ChemicalBook--->CAS DataBase List--->13569-65-8

13569-65-8

13569-65-8 Structure

13569-65-8 Structure
IdentificationMore
[Name]

Rhodium chloride trihydrate
[CAS]

13569-65-8
[Synonyms]

RHODIUM CHLORIDE
RHODIUM CHLORIDE, HYDROUS
RHODIUM CHLORIDE TRIHYDRATE
RHODIUM(III) CHLORIDE TRIHYDRATE
RHODIUM TRICHLORIDE, HYDRATE
RHODIUM TRICHLORIDE TRIHYDRATE
Rhodium (III) chloride solution
RHODIUM(III) CHLORIDE-3-HYDRATE PACKAGE&
RhodiumTrichlorideForSynthesis
RHODIUM(III) CHLORIDE TRIHYDRATE (38% RH)
Rhodium (III) chloride cryohydrate
Rhodium chloride (RhCl3), trihydrate
Triaquatrichlororhodium
[EINECS(EC#)]

682-140-8
[Molecular Formula]

Cl3H6O3Rh
[MDL Number]

MFCD00149840
[Molecular Weight]

263.31
[MOL File]

13569-65-8.mol
Chemical PropertiesBack Directory
[Description]

Rhodium trichloride is an odourless, red-brown to black crystalline powder. It is corrosive to steel and aluminium. It is hygroscopic and absorbs moisture or water from the air. It is incompatible with strong oxidising agents. On decomposition, rhodium trichloride emits hydrogen chloride, carbon monoxide, carbon dioxide, and rhodium/rhodium oxides.
[Appearance]

Rhodium trichloride is a red-brown or black, odorless solid or liquid
[Melting point ]

100 °C (decomp)
[density ]

1 g/cm3
[storage temp. ]

Sealed in dry,Room Temperature
[CAS DataBase Reference]

13569-65-8(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

22-41
[Safety Statements ]

26-36/39
[RIDADR ]

3260
[WGK Germany ]

WGK 1 slightly water endangering
[HazardClass ]

8
[PackingGroup ]

III
[HS Code ]

28439090
[Toxicity]

LD50 orally in Rabbit: 753 mg/kg LD50 dermal Rabbit > 2000 mg/kg
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Rhodium chloride trihydrate(13569-65-8).msds
Hazard InformationBack Directory
[Potential Exposure]

Rhodium trichloride is used in hydro- silylation, hydrogenation, carbonylation, oxidation, aryla- tion. See also “Rhodium Metal.” In plating operations and in catalyst preparation, the metal will be used as the trichloride.
[First aid]

Move victim to fresh air. Call 911 or emergency medical service. Give artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respira- tion with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In case of contact with substance, immediately flush skin or eyes with run- ning water for at least 20 minutes. For minor skin contact, avoid spreading material on unaffected skin. Keep victim warm and quiet. Effects of exposure (inhalation, ingestion, or skin contact) to substance may be delayed. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Medical obser- vation is recommended for 24 to 48 hours after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized para- medic may consider administering a drug or other inhala- tion therapy.
[Shipping]

UN3260 Corrosive solid, acidic, inorganic, n.o.s., Hazard class: 8; Labels: 8-Corrosive material, Technical Name Required.
[Incompatibilities]

Sensitive to humidity. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materi- als, strong bases, strong acids, oxoacids, and epoxides.
[Chemical Properties]

Rhodium trichloride is a red-brown or black, odorless solid or liquid
[Waste Disposal]

Recovery and reclaiming wherever possible in view of high economic value. See “Rhodium Metal.”
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