ChemicalBook--->CAS DataBase List--->13826-86-3

13826-86-3

13826-86-3 Structure

13826-86-3 Structure
IdentificationMore
[Name]

NITRONIUM TETRAFLUOROBORATE
[CAS]

13826-86-3
[Synonyms]

NITRONIUM TETRAFLUOROBORATE
NITRYL TETRAFLUOROBORATE
nitronium,tetrafluoroborate(1-)
nitrylfluoborate
tetrafluoro-borate(1-nitryl
Nitronium tetrafluorborate
NITRONIUM TETRAFLUOROBORATE, 95+%
NITRONIUM TETRAFLUOROBORATE, 0.5M SOLUTI ON IN SULFOLANE
NITRONIUM TETRAFLUOROBORATE SOLUTION, ~0 .5 M IN SULFOLANE
Nitroniumtetrafluoroborate,min.97%
Borate(1-), tetrafluoro-, nitryl
nitronium tetrafluoroborate solution
Nitronium tetrafluoroborate 95%
Nitronium tetrafluoroborate,97%
Nitronium tetrafluoroborate, min. 97%
[EINECS(EC#)]

237-533-5
[Molecular Formula]

BF4NO2
[MDL Number]

MFCD00011432
[Molecular Weight]

132.81
[MOL File]

13826-86-3.mol
Chemical PropertiesBack Directory
[Appearance]

colourless crystalline solid
[Melting point ]

200 °C
[density ]

1.29 g/mL at 20 °C
[storage temp. ]

2-8°C
[solubility ]

Acetonitrile (Slightly, Heated)
[form ]

crystal
[color ]

white
[Stability:]

Stable, but may decompose in water on exposure to moist air. Incompatible with water, strong oxidizing agents.
[Water Solubility ]

Decomposes in water.
[Decomposition ]

decomposes to NO2F and BF3 at temperatures >180 °C.
[Sensitive ]

Hygroscopic
[CAS DataBase Reference]

13826-86-3(CAS DataBase Reference)
[EPA Substance Registry System]

Borate(1-), tetrafluoro-, nitryl (13826-86-3)
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)Health Hazard (GHS08)
GHS05,GHS08
[Signal word ]

Danger
[Hazard statements ]

H314-H317-H334
[Precautionary statements ]

P260-P272-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
[Hazard Codes ]

C
[Risk Statements ]

R34:Causes burns.
R42/43:May cause sensitization by inhalation and skin contact .
R22:Harmful if swallowed.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 3264 8/PG 2
[WGK Germany ]

3
[RTECS ]

QX8620000
[F ]

10-21
[Hazard Note ]

Corrosive/Hygroscopic
[TSCA ]

T
[HazardClass ]

8
[PackingGroup ]

III
[HS Code ]

28429090
[Toxicity]

mouse,LD50,intravenous,180mg/kg (180mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#05621,
Raw materials And Preparation ProductsBack Directory
[Preparation Products]

3-Methoxy-4-pyridinecarboxylic acid
Hazard InformationBack Directory
[Chemical Properties]

colourless crystalline solid
[Uses]

Nitronium Tetrafluoroborate is used in the preparation of triazolyl glycoside as galectin-3 inhibitors.
[General Description]

Nitronium Tetrafluoroborate is used as a electrophilic nitrating agent; mild oxidant; hydride and halide abstracting agent.
[Solubility in organics]

Nitronium Tetrafluoroborate is soluble in sulfolane, acetonitrile; slightly soluble in nitromethane. Compared with NO2 +BF4 -, NO2 +PF6 - has much higher solubility in organic solvents.
[storage]

Due to its hygroscopic nature, Nitronium Tetrafluoroborate (NO2 +BF4 -) should be stored and used under anhydrous conditions. Commercial NO2 +BF4 - often contains varying amounts of NO+BF4 -. Removal of the NO+ from NO2 +BF4 - is difficult. Therefore, pure nitronium tetrafluoroborate should be prepared directly from urea-treated purified HNO3.
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Nitronium tetrafluoroborate, 0.5 M solution in sulfolane(13826-86-3)
[Alfa Aesar]

Nitronium tetrafluoroborate, 96%(13826-86-3)
[Sigma Aldrich]

13826-86-3(sigmaaldrich)
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