ChemicalBook--->CAS DataBase List--->15529-49-4

15529-49-4

15529-49-4 Structure

15529-49-4 Structure
IdentificationMore
[Name]

Tris(triphenylphosphine)ruthenium(II) chloride
[CAS]

15529-49-4
[Synonyms]

DICHLOROTETRAKIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II)
DICHLOROTRIS(TRIPHENYLPHOSPHINE)RUTHENATE (II)
DICHLOROTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II)
DICHLOROTRIS(TRIPHENYLPHOSPHINO)RUTHENIUM (II)
RUTHENIUM DICHLOROTRIS(TRIPHENYLPHOSPHINE)
RUTHENIUM(II)-TRIS(TRIPHENYLPHOSPHINE) DICHLORIDE
TRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(2) DICHLORIDE
TRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) CHLORIDE
TRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) DICHLORIDE
dichlorotris(triphenylphosphine)ruthenium
Dichlorotris(triphenylphosphine)ruthenium(II),99%
dichlorotris(triphenylphosphine)ruthenium(ii), premion
DICHLOROTRIS(TRIPHENYLPHOSPHINO)RUTHENIUM(II) (10% RU)
TRIS(TRIPHENYLPHOSPHINE) RUTHENIUM II
Dichlorotris(triphenylphosphine)ruthenium(II), Premion(R), 99.95% (metals basis), Ru 10.2% min
Dichlorotris(triphenylphosphine)ruthenium(II) Dissociates in solution
Dichlorotris(triphenylphosphine)ruthenium(II), Premion, 99.95% (metals basis), Ru 10.2% min
Ruthenium chloride triphenyl phosphine
Dichlorotris(triphenylphosphine)ruthenium(II), Ruthenium(II)-tris(triphenylphosphine) dichloride
[EINECS(EC#)]

239-569-7
[Molecular Formula]

C54H45Cl2P3Ru
[MDL Number]

MFCD00013077
[Molecular Weight]

958.83
[MOL File]

15529-49-4.mol
Chemical PropertiesBack Directory
[Appearance]

black crystals
[Melting point ]

159 °C
[storage temp. ]

Refrigerator
[solubility ]

Very slightly soluble (with dissociation) in acetone, alcohol, chloroform, ethyl acetate, and toluene
[form ]

Solution
[color ]

Clear
[Water Solubility ]

insoluble
[Hydrolytic Sensitivity]

8: reacts rapidly with moisture, water, protic solvents
[Sensitive ]

Air & Moisture Sensitive
[BRN ]

4935939
[InChI]

InChI=1S/3C18H15P.2ClH.Ru/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h3*1-15H;2*1H;/q;;;;;+2/p-2
[InChIKey]

QUVLSIIMVTXAPD-UHFFFAOYSA-M
[SMILES]

P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.P(C1=CC=CC=C1)(C1=CC=CC=C1)C1C=CC=CC=1.P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.[Ru](Cl)Cl
[CAS DataBase Reference]

15529-49-4(CAS DataBase Reference)
[Storage Precautions]

Air sensitive;Store under inert gas;Moisture sensitive
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R20/21:Harmful by inhalation and in contact with skin .
[Safety Statements ]

S36/37:Wear suitable protective clothing and gloves .
S22:Do not breathe dust .
[RIDADR ]

2811
[WGK Germany ]

3
[TSCA ]

No
[HS Code ]

28439000
[Storage Class]

11 - Combustible Solids
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ethanol-->Tetrahydrofuran-->Dichloromethane-->Isopropyl alcohol-->Hydrazinium hydroxide solution-->Triphenylphosphine-->Lithium-->Ruthenium(III) chloride hydrate
Hazard InformationBack Directory
[Chemical Properties]

black crystals
[Uses]

Dichlorotris(triphenylphosphine)ruthenium(II) serves as a precatalyst for the hydrogenation of alkenes, nitro compounds, ketones, carboxylic acids, synthesis of furans from allenyl sulfides and C-H Activation Catalyst in a Ruthenium/Lewis Acid System
[Uses]

suzuki reaction
[Preparation]

