ChemicalBook--->CAS DataBase List--->14036-06-7

14036-06-7

14036-06-7 Structure

14036-06-7 Structure
IdentificationBack Directory
[Name]

Diethoxymethyl acetate
[CAS]

14036-06-7
[Synonyms]

Nsc158267
DIETHOXYMETHYL ACETATE
Diethoxymethyleacetate
diethoxy-methanoacetate
Diethyloxymethyl acetate
Diethoxymethyl Acetate >
METHYL 2,2-DIETHOXYACETATE
Diethoxymethyl acetate ,97%
methanol, diethoxy-, acetate
ACETIC ACID DIETHOXYMETHYL ESTER
Methanol, 1,1-diethoxy-, 1-acetate
[EINECS(EC#)]

237-873-4
[Molecular Formula]

C7H14O4
[MDL Number]

MFCD00009229
[MOL File]

14036-06-7.mol
[Molecular Weight]

162.18
Chemical PropertiesBack Directory
[Boiling point ]

170-172 °C(Press: 743 Torr)
[density ]

0.993 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.399(lit.)
[Fp ]

82 °F
[storage temp. ]

2-8°C
[solubility ]

sol most common organic solvents
[form ]

Liquid
[color ]

Clear colorless
[BRN ]

1209886
[InChI]

1S/C7H14O4/c1-4-9-7(10-5-2)11-6(3)8/h7H,4-5H2,1-3H3
[InChIKey]

IRUNKQSGDBYUDC-UHFFFAOYSA-N
[SMILES]

CCOC(OCC)OC(C)=O
[LogP]

1.920 (est)
[NIST Chemistry Reference]

Diethoxymethyl acetate(14036-06-7)
[EPA Substance Registry System]

Methanol, diethoxy-, acetate (14036-06-7)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

10-36/37/38
[Safety Statements ]

16-26-36/37/39
[RIDADR ]

UN 3272 3/PG 3
[WGK Germany ]

3
[F ]

9-21
[TSCA ]

TSCA listed
[HazardClass ]

3.2
[PackingGroup ]

III
[HS Code ]

29153900
[Storage Class]

3 - Flammable liquids
[Hazard Classifications]

Eye Irrit. 2
Flam. Liq. 3
Skin Irrit. 2
STOT SE 3
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Acetic anhydride-->Triethyl orthoformate-->Formic acid
[Preparation Products]

2,8-Dichloropyrimido[5,4-d]pyrimidine-->6-Methylpurine-->3-AMINOPYRAZINE-2-CARBONITRILE-->4-CHLORO-1-H-IMIDAZO[4,5-C]PYRIDINE
Hazard InformationBack Directory
[Chemical Properties]

Colorless liquid
[Uses]

Diethoxymethyl acetate was used in the synthesis of D-mannosyl, D-galactosyl and D-glucosyl theophylline nucleosides.
[Preparation]

Diethoxymethyl acetate can be best prepared from triethyl orthoformate and formic acid/acetic anhydride.
[General Description]

Diethoxymethyl acetate reacts with 5-amino-6-ribitylaminouracil hydrochloride to yield 6-dioxo-(1H,3H)-9-N-ribitylpurine.
[Precautions]

Diethoxymethyl acetate is sensitive to moisture and should be handled and stored under dry conditions. At temperatures above 120 °C it decomposes into ethyl acetate and ethyl formate.
Spectrum DetailBack Directory
[Spectrum Detail]

Diethoxymethyl acetate(14036-06-7)1HNMR
Diethoxymethyl acetate(14036-06-7)Raman
Diethoxymethyl acetate(14036-06-7)FT-IR
Diethoxymethyl acetate(14036-06-7)IR
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