| Identification | More | [Name]
Pinacol vinylboronate | [CAS]
75927-49-0 | [Synonyms]
4,4,5,5-TETRAMETHYL-2-VINYL-1,3,2-DIOXABOROLANE
AKOS BRN-0470
PINACOL VINYLBORONATE
VINYLBORONIC ACID PINACOL ESTER
2-Vinyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
Vinylboronic acid pinacol cyclic ester
4,4,5,5-Tetramethyl-2-vinyl-1,3,2-dioxaborolane (stabilized with Phenothiazine) | [Molecular Formula]
C8H17BO3 | [MDL Number]
MFCD00192492 | [Molecular Weight]
172.03 | [MOL File]
75927-49-0.mol |
| Chemical Properties | Back Directory | [Appearance]
Clear colorless to amber liquid | [Boiling point ]
52-54°C 24mm | [density ]
0.908 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.4300(lit.)
| [Fp ]
94 °F
| [storage temp. ]
Refrigerator | [solubility ]
Chloroform (Sparingly), Methanol (Slightly) | [form ]
Powder or Low Melting Solid | [color ]
White to yellow | [Sensitive ]
Air Sensitive | [Stability:]
Light Sensitive, Volatile | [InChI]
InChI=1S/C8H15BO2/c1-6-9-10-7(2,3)8(4,5)11-9/h6H,1H2,2-5H3 | [InChIKey]
DPGSPRJLAZGUBQ-UHFFFAOYSA-N | [SMILES]
O1C(C)(C)C(C)(C)OB1C=C | [CAS DataBase Reference]
75927-49-0(CAS DataBase Reference) |
| Safety Data | Back Directory | [Symbol(GHS) ]
  
GHS02,GHS07,GHS09 | [Signal word ]
Warning | [Hazard statements ]
H226-H317-H411 | [Precautionary statements ]
P210-P233-P240-P273-P280-P303+P361+P353 | [Hazard Codes ]
Xi | [Risk Statements ]
R10:Flammable. | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking . | [RIDADR ]
UN 3272 3/PG 3
| [WGK Germany ]
3
| [TSCA ]
No | [HazardClass ]
3 | [PackingGroup ]
III | [HS Code ]
29319090 | [Storage Class]
3 - Flammable liquids | [Hazard Classifications]
Aquatic Chronic 2
Flam. Liq. 3
Skin Sens. 1 |
| Hazard Information | Back Directory | [Chemical Properties]
Clear colorless to amber liquid | [Uses]
suzuki reaction | [Synthesis]
Under nitrogen protection, 193 g of pinacol and 14 g of 2,6-di-tert-butyl-4-methylphenol were added to a 1 L reaction flask and heated to 85-90 °C until the pinacol was completely melted. The intermediate reactants were added slowly dropwise, taking care to control the rate of dropwise acceleration. Subsequently, diisopropylamine was isolated by distillation using an atmospheric pressure steam distillation apparatus. Upon completion of the reaction, a colorless and transparent vinylboronic acid pinacol ester liquid product containing 225 g of the target product was obtained, which was analyzed by gas chromatography (GC) with a purity of 99.1% (excluding polymerization inhibitors). | [References]
[1] Patent: CN105503926, 2016, A. Location in patent: Paragraph 0018 |
| Well-known Reagent Company Product Information | Back Directory | [Acros Organics]
2-Vinyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, 97+%(75927-49-0) | [Alfa Aesar]
Vinylboronic acid pinacol ester, 97%(75927-49-0) | [Sigma Aldrich]
75927-49-0(sigmaaldrich) | [TCI AMERICA]
4,4,5,5-Tetramethyl-2-vinyl-1,3,2-dioxaborolane (stabilized with Phenothiazine),>95.0%(GC)(75927-49-0) |
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