-one, 97%
(+/-)-cis-Bicyclo[3.2.0]hept-2-en-6-one
Bicyclo[3.2.0]hept-2-en-6-one bisulphite adduct
(+/-)-cis-Bicyclo[3.2.0]hept-2-en-6-one >=98.0%
low price (+/-)-cis-Bicyclo[3.2.0]hept-2-en-6-one
(±)-cis-Bicyclo[3.2.0]hept-2-en-6-one | [Molecular Formula]
C7H8O | [MDL Number]
MFCD00066201 | [MOL File]
13173-09-6.mol | [Molecular Weight]
108.14 |
| Chemical Properties | Back Directory | [Boiling point ]
158-160 °C(lit.)
| [density ]
1.025 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.4820(lit.)
| [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [Appearance]
Colorless to light yellow Liquid | [Sensitive ]
Air Sensitive | [InChI]
InChI=1S/C7H8O/c8-7-4-5-2-1-3-6(5)7/h1-2,5-6H,3-4H2 | [InChIKey]
LNLLHUHPGPKRBM-UHFFFAOYSA-N | [SMILES]
C12C(C(=O)C1)CC=C2 |
| Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
22-37/38-41 | [Safety Statements ]
26-39 | [RIDADR ]
UN1224 | [WGK Germany ]
3
| [F ]
10-23 | [HazardClass ]
3 | [PackingGroup ]
III | [HS Code ]
29337900 | [Storage Class]
10 - Combustible liquids | [Hazard Classifications]
Acute Tox. 4 Oral
Eye Dam. 1
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Uses]
Bicyclo[3.2.0]hept-2-en-6-one is widely utilized to study enantioselective Baeyer-Villiger oxidation of (±)-cis-bicyclo(3.2.0)hept-2-en-6-one. It is used in the synthesis of a series of chalcone derivatives by reacting with arylaldehydes. It is also used to analyze the extremophile enzymes (monooxygenase and hydrolases) in microorganisms which are isolated from a deep-water petroleum reservoir and at high temperatures using fluorogenic assays and multibioreactions. | [General Description]
(±)-cis-bicyclo(3.2.0)hept-2-en-6-one undergoes preparative scale Baeyer–Villiger biooxidation at high concentration using recombinant Escherichia coli biocatalyst and adsorbent resin (in situ substrate feeding and product removal). |
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