ChemicalBook--->CAS DataBase List--->133745-75-2

133745-75-2

133745-75-2 Structure

133745-75-2 Structure
IdentificationMore
[Name]

N-Fluorobenzenesulfonimide
[CAS]

133745-75-2
[Synonyms]

N-FLUOROBENZENESULFONAMIDE
N-FLUOROBENZENESULFONIMIDE
N-FLUOROBENZENESULPHONIMIDE
N-FLUOROBIS(PHENYLSULFONYL)AMINE
N-FLUORODIBENZENESULFONAMIDE
N-FLUORODIBENZENESULFONIMIDE
N-FLUORODI(BENZENESULFONYL)AMINE
NFSI
N-Fluoro Dibenzenesulfonic amide
Benzenesulfonamide, N-fluoro-N-(phenylsulfonyl)-
accufluor nfsi
N-Fluorodibenzenesulfonimide (NFSI)
N-Fluorobenzenesulfonimide [Fluorinating Reagent]
N-Fluorodi(benzenesulfonyl)amine, N-Fluorodibenzenesulfonimide, NFSI
N-Fluorobenzenesulfonimide, N-Fluorodibenzenesulfonimide, NFSI
bis(phenylsulfonyl)fluoroamine (N-FLUOROBENZENESULFONIMIDE)
Bis(phenylsulfonyl)fluoroamine
[EINECS(EC#)]

-0
[Molecular Formula]

C12H10FNO4S2
[MDL Number]

MFCD00144885
[Molecular Weight]

315.34
[MOL File]

133745-75-2.mol
Chemical PropertiesBack Directory
[Appearance]

Off-white to light brown crystalline powder
[Melting point ]

114-116 °C
[Boiling point ]

471.4±28.0 °C(Predicted)
[density ]

1.4466 (estimate)
[Fp ]

110℃
[storage temp. ]

Keep in dark place,Inert atmosphere,Room temperature
[solubility ]

Very soluble in acetonitrile, dichloromethane or THF and less soluble in toluene.
[form ]

solid
[pka]

-32.45±0.70(Predicted)
[color ]

white
[BRN ]

5348902
[InChI]

InChI=1S/C12H10FNO4S2/c13-14(19(15,16)11-7-3-1-4-8-11)20(17,18)12-9-5-2-6-10-12/h1-10H
[InChIKey]

RLKHFSNWQCZBDC-UHFFFAOYSA-N
[SMILES]

C1(S(N(F)S(C2=CC=CC=C2)(=O)=O)(=O)=O)=CC=CC=C1
[CAS DataBase Reference]

133745-75-2(CAS DataBase Reference)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P264-P271-P280-P302+P352-P305+P351+P338
[Hazard Codes ]

Xi,O
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection .
[WGK Germany ]

3
[F ]

10
[Hazard Note ]

Oxidising Agent
[TSCA ]

No
[HazardClass ]

IRRITANT
[HS Code ]

29350090
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Hazard InformationBack Directory
[Chemical Properties]

Off-white to light brown crystalline powder
[Uses]

Versatile fluorinating reagent used in the fluorination of aryls, enolates, carbanions, organolithiums, etc.
[Application]

N-Fluorobenzenesulfonimide is a mild electrophilic fluorinating reagent, that can also be used as a strong oxidant for the promotion of reductive elimination from transition metals.
[General Description]

N-Fluorobenzenesulfonimide (NFSi) is a commonly used electrophilic fluorinating agent in organic synthesis to introduce fluorine into neutral organic molecules. It is also used to fluorinate nucleophilic substrates such as reactive organometallic species and malonate anions.
NFSi can be synthesized by the reaction of benzenesulfonimide with fluorine.
[Synthesis]

There are two main methods for the production of N-fluorobenzenesulfonamide, the first Differding method, the specific preparation process is: diphenylsulfonimide dissolved in acetonitrile, add sodium fluoride, the mixture cooled down to -35 ° C, the v

Spectrum DetailBack Directory
[Spectrum Detail]

N-Fluorobenzenesulfonimide(133745-75-2)MS
N-Fluorobenzenesulfonimide(133745-75-2)1HNMR
N-Fluorobenzenesulfonimide(133745-75-2)13CNMR
N-Fluorobenzenesulfonimide(133745-75-2)IR1
N-Fluorobenzenesulfonimide(133745-75-2)IR2
N-Fluorobenzenesulfonimide(133745-75-2)Raman
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

N-Fluorobenzenesulfonimide, 97%(133745-75-2)
[TCI AMERICA]

N-Fluorobenzenesulfonimide  [Fluorinating Reagent],>95.0%(T)(133745-75-2)
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