| Identification | More | [Name]
[3-[[(Phenylamino)carbonyl]oxy]phenyl]carbamic acid ethyl ester | [CAS]
13684-56-5 | [Synonyms]
(3-ETHOXYCARBONYLAMINOPHENYL) ANILINOFORMATE
3-ETHOXYCARBONYLAMINOPHENYL-N-PHENYL-CARBAMATE
BETANAL AM
BETANAL AM(R)
BETANEX(R)
DESMEDIPHAM
EP-475
ETHYL 3-PHENYLCARBAMOYLOXYPHENYLCARBAMATE
ETHYL-M-HYDROXYCARBANILATE CARBANILATE(ESTER)
KEMIFAM
SN-38107
(3-(((phenylamino)carbonyl)oxy)phenyl)-carbamicaciethylester
3-(Aethoxycarbonylaminophenyl)-N-phenyl-carbamat
3-Ethoxycarbnylaminophenyl N-Phenylcarbamate
Bentanex
Betamix70WP
Betanal-475
betanalam11
Betanex
Betanex70WP | [EINECS(EC#)]
237-198-5 | [Molecular Formula]
C16H16N2O4 | [MDL Number]
MFCD00055462 | [Molecular Weight]
300.31 | [MOL File]
13684-56-5.mol |
| Safety Data | Back Directory | [Hazard Codes ]
N | [Risk Statements ]
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment . | [Safety Statements ]
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet . | [RIDADR ]
UN 3077 | [WGK Germany ]
2 | [RTECS ]
FD0425000 | [HS Code ]
29242990 | [Toxicity]
LC50 (96-hour) for rainbow trout 3.8 mg/L and bluegill sunfish 13.4 mg/L
(Hartley and Kidd, 1987); acute oral LD50 of pure desmedipham and the formulated product
for rats 10,300 and 3,700 mg/kg, respectively (Ashton and Monaco, 1991). |
| Hazard Information | Back Directory | [Potential Exposure]
A postemergence bis-carbamate herbi-
cide used on sugarbeets to control annual weeds such as
pigweed, wild mustard, lamb’s quarters, nightshade, chick-
weed, buckwheat, goosefoot, ragweed, fiddleneck, and
kochia | [First aid]
Speed in removing material from eyes and skin
is of extreme importance. Eyes: Eye contact can cause dan-
gerous amounts of these chemicals to be quickly absorbed
through the mucous membrane into the bloodstream.
Immediately and gently flush eyes with plenty of warm or
cold water (NO hot water) for at least 15 minutes, occa-
sionally lifting the upper and lower eyelids. Get medical
aid immediately. Skin: Get medical aid. Dermal contact can
cause dangerous amounts of these chemicals to be absorbed into the bloodstream. Wearing the appropriate PPE equip-
ment and respirator for carbamate pesticides, immediately
flush skin with plenty of soap and water for at least 15 min-
utes while removing contaminated clothing and shoes.
Shampoo hair promptly if contaminated; protect eyes.
Ingestion: Call poison control. Loosen all clothing. Never
give anything by mouth to an unconscious person. Get
medical aid. Do NOT induce vomiting.
If conscious, alert,
and able to swallow, rinse mouth and have victim drink
four to eight ounces of water. Check to see if poison con-
trol instructs you to use ipecac syrup, otherwise administer
slurry of activated charcoal (2 oz in 8 oz of water). If vic-
tim is UNCONSCIOUS OR HAVING CONVULSIONS,do
nothing except keep victim warm.
In some cases you may
be specifically instructed by poison control to induce vomit-
ing by way of two tablespoons of syrup of ipecac (adult)
washed down with a cup of water. Do NOT give activated
charcoal before or with ipecac syrup. Inhalation: Get medi-
cal aid. Do not contaminate yourself. Wearing the appropri-
ate PPE equipment and respirator for carbamate pesticides,
immediately remove the victim from the contaminated area
to fresh air. If the victim is not breathing, administer artifi-
cial respiration. Do not use mouth-to-mouth method if vic-
tim ingested or inhaled the substance; give artificial
respiration with the aid of a pocket mask equipped with a
one-way valve or other proper respiratory medical device.
If breathing is difficult, administer oxygen through bag/
mask apparatus until medical help arrives. Do not leave
victim unattended. | [Shipping]
UN2757 Carbamate pesticides, solid, toxic,
Hazard Class: 6.1; Labels: 6.1-Poisonous materials. | [Incompatibilities]
Esters with acids to liberate heat along
with alcohols and acids. Strong oxidizing acids may cause
a vigorous reaction that is sufficiently exothermic to ignite
the reaction products. Heat is also generated by the interac-
tion of esters with caustic solutions. Flammable hydrogen
is generated by mixing esters with alkali metals and
hydrides. Carbamates are incompatible with reducing
agents, strong acids, oxidizing acids, peroxides, and bases.
Contact with active metals or nitrides cause the release of
flammable, and potentially explosive, hydrogen gas. Forms
Carbon monoxide and toxic nitrogen oxides when heated to
decomposition. | [Chemical Properties]
Colorless, crystalline solid. | [Waste Disposal]
Do not discharge into drains
or sewers. Dispose of waste material as hazardous waste
using a licensed disposal contractor to an approved landfill.
Consult with environmental regulatory agencies for guid-
ance on acceptable disposal practices. Incineration with
effluent gas scrubbing is recommended. Containers must be
disposed of properly by following package label directions
or by contacting your local or federal environmental control
agency, or by contacting your regional EPA office. | [Uses]
[3-[[(Phenylamino)carbonyl]oxy]phenyl]carbamic acid ethyl ester is a carbanilate based herbicide used in the weed control programs in sugar beet.
| [Uses]
Desmedipham is a carbanilate based herbicide used in the weed control programs in sugar beet. | [Uses]
Selective systemic herbicide used to control broad-leaved weeds such as buckwheat,
chickweed, fiddleneck, kochnia, mustard, pigweed and ragweed. | [Definition]
ChEBI: A carbamate ester that is phenylcarbamic acid in which the hydrogen of the hydroxy group has been replaced by a 3-[(ethoxycarbonyl)amino]phenyl group. It is an agrochemical used as a herbicide. | [Environmental Fate]
Soil. Degrades in soil forming the intermediate 3-hydroxycarbanilate (Worthing and
Hance, 1991). The reported half-lives in soil are 70 days, 20 hours and 10 minutes at pH
values of 5, 7 and 9, respectively (Worthing and Hance, 1991).
Plant. In sugar beets, m-aminophenol and ethyl-N-(3-hydroxyphenyl)-carbamate were
identified as metabolites (Hartley and Kidd, 1987). |
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