ChemicalBook--->CAS DataBase List--->55716-66-0

55716-66-0

55716-66-0 Structure

55716-66-0 Structure
IdentificationBack Directory
[Name]

4-Aminobenzocyclobutene
[CAS]

55716-66-0
[Synonyms]

4-AMBCB
4-Aminobenzocyclobutene
4-(cyclobut-1-en-1-yl)aniline
1,2-DIHYDROCYCLOBUTABENZEN-5-AMINE
Bicyclo[4.2.0]octa-1,3,5-trien-3-amine
bicyclo[4.2.0]octa-1(6),2,4-trien-4-amine
Bicyclo[4.2.0]octa-1,3,5,7-tetraen-3-aMine
4-Aminobenzocyclobutene ISO 9001:2015 REACH
4-bicyclo[4.2.0]octa-1(6),2,4,7-tetraenamine
4-AMBCB 4-Aminobenzocyclobutene
[Molecular Formula]

C8H9N
[MDL Number]

MFCD09834064
[MOL File]

55716-66-0.mol
[Molecular Weight]

119.16
Chemical PropertiesBack Directory
[Boiling point ]

257.3±29.0 °C(Predicted)
[density ]

1.156±0.06 g/cm3(Predicted)
[storage temp. ]

Keep in dark place,Sealed in dry,2-8°C
[pka]

5.17±0.20(Predicted)
[InChI]

InChI=1S/C8H9N/c9-8-4-3-6-1-2-7(6)5-8/h3-5H,1-2,9H2
[InChIKey]

JTXHBTQCQCFUQW-UHFFFAOYSA-N
[SMILES]

C12C(CC1)=CC=C(N)C=2
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319
[Precautionary statements ]

P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313
Hazard InformationBack Directory
[Uses]

4-Aminobenzocyclobutene can be used as a starting material for the synthesis of novel BCB-functionalised monomers. It is synthesised by subjecting a siloxane containing a dianhydride to an imidisation reaction with 4-aminobenzocyclobutene. The resulting BCB monomer exhibits good solubility in common organic solvents such as ethanol, acetone and dichloromethane. They were converted into cross-linked polymers via ring-opening and the subsequent Diels–Alder reaction at an appropriate temperature. The resulting BCB polymers (BCB resins) exhibit good thermal stability, excellent dielectric properties, low water absorption and good flatness.[1]
[Preparation]

4-Aminobenzocyclobutene is prepared from 4-bromobenzocyclobutene using Cu2O as a catalyst[1].
[References]

[1] Jun Yang. (2013). Synthesis and properties of novel benzocyclobutene-functionalized siloxane thermosets. Polymer International, 62 12, 1684–1691. https://doi.org/10.1002/pi.4467
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