ChemicalBook--->CAS DataBase List--->13759-83-6

13759-83-6

13759-83-6 Structure

13759-83-6 Structure
IdentificationMore
[Name]

SAMARIUM NITRATE HEXAHYDRATE
[CAS]

13759-83-6
[Synonyms]

SAMARIUM(+3)NITRATE HEXAHYDRATE
SAMARIUM (III) NITRATE
SAMARIUM(III) NITRATE HEXAHYDRATE
SAMARIUM NITRATE HEXAHYDRATE
nitricacid,samarium(3+)salt,hexahydrate
samarium(iii)nitrate,hexahydrate(1:3:6)
samariumnitrat
samariumtrinitratehexahydrate
Samarium(III) nitrate hexahydrate, 99.999% metals basis
SAMARIUM(III) NITRATE HEXAHYDRATE, 99.9%
SAMARIUM (III) NITRATE, REACTON, 99.99% (REO)
SAMARIUM (III) NITRATE HEXAHYDRATE (99.9%-SM) (REO)
Samarium(III) nitrate hexahydrate, 99.90%
samarium(iii) nitrate hydrate, reacton
Samarium(III) nitrate hydrate, REacton(R), 99.99% (REO)
Trinitric acid samarium(III)·6hydrate
[EINECS(EC#)]

233-798-6
[Molecular Formula]

H12N3O15Sm
[MDL Number]

MFCD00149857
[Molecular Weight]

444.47
[MOL File]

13759-83-6.mol
Chemical PropertiesBack Directory
[Appearance]

yellow crystals or crystalline powder
[Melting point ]

78°C
[density ]

2.375
[storage temp. ]

0-6°C
[solubility ]

H2O: 0.1 g/mL, clear
[form ]

Crystals or Crystalline Powder
[color ]

Yellow
[Water Solubility ]

Soluble in water and acetonitrile.
[Sensitive ]

Hygroscopic
[Stability:]

hygroscopic
[InChI]

InChI=1S/3NO3.6H2O.Sm/c3*2-1(3)4;;;;;;;/h;;;6*1H2;/q3*-1;;;;;;;+3
[InChIKey]

HDCOFJGRHQAIPE-UHFFFAOYSA-N
[SMILES]

[N+]([O-])([O-])=O.[N+]([O-])([O-])=O.[N+]([O-])([O-])=O.O.O.O.O.O.O.[Sm+3]
[CAS DataBase Reference]

13759-83-6(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

O,Xi
[Risk Statements ]

R8:Contact with combustible material may cause fire.
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S17:Keep away from combustible material .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S24/25:Avoid contact with skin and eyes .
S22:Do not breathe dust .
[RIDADR ]

UN 1477 5.1/PG 3
[WGK Germany ]

2
[RTECS ]

VP3150000
[TSCA ]

Yes
[HazardClass ]

5.1
[PackingGroup ]

III
[HS Code ]

28469099
[Storage Class]

5.1B - Oxidizing hazardous materials
[Hazard Classifications]

Eye Irrit. 2
Ox. Sol. 2
Skin Irrit. 2
STOT SE 3
Hazard InformationBack Directory
[Chemical Properties]

Samarium (III) nitrate hexahydrate is a yellow to tan powder and chunks in physical appearance and is an oxidiser. It has application as a chemical reagent. It is hygroscopic – absorbs moisture from the air.
[Uses]

Samarium(III) nitrate hexahydrate is a Lewis acid catalyst that is used in the synthesis of a variety of materials for applications such as:
  • synthesis of nitrate precursor solution which can be used as a nanocatalyst in the solid oxide regenerative fuel cells.
  • for the formation of coumarin derivative by von Pechmann condensation of phenol with ethyl acetoacetate in the presence of samarium complex as catalyst.
  • for the preparation of samarium doped ceria, which can be used in the fabrication of electrolyte for fuel cells.

[Uses]

Samarium(III) nitrate hydrate is used as a catalyst in von Pechmann condensation for the preparation of coumarins. Further, it finds use in optical glasses, structural ceramics, catalysts, electrical components and photo-optical material. It is also used as a laboratory reagent. In addition to this, it is used in NMR spectroscopy for spectral resolution and is used for doping purposes.
[reaction suitability]

reagent type: catalyst
core: samarium
Spectrum DetailBack Directory
[Spectrum Detail]

SAMARIUM NITRATE HEXAHYDRATE(13759-83-6)IR1
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Samarium(III) nitrate hexahydrate, 99.90%(13759-83-6)
[Alfa Aesar]

Samarium(III) nitrate hydrate, REacton, 99.99% (REO)(13759-83-6)
[Sigma Aldrich]

13759-83-6(sigmaaldrich)
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