| Identification | Back Directory | [Name]
(ACETYLACETONATO)DICARBONYLIRIDIUM(I) | [CAS]
14023-80-4 | [Synonyms]
dicarbonyl(2,4-pentandione)iridium
(Acetylacetonato)dicarbonyliridium
IRIDIUM I DICARBONYL PENTANEDIONATE
2,4-Pentanedionatodicarbonyl iridium
Dicarbonyl(2,4-pentanedionato)iridium
(ACETYLACETONATO)DICARBONYLIRIDIUM(I)
DICARBONYLACETYLACETONATO IRIDIUM (I)
Dicarbonylacetylacetonatoiridium(I),98%
dicarbonyl-2,4-pentanedionatoiridium(i)
DICARBONYL-2,4-PENTANEDIONATOIRIDATE (I)
IRIDIUM(I) DICARBONYL 2,4-PENTANEDIONATE
Dicarbonyl(2,4-pentanedionato)iridium(Ⅰ)
Iridium, dicarbonyl(2,4-pentanedionato-O,O')-
DicarbonylacetylacetonatoiridiumIcopperbrownxtl
Dicarbonylacetylacetonato iridiuM(I),98% Ir(CO)2(CH3COCHCOCH3) | [Molecular Formula]
C7H7IrO4 | [MDL Number]
MFCD00049135 | [MOL File]
14023-80-4.mol | [Molecular Weight]
347.35 |
| Chemical Properties | Back Directory | [Appearance]
metallic brown | [Melting point ]
>145℃ | [Boiling point ]
100°C 0,05mm | [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [form ]
crystal | [color ]
copper brown | [Stability:]
store cold | [InChI]
InChI=1S/C5H8O2.2CO.Ir/c1-4(6)3-5(2)7;2*1-2;/h3,6H,1-2H3;;;/q;;;+1/p-1/b4-3-;;; | [InChIKey]
DFIAYCFHPDOZLK-FGSKAQBVSA-M | [SMILES]
C(=C/C(=O)C)(\C)/O[Ir].[O+]#[C-].[O+]#[C-] |
| Hazard Information | Back Directory | [Chemical Properties]
metallic brown | [Uses]
Catalyst for isomerization and anti-Markovnikov arylation of olefins
Reactant for:
- Oxidative addition of perfluoroalkyl iodides
- Synthesis of iridium heterocycles
- Scaffolding of iridium complexes
- Metal carbonyl cluster synthesis
- Mixed-bridged bimetallic d8 complex synthesis
| [reaction suitability]
core: iridium
reagent type: catalyst |
| Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
20/21/22-36/37/38-63 | [Safety Statements ]
22-26-36 | [RIDADR ]
UN3466 | [WGK Germany ]
3
| [TSCA ]
No | [HazardClass ]
6.1 | [PackingGroup ]
III | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Eye Irrit. 2
Repr. 2
Skin Irrit. 2
STOT SE 3 |
|
| Company Name: |
Alfa Aesar
|
| Tel: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Tel: |
021-021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
|