ChemicalBook--->CAS DataBase List--->14128-54-2

14128-54-2

14128-54-2 Structure

14128-54-2 Structure
IdentificationMore
[Name]

LITHIUM ALUMINUM DEUTERIDE
[CAS]

14128-54-2
[Synonyms]

LAD (D4)
LITHIUM ALUMINIUM DEUTERIDE
LITHIUM ALUMINUM DEUTERIDE
LITHIUM ALUMINUM DEUTERIDE (D4)
aluminium lithium deuteride
lithium tetradeuteridoaluminate
LITHIUM ALUMINUM DEUTERIDE, 96 ATOM % D, 1.0M SOLUTION IN DIETHYL ETHER
LITHIUM ALUMINUM DEUTERIDE, 96 ATOM % D, 1.0M SOLUTION IN TETRAHYDROFURAN
LITHIUM ALUMINUM DEUTERIDE, 98 ATOM % D
Lithium aluminium deuteride, 1.0M in diethyl ether
1.0MsolutioninDiethylether
Lithium aluminium deuteride, for NMR, 98 atom% D
Lithiumaluminumdeuteride,98%isotopicpurity
Aluminate(1-), tetrahydro-d4-, lithium, (T-4)-
deuterated lah
lithium aluminum deuteride solution
lithium aluminum deuteride, 1.0m in diethyl ether
LITHIUM ALUMINIUM DEUTERIDE ISOTOPIC PURITY
Lithium aluminium deuteride >99 Atom % D
Lithium aluminium deuteride, 98 atom% d, for NMR
[EINECS(EC#)]

237-980-6
[Molecular Formula]

AlD4Li
[MDL Number]

MFCD00044245
[Molecular Weight]

41.98
[MOL File]

14128-54-2.mol
Chemical PropertiesBack Directory
[Appearance]

solid
[Melting point ]

125 °C(lit.)
[density ]

0.736
[Fp ]

<−30 °F
[storage temp. ]

water-free area
[form ]

Liquid
[color ]

Clear colorless to faint yellow
[Stability:]

Reacts violently with water.
[Water Solubility ]

soluble ether, tetrahydrofuran [HAW93]
[Sensitive ]

air sensitive, moisture sensitive
[InChI]

InChI=1S/Al.Li.4H/q-1;+1;;;;/i;;4*1+1
[InChIKey]

OCZDCIYGECBNKL-HGZFDWPVSA-N
[SMILES]

[Al-]([2H])([2H])([2H])[2H].[Li+]
[CAS DataBase Reference]

14128-54-2(CAS DataBase Reference)
[CAS Number Unlabeled]

16853-85-3
Hazard InformationBack Directory
[Chemical Properties]

solid
[Uses]

Lithium aluminum deuteride is used as a source of deuterium atoms (heavy hydrogen, 1D-2) to produce tritium (1T-3) (super heavy hydrogen) for cooling nuclear reactors.
[Production Methods]

Lithium aluminum deuteride can be prepared in situ by the method of Wiberg & Schmidt, using lithium deuteride and redistilled aluminium bromide[1].
[References]

[1] le C. Holding, A. F., & Ross, W. A. (1958). The laboratory preparation of lithium deuteride and lithium aluminium deuteride. 8 5, 321–324. https://doi.org/10.1002/jctb.5010080508
Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)Corrosion (GHS05)Skull and Crossbones (GHS06)
GHS02,GHS05,GHS06
[Signal word ]

Danger
[Hazard statements ]

H301-H260-H314
[Precautionary statements ]

P264-P270-P301+P310-P321-P330-P405-P501-P223-P231+P232-P280-P335+P334-P370+P378-P402+P404-P501-P260-P264-P280-P301+P330+P331-P303+P361+P353-P363-P304+P340-P310-P321-P305+P351+P338-P405-P501
[Hazard Codes ]

F+,C,F
[Risk Statements ]

R15:Contact with water liberates extremely flammable gases.
R40:Limited evidence of a carcinogenic effect.
R34:Causes burns.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R19:May form explosive peroxides.
R14:Reacts violently with water.
R12:Extremely Flammable.
R11:Highly Flammable.
[Safety Statements ]

S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S36:Wear suitable protective clothing .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S16:Keep away from sources of ignition-No smoking .
S7/8:Keep container tightly closed and dry .
S43:In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add-Never use water) .
S24/25:Avoid contact with skin and eyes .
[RIDADR ]

UN 3399 4.3/PG 1
[WGK Germany ]

3
[HazardClass ]

4.3
[PackingGroup ]

I
[HS Code ]

28459000
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Lithium deuteride-->Aluminum Bromide
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Lithium aluminium deuteride, for NMR, 98 atom% D(14128-54-2)
[Alfa Aesar]

Lithium aluminum deuteride, 1.0M in diethyl ether(14128-54-2)
[Sigma Aldrich]

14128-54-2(sigmaaldrich)
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