| Identification | More | [Name]
SAMARIUM(III) ISOPROPOXIDE | [CAS]
3504-40-3 | [Synonyms]
SAMARIUM (III) I-PROPOXIDE
SAMARIUM(III) ISOPROPOXIDE
Samarium(III) isopropoxide in ampoules
SAMARIUM I-PROPOXIDE
SAMARIUM ISOPROPOXIDE
SAMARIUM TRI-I-PROPOXIDE
SAMARIUM(III) ISOPROPOXIDE, 99.9%
SAMARIUM (III) I-PROPOXIDE, MIN. 97% (99.9%-SM) (REO)
SAMARIUM (III) ISOPROPOXIDE, 5% W/V IN TOLUENE-ISOPROPANOL,
5%w/vintoluene-isopropanol(REO)
SAMARIUM(III) ISOPROPOXIDE (99.9% SM) (REO)
Samarium tetraisopropoxide
Samarium(III) isopropoxide, 5% w/v in toluene-isopropanol, 99% (REO) | [Molecular Formula]
C9H21O3Sm | [MDL Number]
MFCD00058820 | [Molecular Weight]
327.62 | [MOL File]
3504-40-3.mol |
| Chemical Properties | Back Directory | [Boiling point ]
210-30°C/0.01mmHg | [form ]
Powder | [color ]
cream colored | [Water Solubility ]
Hydrolyzes with water. | [Hydrolytic Sensitivity]
7: reacts slowly with moisture/water | [Sensitive ]
Moisture Sensitive | [Exposure limits]
ACGIH: TWA 20 ppm
OSHA: Ceiling 300 ppm; TWA 200 ppm
NIOSH: IDLH 500 ppm; TWA 100 ppm(375 mg/m3); STEL 150 ppm(560 mg/m3) | [InChI]
1S/3C3H7O.Sm/c3*1-3(2)4;/h3*3H,1-2H3;/q3*-1;+3 | [InChIKey]
HJCRVWSKQNDSPZ-UHFFFAOYSA-N | [SMILES]
CC(C)O[Sm](OC(C)C)OC(C)C | [CAS DataBase Reference]
3504-40-3(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
F,Xi | [Risk Statements ]
R11:Highly Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S33:Take precautionary measures against static discharges . | [RIDADR ]
UN 1325 4.1/PG 3
| [WGK Germany ]
3
| [TSCA ]
No | [HazardClass ]
3 | [PackingGroup ]
II | [Storage Class]
4.1B - Flammable solid hazardous materials | [Hazard Classifications]
Eye Irrit. 2
Flam. Sol. 2
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Uses]
Used with a dinucleating Schiff base ligand in a catalytic asymmetric nitro-Mannich reaction. | [reaction suitability]
core: samarium
reagent type: catalyst |
|
| Company Name: |
INTATRADE GmbH
|
| Tel: |
+49 3493/605464 |
| Website: |
www.intatrade.de |
| Company Name: |
Alfa Aesar
|
| Tel: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Tel: |
021-021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
|