| Identification | More | [Name]
DEUTERIUM BROMIDE | [CAS]
13536-59-9 | [Synonyms]
DEUTERIUM BROMIDE HYDROBROMIC ACID-D Deuterium Bromide (45% in D2O) Deuterium bromide solution DEUTERIUM BROMIDE, 47 WT. % SOLUTION IN D2O, 99+ ATOM % D DEUTERIUM BROMIDE, 99 ATOM % D DEUTERIUM BROMIDE 99 PLUS ATOM % D*47% S OLUTION IN 48%inD2O n-Deuterium Bromide (45% w/w in D2O) hydrogen bromide, deuterated Deuterium Bromide >99.0 Atom % D Deuterium bromide, 48% w/w in D2O, 99+% (Isotopic) Deuterium Bromide 98.0atom%D (45% in D2O) (2H)Hydridebromine Hydrogen bromide (1D) Hydrogen bromide (D) Deuterium bromide, 46 wt% in Deuterium oxide | [EINECS(EC#)]
236-894-6 | [Molecular Formula]
BrD | [MDL Number]
MFCD00044232 | [Molecular Weight]
81.92 | [MOL File]
13536-59-9.mol |
| Chemical Properties | Back Directory | [Appearance]
clear colorless to slightly yellow solution | [Melting point ]
−87 °C(lit.)
| [Boiling point ]
126 °C(lit.)
| [density ]
1.537 g/mL at 25 °C
| [vapor density ]
2.71 (20 °C, vs air)
| [vapor pressure ]
334.7 psi ( 21 °C)
| [Fp ]
126°C | [solubility ]
Water (Soluble) | [form ]
Liquid | [color ]
Colorless | [Water Solubility ]
soluble H2O [CRC10] | [Sensitive ]
Moisture Sensitive | [InChI]
InChI=1S/BrH/h1H/i/hD | [InChIKey]
CPELXLSAUQHCOX-DYCDLGHISA-N | [SMILES]
Br[2H] | [CAS DataBase Reference]
13536-59-9(CAS DataBase Reference) | [CAS Number Unlabeled]
10035-10-6 |
| Hazard Information | Back Directory | [Chemical Properties]
clear colorless to slightly yellow solution | [Description]
Deuterium bromide is stored either as a liquid at a low temperature or as a gas in a sealed glass flask. Pure DBr reacts with Hg only on long exposure.
| [Uses]
NMR Solvent | [Preparation]
The vacuum-sealed ampoules with the starting materials are broken by vigorous shaking in an evacuated 5-liter flask closed by a ground glass stopper with a stopcock. To complete the deuterolysis, the mixture is left standing in the dark for two days, with occasional shaking. The reaction should not be accelerated by heating or disproportionation (4 D3PO3 = 3 D3P04 + PD3) will occur, and the DBr will be contaminated with PD3. After sealing the flask to a high vacuum system, the impure gas is condensed in a receiver cooled with liquid nitrogen and purified by fractional distillation, using a low-temperature distillation flask.only half of the deuterium feed is converted to desired products.
|
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed . R34:Causes burns. | [Safety Statements ]
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) . S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 1788 8/PG 2
| [WGK Germany ]
3 | [HazardClass ]
8 | [PackingGroup ]
II | [HS Code ]
2845901000 |
|
| Company Name: |
Alfa Aesar
|
| Tel: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Tel: |
021-021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
|