Tris(triphenylphosphine)ruthenium(II) chloride can be prepared by refluxing hydrated Ruthenium(III) Chloride and Triphenylphosphine in ethanol  according to the procedure of Wilkinson.
[General Description]

Tris(triphenylphosphine)ruthenium(II) chloride can be used in the hydrogenation of nitro groups, imines, and ketones, and the selective oxidation of alcohols.
[reaction suitability]

core: ruthenium
reagent type: catalyst
reaction type: C-H Activation
Spectrum DetailBack Directory
[Spectrum Detail]

Tris(triphenylphosphine)ruthenium(II) chloride(15529-49-4)IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Tris(triphenylphosphine)ruthenium(II) chloride, 98%(15529-49-4)
[Alfa Aesar]

Dichlorotris(triphenylphosphine)ruthenium(II), Premion, 99.95% (metals basis), Ru 10.2% min(15529-49-4)
[Sigma Aldrich]

15529-49-4(sigmaaldrich)
[TCI AMERICA]

Tris(triphenylphosphine)ruthenium(II) Dichloride,>90.0%(T)(15529-49-4)
15529-49-4 suppliers list
Company Name: Guiyan Chemical Materials (Yunnan) Co., LTD  Gold
Telephone: 18317061306
Website: www.sino-platinum.com.cn
Company Name: Beijing Guofang Dingsheng Technology Co., Ltd.  Gold
Telephone: 18610472091
Website: http://www.gfdschem.com
Company Name: Leshan Bangsheng New Materials Co., Ltd  Gold
Telephone: 0833-2599138 19162614312
Website: www.bangshengchem.com/
Company Name: Panjin Greenchem Technology Co., Ltd.  Gold
Telephone: 13121959385
Website:
Company Name: Changsha Shunyan New Materials Technology Co., Ltd  Gold
Telephone: 13005015646
Website:
Company Name: Yunnan Precious Metals Laboratory Co., Ltd  Gold
Telephone: 13529192135
Website:
Company Name: J & K SCIENTIFIC LTD.  
Telephone: 18210857532 18210857532
Website: https://www.jkchemical.com
Company Name: Meryer (Shanghai) Chemical Technology Co., Ltd.  
Telephone: 4006356688 18621169109
Website: www.x-labseek.com/
Company Name: Alfa Aesar  
Telephone: 400-6106006
Website: http://chemicals.thermofisher.cn
Company Name: TCI (Shanghai) Development Co., Ltd.  
Telephone: 021-67121386
Website: https://www.tcichemicals.com/CN/zh/
Company Name: ShangHai DEMO Chemical Co.,Ltd  
Telephone: 400-021-7337 2355568890
Website: www.demochem.com
Company Name: Beijing HwrkChemical Technology Co., Ltd  
Telephone: 89508211 18501085097
Website: http://www.hwrkchemical.com
Company Name: Capot Chemical Co., Ltd  
Telephone: +86 (0) 571 85 58 67 18
Website: www.capotchem.com
Company Name: JinYan Chemicals(ShangHai) Co.,Ltd.  
Telephone: 13817811078
Website: www.jingyan-chemical.com
Company Name: Jia Xing Isenchem Co.,Ltd  
Telephone: 0573-85285100 18627885956
Website: https://www.chemicalbook.com/ShowSupplierProductsList14265/0_EN.htm
Company Name: Beijing VSciChem Technology Co., Ltd.  
Telephone: 13811761079
Website: http://www.vscichem.com
Company Name: Accela ChemBio Co.,Ltd.  
Telephone: 021-50795510 4000665055
Website: http://www.shao-yuan.com/
Company Name: Shanghai Hanhong Scientific Co.,Ltd.  
Telephone: 021-54306202 13764082696
Website: https://www.hanhongsci.com
Tags:15529-49-4 Related Product Information
10049-08-8 13965-03-2 791-28-6 14694-95-2 7447-40-7 77-86-1 603-35-0 7440-18-8 6976-37-0 5704-04-1 63995-70-0 15604-36-1 1034-39-5 55102-19-7 12012-95-2 14221-02-4 53199-31-8 6850-28-8