ChemicalBook--->CAS DataBase List--->7789-33-5

7789-33-5

7789-33-5 Structure

7789-33-5 Structure
IdentificationMore
[Name]

IODINE MONOBROMIDE
[CAS]

7789-33-5
[Synonyms]

BROMINE IODIDE
HANUS SOLUTION
IODINE BROMIDE
IODINE MONOBROMIDE
IODINE SOLUTION ACCORDING TO HANUS
IODOBROMIDE
IODOMONOBROMIDE
IBr
Iodine bromide (IBr)
Iodine(I)bromide
iodinebromide(ibr)
Bromoiodine
IODINE MONOBROMIDE, 1.0M SOLUTION IN DIC HLOROMETHANE
HANUS SOL FOR THE DET. OF IODINE VALUE
IODINE MONOBROMIDE BOTTLE OF 100 G
IODINE 0,1 MOL IBR/L, VOLUMETRIC SOLUTIO N ACCORDING TO HANUS
IodineMonobromide-(IodineBromide,Bromoiodine)[AmpulePacking]
Iodinebromide,99%min
Iodinebromide,98%
iodine according to hanus for the iodine value determination
[EINECS(EC#)]

232-159-9
[Molecular Formula]

BrI
[MDL Number]

MFCD00011353
[Molecular Weight]

206.81
[MOL File]

7789-33-5.mol
Chemical PropertiesBack Directory
[Appearance]

dark grey to brownish-black crystalline mass,
[Melting point ]

42-50 °C (lit.)
[Boiling point ]

116 °C
[density ]

4.416 g/mL at 25 °C(lit.)
[Fp ]

116°C
[storage temp. ]

Refrigerator (+4°C)
[solubility ]

Aqueous Base (Slightly), Methanol (Slightly), Water (Slightly)
[form ]

Solution
[color ]

Dark red
[Specific Gravity]

4.4157
[PH]

<1 (H2O, 20°C)
[Water Solubility ]

Soluble in water, alcohol, ether, carbon disulfide and glacial acetic acid.
[Specific Heat Capacity]

Cp(gas):0.176007J/(g·K),at 25℃
[Sensitive ]

Moisture & Light Sensitive
[Merck ]

14,5016
[BRN ]

3902973
[Henry's Law Constant]

2.4×10-1 mol/(m3Pa) at 25℃, Wagman et al. (1982)
[Stability:]

Light Sensitive
[InChI]

1S/BrI/c1-2
[InChIKey]

CBEQRNSPHCCXSH-UHFFFAOYSA-N
[SMILES]

BrI
[Uses]

Organic synthesis.
[CAS DataBase Reference]

7789-33-5(CAS DataBase Reference)
[EPA Substance Registry System]

Iodine bromide (IBr) (7789-33-5)
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

R34:Causes burns.
R35:Causes severe burns.
R10:Flammable.
R40:Limited evidence of a carcinogenic effect.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S27:Take off immediately all contaminated clothing .
[RIDADR ]

UN 3264 8/PG 2
[WGK Germany ]

3
[F ]

1-8
[TSCA ]

Yes
[HazardClass ]

8
[PackingGroup ]

II
[HS Code ]

28129090
[Storage Class]

8A - Combustible corrosive hazardous materials
[Hazard Classifications]

Eye Dam. 1
Skin Corr. 1B
STOT SE 3
[Hazardous Substances Data]

7789-33-5(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

iodine-->Carbon dioxide
[Preparation Products]

BROMINE TRIFLUORIDE
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

iodine bromide(7789-33-5).msds
Hazard InformationBack Directory
[Hazard]

Toxic by ingestion and inhalation, vapors corrosive to tissue.
[Chemical Properties]

dark grey to brownish-black crystalline mass,
[Preparation]

Prepared from the elements, excess Br is removed by heating to 50 °C in a current of CO2.
[Health Hazard]

Vapors of iodine monobromide are irritatingto the skin, eyes, and mucous membranes.Its concentrated solutions are corrosive to theskin. Toxicity data for this compound are notavailable.
[Fire Hazard]

Noncombustible solid. The molten salt ex plodes when mixed with potassium, and ignites with finely divided aluminum. Its mixture with sodium explodes on impact. The reaction of phosphorus with molten salt is violent.
[reaction suitability]

reagent type: oxidant
[Purification Methods]

The brown-black crystals are purified by repeated fractional crystallisation from its melt. The vapour dissociates on heating [Yost et al. J Amer Chem Soc 55 552 1933, Schmeisser in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I pp 291-292 1963].
[Precautions]

corrosive solid and vapor; readily absorbed through skin and mucous membranes; use in a fume hood and wear gloves and appropriate protective clothing; air-, moisture-, and light-sensitive; should be stored refrigerated (under N2) in a tightly sealed amber bottle. Forms explosive mixtures with potassium and sodium, and reacts extremely exothermically with phosphorus and tin.
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Iodine monobromide, 98%(7789-33-5)
[Alfa Aesar]

Iodine monobromide, 98%(7789-33-5)
[Sigma Aldrich]

7789-33-5(sigmaaldrich)
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