| Identification | More | [Name]
Carbonyltris(triphenylphosphine)rhodium(I) hydride | [CAS]
17185-29-4 | [Synonyms]
CARBONYLHYDRIDOTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I)
CARBONYLTRIS(TRIPHENYLPHOSPHINE)RHODIUM(1) HYDRIDE
CARBONYLTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) HYDRIDE
HYDRIDOCARBONYLTRIS(TRIPHENYLPHOSPHINE)RHODIUM (I)
TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) CARBONYL HYDRIDE
(betab-5-23)-rhodiu
carbonylhydrotris(triphenylphosphine)rhodium
TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) &
Carbonylhydridotris(triphenylphosphine)rhodium(I).99.9%
CARBONYLHYDIDOTRIS (TRIPHENYLPHOSPHINE) RHODIUM(I)
Hydridocarbonyltris(triphenylphosphine)rhodium(I),98%
Rhodium, carbonylhydrotris(triphenylphosphine)-, (TB-5-23)-
tris(triphenylphosphine)rhodium carbonyl hydride
Carbonyltris(triphenylphosphine)rhodium
Carbonylhydrotris(triphenylphosphin)rhodium
Carbonylhydridotris(triphenylphosphine)rhodium(I), Rh 10.0% min
Efficient hydroformylation catalyst. Unstable in solution in presence of air.
Carbonylhydridotris(triphenylphosphine)rhodium(I), Rh 11.2%
rhodium(I) tris(triphenylphosphine) carbonyl hydride
Carbonyl hydridotris(triphenylphosphine) rhodium | [EINECS(EC#)]
241-230-3 | [Molecular Formula]
C55H48OP3Rh | [MDL Number]
MFCD00151644 | [Molecular Weight]
920.8 | [MOL File]
17185-29-4.mol |
| Chemical Properties | Back Directory | [Appearance]
yellow crystals | [Melting point ]
150 °C (dec.) (lit.) | [density ]
1.33 | [vapor pressure ]
0Pa at 25℃ | [storage temp. ]
2-8°C | [solubility ]
Soluble in hydrocarbons (e.g. benzene and toluene) with dissociation of phosphine ligands | [form ]
crystal | [color ]
light yellow | [Hydrolytic Sensitivity]
7: reacts slowly with moisture/water | [Sensitive ]
Moisture Sensitive | [Merck ]
9758 | [Exposure limits]
ACGIH: TWA 0.01 mg/m3; TWA 1 mg/m3
NIOSH: IDLH 2 mg/m3; IDLH 100 mg/m3; TWA 0.001 mg/m3; TWA 0.1 mg/m3 | [InChI]
1S/3C18H15P.CO.Rh.H/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;/h3*1-15H;;; | [InChIKey]
CEKFIOLKXHVOKA-UHFFFAOYSA-N | [SMILES]
[RhH].[C-]#[O+].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9 | [CAS DataBase Reference]
17185-29-4(CAS DataBase Reference) | [NIST Chemistry Reference]
carbonyl(hydrido)tris(triphenylphosphine)rhodium(17185-29-4) | [EPA Substance Registry System]
Rhodium, carbonylhydrotris(triphenylphosphine)-, (TB-5-23)- (17185-29-4) |
| Safety Data | Back Directory | [Hazard Codes ]
T | [Risk Statements ]
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed . | [Safety Statements ]
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37:Wear suitable protective clothing and gloves . | [RIDADR ]
UN 2811 6.1/PG 2
| [WGK Germany ]
1
| [F ]
10-23 | [TSCA ]
Yes | [HazardClass ]
4.3 | [PackingGroup ]
III | [HS Code ]
28439000 | [Storage Class]
11 - Combustible Solids |
| Hazard Information | Back Directory | [Chemical Properties]
yellow crystals | [Uses]
Catalyst. | [Uses]
Hydrogenation, hydrosilation, isomerization, carbonylation, hydroformylation, oxidation | [Production Methods]
Carbonyltris(triphenylphosphine)rhodium(I) hydride is obtained by the reaction of a solution of RhCl3.3 H2O in alcoholic alkali with aqueous formaldehyde (the carbon monoxide source) and an excess of triphenyl phosphine. The commercial product is a microcrystalline powder with a purity of 97 % (Degussa). | [reaction suitability]
core: rhodium
reagent type: catalyst |
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