ChemicalBook--->CAS DataBase List--->13465-84-4

13465-84-4

13465-84-4 Structure

13465-84-4 Structure
IdentificationMore
[Name]

SILICON (IV) IODIDE
[CAS]

13465-84-4
[Synonyms]

SILICON IODIDE
SILICON (IV) IODIDE
SILICON TETRAIODIDE
TETRAIODOSILANE
SiI4
Silane, tetraiodo-
tetraiodo-silan
Siliconiodidemetalsbasisoffwhitepowder
SILICON TETRAIODIDE, 99.9+%
Silicon(IV)iodide,99.9%(metalsbasis)
Silicon(IV)iodide(99.9%-Si)
Silicon(IV) iodide, 99% (metals basis)
Silicon(IV) iodide, 99.999% (metals basis)
Tetraiodosilicon
[EINECS(EC#)]

236-706-2
[Molecular Formula]

I4Si
[MDL Number]

MFCD00054041
[Molecular Weight]

535.7
[MOL File]

13465-84-4.mol
Chemical PropertiesBack Directory
[Appearance]

White crystals. Noncombustible.
[Melting point ]

120 °C
[Boiling point ]

287.4 °C
[density ]

4.198
[Fp ]

287.5°C
[form ]

Lumps
[color ]

White
[Specific Gravity]

4.198
[Water Solubility ]

Soluble in organic solvents. Insoluble in water.
[Hydrolytic Sensitivity]

8: reacts rapidly with moisture, water, protic solvents
[Sensitive ]

Moisture Sensitive
[CAS DataBase Reference]

13465-84-4(CAS DataBase Reference)
[EPA Substance Registry System]

Silane, tetraiodo- (13465-84-4)
Safety DataBack Directory
[Hazard Codes ]

T
[Risk Statements ]

R24/25:Toxic in contact with skin and if swallowed .
R34:Causes burns.
R42/43:May cause sensitization by inhalation and skin contact .
R61:May cause harm to the unborn child.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S53:Avoid exposure-obtain special instruction before use .
[RIDADR ]

3260
[TSCA ]

Yes
[HazardClass ]

8
[PackingGroup ]

II
Hazard InformationBack Directory
[Hazard]

Toxic by ingestion and inhalation, irritant to tissue.
[Chemical Properties]

White crystals. Noncombustible.
[Uses]

Silicon(IV) iodide is used as a precursor to prepare silicon amides. It finds application in the manufacture and etching of silicon in microelectronics.
Questions And AnswerBack Directory
[Description]

Silicon Iodide is the iodide of silicon. It is a precursor to silicon amide. It is also applied in the manufacture and etching of silicon in microelectronics. Selective area regrowth of silicon-doped GaAs has been successfully achieved by chemical beam epitaxy (CBE) on dry etched trench structures. Silicon tetraiodide is useful for the above process in abrupt to manipulate metal-semiconductor field effect transistor (MESFET) and heterostructure field effect transistor (HFET). Silicon iodide can also be reduced as the source to form pure silicon and hydrogen iodide.
[Reference]

  1. Izumi, Shigekazu, et al. Journal of Crystal Growth 175.175(1997): 404-410.
  2. http://jes.ecsdl.org/content/104/11/663.short
  3. https://en.wikipedia.org/wiki/Silicon_tetraiodide
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Silicon(IV) iodide, 99.999% (metals basis)(13465-84-4)
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