ChemicalBook--->CAS DataBase List--->78-38-6

78-38-6

78-38-6 Structure

78-38-6 Structure
IdentificationMore
[Name]

DIETHYL ETHYLPHOSPHONATE
[CAS]

78-38-6
[Synonyms]

AURORA KA-1434
DIETHYL ETHANEPHOSPHONATE
DIETHYL ETHYLPHOSPHONATE
ETHANEPHOSPHONIC ACID DIETHYL ETHER
ETHYLPHOSPHONIC ACID DIETHYL ESTER
Amgard v 490
Diethoxyethylphosphine oxide
Ethanephosphonic acid, diethyl ester
ethanephosphonicacid,diethylester
ethyl-phosphonicacidiethylester
Phosphonic acid, ethyl-, diethyl ester
Phosphonicacid,ethyl-,diethylester
ETHYLPHOSPHONIC ACID DIETHYL ESTER 97+%
Diethylethylphosphonate,98%
[EINECS(EC#)]

201-111-9
[Molecular Formula]

C6H15O3P
[MDL Number]

MFCD00039888
[Molecular Weight]

166.16
[MOL File]

78-38-6.mol
Chemical PropertiesBack Directory
[Appearance]

colourless liquid
[Boiling point ]

82-83 °C (11 mmHg)
[density ]

1.024 g/mL at 20 °C(lit.)
[vapor pressure ]

7.2hPa at 20℃
[refractive index ]

n20/D 1.417
[Fp ]

105°C
[solubility ]

Chloroform (Soluble), Dichloromethane, Ethyl Acetate (Slightly)
[form ]

Liquid
[color ]

Clear colorless
[Stability:]

Stable, but hydrolyzes under both acidic and basic conditions. Incompatible with strong oxidizing agents.
[Water Solubility ]

Miscible with alcohol, ether and organic solvents. Slightly miscible with water.
[BRN ]

1756861
[Henry's Law Constant]

3.4×100 mol/(m3Pa) at 25℃, Bartelt-Hunt et al. (2008)
[Dielectric constant]

9.9(45℃)
[LogP]

3.2 at 20℃
[CAS DataBase Reference]

78-38-6(CAS DataBase Reference)
[EPA Substance Registry System]

Diethyl ethylphosphonate (78-38-6)
Questions And AnswerBack Directory
[Preparation]

Triethyl phosphite and the catalyst ethyl p-toluenesulfonate were mixed and stirred until homogeneous, then heated to the reflux temperature of triethyl phosphite. After reflux reaction, the mixture was distilled under reduced pressure, and the fraction at 118–120 °C was collected under a vacuum of 0.095 MPa to obtain the colorless and transparent product diethyl ethylphosphonate.
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)Exclamation Mark (GHS07)Environment (GHS09)
GHS05,GHS07,GHS09
[Signal word ]

Danger
[Hazard statements ]

H313-H319-H401-H302-H318-H411
[Precautionary statements ]

P273-P280-P305+P351+P338-P264-P280i-P301+P312a-P337+P313-P501a
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S37/39:Wear suitable gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[RIDADR ]

UN 3082 9/PG 3
[WGK Germany ]

2
[RTECS ]

SZ7925000
[TSCA ]

Yes
[REACH Registrations]

Active
[HazardClass ]

9
[HS Code ]

29310040
[Hazardous Substances Data]

78-38-6(Hazardous Substances Data)
Hazard InformationBack Directory
[General Description]

Colorless liquid with a mild odor.
[Reactivity Profile]

Organophosphates, such as DIETHYL ETHYLPHOSPHONATE(78-38-6), are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.
[Air & Water Reactions]

Slightly water soluble. May hydrolyze under acid or basic conditions .
[Chemical Properties]

colourless liquid
[Uses]

Diethyl Ethylphosphonate can be used as a flame retardant, and also used as a general reagent in phosphinoalkene and phosphinoalkyne synthesis.
[Uses]

Diethyl ethylphosphonate is used for heavy-metal extraction and solvent separation. It is also used as a gasoline additive, antifoam agent, plasticizer and textile conditioner. Further, it serves as an antistatic agent, flame retardant and as a general reagent in phosphinoalkene and phosphinoalkyne synthesis.
Spectrum DetailBack Directory
[Spectrum Detail]

DIETHYL ETHYLPHOSPHONATE(78-38-6)MS
DIETHYL ETHYLPHOSPHONATE(78-38-6)1HNMR
DIETHYL ETHYLPHOSPHONATE(78-38-6)13CNMR
DIETHYL ETHYLPHOSPHONATE(78-38-6)IR1
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Diethyl ethylphosphonate, 98%(78-38-6)
[Alfa Aesar]

Diethyl ethylphosphonate, 98%(78-38-6)
[Sigma Aldrich]

78-38-6(sigmaaldrich)
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