ChemicalBook--->CAS DataBase List--->24307-26-4

24307-26-4

24307-26-4 Structure

24307-26-4 Structure
IdentificationMore
[Name]

Mepiquat chloride
[CAS]

24307-26-4
[Synonyms]

1,1-DIMETHYLPIPERIDINIUM CHLORIDE
AGRO-FIX
BAS 08300W
MEGAHIX
MEPEX
MEPIQUAT CHLORIDE
N,N-DIMETHYLPIPERDINIUM CHLORIDE
N,N-DIMETHYL-PIPERIDINIUM CHLORIDE
PIX
PIX(R)
ROQUAT
TOPIT
1,1-dimethyl-piperidiniuchloride
1,1-Dimethylpiperidyliumchloride
bas-083
bas08301w
bas08305w
bas08306w
bas08307w
bas85559x
[EINECS(EC#)]

246-147-6
[Molecular Formula]

C7H16ClN
[MDL Number]

MFCD00055543
[Molecular Weight]

149.66
[MOL File]

24307-26-4.mol
Chemical PropertiesBack Directory
[Appearance]

White crystalline solid, off-white powder, or pinkish liquid. Slightly sweet, musty odor;
[Melting point ]

285°C
[Boiling point ]

245.45°C (rough estimate)
[density ]

0.9989 (rough estimate)
[refractive index ]

1.5760 (estimate)
[storage temp. ]

0-6°C
[solubility ]

Methanol (Slightly), Water
[form ]

neat
[color ]

Light Brown
[Specific Gravity]

1.187
[Odor]

Slightly sweet, musty smell
[Merck ]

14,5857
[BRN ]

3914089
[Henry's Law Constant]

3.3×1011 mol/(m3Pa) at 25℃, Maniere et al. (2011)
[Stability:]

Hygroscopic
[Major Application]

agriculture
environmental
[InChI]

1S/C7H16N.ClH/c1-8(2)6-4-3-5-7-8;/h3-7H2,1-2H3;1H/q+1;/p-1
[InChIKey]

VHOVSQVSAAQANU-UHFFFAOYSA-M
[SMILES]

[Cl-].C[N+]1(C)CCCCC1
[CAS DataBase Reference]

24307-26-4(CAS DataBase Reference)
[EPA Substance Registry System]

24307-26-4(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H302-H412
[Precautionary statements ]

P264-P270-P273-P301+P312-P501
[Hazard Codes ]

Xn
[Risk Statements ]

R22:Harmful if swallowed.
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
[Safety Statements ]

S61:Avoid release to the environment. Refer to special instructions safety data sheet .
[RIDADR ]

Not a regulated material.
[WGK Germany ]

2
[RTECS ]

TN4939200
[TSCA ]

TSCA listed
[HS Code ]

29333990
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Acute Tox. 4 Oral
Aquatic Chronic 3
[Hazardous Substances Data]

24307-26-4(Hazardous Substances Data)
[Toxicity]

LD50 in mice, rats (mg/kg): 780, 464 orally; in rats (mg/kg): >2000 dermally (BASF Agric. Chem. Div.)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Chloroform-->Formaldehyde-->Formic acid-->Piperidine-->Chloromethane-->Glyoxylic acid-->Aluminium-nickel-->N-Methylpiperidine-->1,1-Dimethylpiperidinium iodide
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

N,N-Dimethylpiperidinium chloride(24307-26-4).msds
Hazard InformationBack Directory
[Hazard]

Moderately toxic by ingestion. Low toxicity by inhalation and skin contact.
[Potential Exposure]

A quarternary ammonium salt herbicide and plant growth regulator registered solely for use on cotton, to control growth and yield
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions) if breathing has stopped, and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit
[Shipping]

UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required
[Incompatibilities]

Decomposes in temperatures above 320℃. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides.
[Chemical Properties]

White crystalline solid, off-white powder, or pinkish liquid. Slightly sweet, musty odor;
[Waste Disposal]

Do not discharge into drains or sewers. Dispose of waste material as hazardous waste using a licensed disposal contractor to an approved landfill. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Incineration with effluent gas scrubbing is recommended. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Noncombustible containers should be compacted and buried under more than 16 in/40 cm. of soil. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.
[Uses]

Mepiquat Chloride is a plant growth regulator used to improve crop quality and maximize yield.
[Uses]

Plant growth regulator.
[Definition]

ChEBI: A quaternary ammonium salt consisting of equimolar amounts of mepiquat cations and chloride anions. A plant growth regulator, it is used in agriculture to reduce vegetative growth including sprout suppression in garlic, leeks and onions.
[Production Methods]

The industrial synthesis of mepiquat chloride begins with the preparation of N-methylpiperidine, which serves as the core nitrogen-containing ring. This intermediate undergoes quaternisation, a key step where it reacts with chloromethyl compounds such as methyl chloride or chloromethyl acetate under controlled temperature and pressure to form the quaternary ammonium salt, mepiquat chloride. The reaction is typically carried out in aqueous or polar organic solvents, and the product is isolated by crystallisation or solvent evaporation. Continuous production methods have been developed to improve efficiency and reduce waste, including inline monitoring and purification systems.
[Agricultural Uses]

Herbicide, Plant growth regulator: Registered solely for cotton, to control the growth and yield.
[Trade name]

BAS 083 01 W®; BAS 85559X®; MEPEX®; MEPICHLOR®; MEPPLUS®; PIX®; PONNAX®; ROQUAT®; TERPAL® (with Ethephon)
[Mechanism of action]

Gibberellin biosynthesis inhibitor
[Pesticide Type]

Plant Growth Regulator
Questions And AnswerBack Directory
[Description]

Mepiquat chloride (N, N-dimethylpiperidinium chloride), well known as PIX, is a potential systemic plant growth regulator. It is applied in cereals including wheat, oats, barley, rye, triticale and is extensively used in the cotton production. It is intended to increase yield by inhibiting gibberellic acid synthesis. The use of mepiquat chloride results in a shorter and more compact plant, lower leaf area index due to smaller leaf size and earlier maturity.
[References]

[1] X. Ren, L. Zhang, M. Du, J. Evers, W. van der Werf, X Tian and Z. Li, Managing mepiquat chloride and plant density for optimal yield and quality of cotton, Field Crops Research, 2013, vol. 149, 1-10
[2] Amarjit Basra, Plant Growth Regulators in Agriculture and Horticulture: Their Role and Commercial Use, 2000
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

24307-26-4(sigmaaldrich)
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