| Identification | Back Directory | [Name]
cataCXium A-Pd-G2 | [CAS]
1375477-29-4 | [Synonyms]
cataCXium A-Pd-G2
cataCXium(R) A Pd G2
2nd Gen. precatalyst cataCXium
Chloro[(di(1-adamantyl)-N-butylphosphine)-2-(2-aminobiphenyl)]palladium(II)
Chloro[(di(1-adamantyl)-N-butylphosphine)-2-(2-aminobiphenyl)]palladium(II) / CataCXium A-Pd-G2
[2'-(Amino)[1,1'-biphenyl]-2-yl][butylbis(tricyclo[3.3.1.1(3,7)]dec-1-yl)phosphine]chloropalladium
Palladium, [2'-(amino-κN)[1,1'-biphenyl]-2-yl-κC][butylbis(tricyclo[3.3.1.13,7]dec-1-yl)phosphine]chloro- | [Molecular Formula]
C36H49ClNPPd | [MDL Number]
MFCD22200549 | [MOL File]
1375477-29-4.mol | [Molecular Weight]
668.64 |
| Chemical Properties | Back Directory | [Melting point ]
220°C (decomposition) | [storage temp. ]
Keep in dark place,Inert atmosphere,2-8°C | [form ]
solid | [InChIKey]
ACPPOLPZSAKAJG-UHFFFAOYSA-N | [SMILES]
P([Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[Cl-])(C12CC3CC(CC(C3)C1)C2)(C12CC3CC(CC(C3)C1)C2)CCCC |
| Hazard Information | Back Directory | [Uses]
cataCXium? A Pd G2 is a Buchwald′s second generation catalyst that can be used as a palladium source for the coupling of potassium 1-(benzyloxy)alkyltrifluoroborates with aryl and heteroaryl chlorides via Suzuki-Miyaura reaction to yield protected secondary alcohols. | [Uses]
Chloro[(di(1-adamantyl)-N-butylphosphine)-2-(2-aminobiphenyl)]palladium(II) is a Buchwald′s second generation catalyst that can be used as a palladium source for the coupling of potassium 1-(benzyloxy)alkyltrifluoroborates with aryl and heteroaryl chlorides via Suzuki-Miyaura reaction to yield protected secondary alcohols. | [reaction suitability]
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings |
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