| Identification | More | [Name]
2-(Trimethylsilyl)pyridine | [CAS]
13737-04-7 | [Synonyms]
2-(TRIMETHYLSILYL)PYRIDINE
2-(TRIMETHYLSILYL)PYRIDINE, PURUM, 98%
2-Trimethylsilanyl-pyridine
Pyridine,2-(trimethylsilyl)-
2-(Trimethysilyl)pyridine
2-TRIMETHYLSILY-PYRIDINE
2-(TRIMETHYLSILYL)PYRIDINE, 97+%
2-pyridyltrimethylsilane | [Molecular Formula]
C8H13NSi | [MDL Number]
MFCD06797181 | [Molecular Weight]
151.28 | [MOL File]
13737-04-7.mol |
| Chemical Properties | Back Directory | [Appearance]
Clear colorless to brown liquid | [Boiling point ]
47-49 °C5 mm Hg(lit.) | [density ]
0.9113 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.489(lit.)
| [Fp ]
126 °F
| [storage temp. ]
Refrigerator | [form ]
clear liquid | [pka]
6.62±0.10(Predicted) | [color ]
Colorless to Almost colorless | [Specific Gravity]
0.911 | [Hydrolytic Sensitivity]
4: no reaction with water under neutral conditions | [Sensitive ]
Light Sensitive | [InChI]
InChI=1S/C8H13NSi/c1-10(2,3)8-6-4-5-7-9-8/h4-7H,1-3H3 | [InChIKey]
IBLKFJNZUSUTPB-UHFFFAOYSA-N | [SMILES]
C1([Si](C)(C)C)=NC=CC=C1 | [CAS DataBase Reference]
13737-04-7(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R10:Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection . | [RIDADR ]
UN 1993 3/PG 3
| [WGK Germany ]
3
| [HazardClass ]
3 | [PackingGroup ]
III | [HS Code ]
29333990 |
| Hazard Information | Back Directory | [Chemical Properties]
Clear colorless to brown liquid | [Synthesis]
A solution of 2-chloropyridine (20.7 mL, 217 mmol) and trimethylchlorosilane (28.0 mL, 221 mmol) in THF (100 mL) was added dropwise to a rapidly stirred mixture of magnesium chips (6.75 g, 281 mmol) in THF (175 mL).
The solution in was added dropwise to |
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