14056-88-3

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14056-88-3 Structure

Identification	Back Directory
[Name] CIS-DICHLOROBIS(TRIPHENYLPHOSPHINE)PLATINUM(II)
[CAS] 14056-88-3
[Synonyms] CIS PTCL2(PPH3)2 Chlorotri platinuM DICHLOROBIS(TRIPHENYLPHOSPHINE)PLATINATE (II) trans-Bis(triphenylphosphine)platinum dichloride TRANS-DICHLOROBIS(TRIPHENYLPHOSPHINE)PLATINUM(II) CIS-BIS(TRIPHENYLPHOSPHINE)PLATINUM(II) DICHLORIDE
[Molecular Formula] C36H30Cl2P2Pt
[MDL Number] MFCD00010825
[MOL File] 14056-88-3.mol
[Molecular Weight] 790.55

Chemical Properties	Back Directory
[Melting point ] ≥300 °C(lit.)
[storage temp. ] under inert gas (nitrogen or Argon) at 2–8 °C
[InChI] 1S/2C18H15P.2ClH.Pt/c21-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h21-15H;2*1H;/q;;;;+2/p-2
[InChIKey] XAFJSPPHVXDRIE-UHFFFAOYSA-L
[SMILES] Cl[Pt]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6

Safety Data	Back Directory
[Symbol(GHS) ] GHS07,GHS08
[Signal word ] Danger
[Hazard statements ] H302-H315-H317-H319-H334-H335-H373
[Precautionary statements ] P260-P264-P280-P301+P312-P302+P352-P305+P351+P338
[Hazard Codes ] Xi
[Risk Statements ] 36/37/38
[Safety Statements ] 26-37/39
[WGK Germany ] 3
[Storage Class] 11 - Combustible Solids
[Hazard Classifications] Acute Tox. 4 Oral Eye Irrit. 2 Resp. Sens. 1 Skin Irrit. 2 Skin Sens. 1 STOT RE 2 STOT SE 3

Hazard Information	Back Directory
[Uses] Catalyst for: Preparation of soluble polymers of monosubstituted acetylenes with quaternary ammonium pendant groups Alkynylation and hydrogenation reactions Hetero-Diels-Alder/ring-opening reactions Insertion of carbenes into O-H bonds of alcohols Cyclopropanation of olefins Hydroformylation reactions
[reaction suitability] core: platinum reagent type: catalyst

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